[Ni(en)3]4[HVⅣ12VⅤ6O42(PO4)]复合物的合成及晶体结构

A new complex [Ni(en)₃]₄[HV^Ⅳ₁₂V^Ⅴ₆O₄₂(PO₄)] has been hydrothermally synthesized and characterized by X-Ray diffraction, IR and Elemental analysis. Single crystal X-ray analysis indicates that this compoud crystallizes in cubic system,space group Im 3m with a=17.4081(2)?, V=5275.38(10)?³, R=0.0420, wR=0.1055, Z=2, D_c=1.663g·cm^-3, μ=2.297mm^-1, F(000)=2636. The crystal structure consists of [Ni(en)₃]²⁺ cations and {HV₁₈O₄₂(PO₄)}^8- cluster anion which construct from 18 {VO₅} square pyramids. The VO₅ pyramids joined each other to form a {V₁₈O₄₂} cage hosting a tetrahedral {PO₄}^3- moiety with disordered oxygen atoms. CCDC: 185574.     

乙酰基硫代甲酰芳胺合成二氢吡嗪的研究

报道了一种合成乙酰基硫代甲酰芳胺的方法. 合成的乙酰基硫代甲酰芳胺与1,2-乙二胺缩合生成5-(4'-取代苯胺基)-6-甲基-2,3-二氢吡嗪类杂环化合物.     

化学气相沉积法制备氧化锡自组装纳米结构

采用化学气相沉积法在镀有5-10 nm厚金膜的SiO2衬底上, 通过控制生长条件, 实现了二氧化锡纳米结构的自组装生长, 成功制备出了莲花状和菊花状的二氧化锡自组装纳米结构. 利用扫描电子显微镜、X射线衍射等表征分析手段对样品的表面形貌、结构及成份进行表征和研究. 并在此基础上, 讨论了两种自组装纳米结构的生长机制.     

高效液相色谱-荧光检测法测定敬钊毒素-I的磷脂膜结合活性

敬钊毒素-I(JZTX-I)是一种能够抑制心肌钠通道失活的新型蜘蛛神经毒素,该文结合高效液相色谱与色氨酸荧光测定技术研究了JZTX-I的磷脂膜结合活性。脂质体共沉淀实验表明,JZTX-I具有不依赖于带负电荷磷脂组成的生物膜结合活性。当加入由酸性或中性磷脂构成的脂质体后,JZTX-I能够分别产生6.4和4.7 nm的蓝移以及7.4和8.0 nm的红移激发漂移,显示JZTX-I能够插入磷脂膜,同时该分子疏水表面的色氨酸残基处于一个运动受限的界面区域。荧光淬灭实验进一步证实,与脂质体结合能够减少该毒素分子表面色氨酸残基的溶剂暴露。该研究结果为阐明JZTX-I的离子通道门控调节机制提供了新的信息。     

冠醚化Schiff 碱配合物金属胶束催化BNPP水解动力学

研究了两种新的冠醚化Schiff 碱过渡金属配合物与表面活性剂Brij35(聚氧乙烯(23)十二烷基醚)形成的金属胶束对BNPP（对硝基苯酚磷酸二酯）的催化水解反应. 探讨了催化反应机理, 建立了一种金属胶束催化BNPP水解的动力学数学模型; 计算了模拟酶催化反应的相关参数和表观活化能. 结果表明, 此类金属胶束作为模拟水解金属酶对BNPP水解反应表现出良好的催化活性.     

高纯氧化钇中镧、铈、钐、铝、铅和铜的电感耦合等离子体原子发射光谱法测定

本文以纯Y_2O_3中杂质元素的ICP-AES测定为例,研究用数值微分技术解决光谱干扰同题。结果表明,导数光谱法不仅可以有效地消除来自基体的光谱干扰,还能减小谱线干扰对检测能力的影响。当分析物浓度较低时,导数光谱法的加入回收率明显优于离峰分析法,多数情况下也优于在峰法校正光谱干扰时的回收率。     

表面修饰的二氧化锡纳米粒子的制备及微结构表征

采用胶体化学制得表面包覆有ＤＢＳ的二氧化锡纳米粒子，并运用一系列手段对其微结构进行了表征。     

Synthesis and Anti-inflammatory Action of(η-C5H5)2Ti(Sal)2 and (η-C5H5)2Ti(Clo)2

Two new complexes (Cp)2Ti(Sal)2 and(Cp)2Ti(Clo)2(Cp=Cyclopentadienyl η5-C5H5), have been synthesized in anhydrous THF by the reaction of Hsal(o-hydroxybenzoic acid, salicylate acid) or Hclo[N-(m-chloro-phe-nyl) anthranili acid, acidum clofenamicum] with (Cp)2TiCl2 and characterized by means of elemental analyses, IR, 1H NMR, 13C NMR, UV and molar conductivity. In complex (Cp)2Ti(Sal)2 or (Cp)2Ti(Clo)2, the oxygen atom of the carboxyl group coordinates to Ti(IV) in a monodentate manner. The inhibitory action of the complexes on mouse ear tumefaction caused by croton oil and rat foot granulation growth caused by cotton balls is higher than that of the corresponding ligands Hsal, Hclo and [(Cp)2TiCl2], whereas their toxicity is lower than those of the free ligands.     

Evaluation of Transient Absorption Spectra of N, N, N, N- Tetra - ( p -methylphenyl ) - 4, 4- diamino - 1, 1- diphenyl Ether ( TPDAE ) for Electron Transfer from TPDAE to Fullerenes ( C_(60) / C_(70) ) by Laser Flash Photolysis

Fullerenes C60 and C70 have high electron affinity ( 2.6 - 2.8 ev ) and readily form anions on electronchemical reduction1, which were famous as electron acceptor in photo-excitation because of symmetrical shape, large size, and properties of its p - electron system2. After observation of molecular ferromagnetism3 in the tetrakis (dimethylamino ) ethylene salt of C60 as well as the occurrence of ultra-fast photoinduced electron transfer within the dimethyl aniline - C60 complex4, prompted us…     

Evaluation of Transient Absorption Spectra of N, N, N′, N′- Tetra - ( p -methylphenyl ) - 4, 4′- diamino - 1, 1′- diphenyl Ether ( TPDAE ) for Electron Transfer from TPDAE to Fullerenes ( C60 / C70 ) by Laser Flash Photolysis

Photoinduced electron transfer processes between fullerenes (C60 / C70) and N, N, N′, N′- tetra - ( p-methylphenyl ) - 4, 4′- diamino - 1, 1′- diphenyl ether ( TPDAE ) have been studied by nanosecond laser flash photolysis. Quantum yields and rate constants of electron transfer from TPDAE to excited triplet state of fullerenes (C60 / C70 ) in benzonitrile have been evaluated by observing the transient absorption bands in the near-IR region where the excited triplet state, radical anion of fullerenes ( C60 / C70 ) and radical cations of TPDAE appear.