Synthesis,Crystal Structure and Luminescence of [Ag(PPh3)2(H2TMT)]

The silver complex Ag(PPh₃)₂(H₂TMT) ( 1 )(H₃TMT = 2,4,6‐trimercapto‐1,3,5‐triazine) has been synthesized and characterized. The ligand trimercaptotriazine exhibits a novel coordination mode and the complex shows a special hydrogen bonding linkage in the crystal packing. The colorless crystals of 1 exhibit broad emission in the visible region at room temperature. TDDFT calculation indicated that the π–π attraction is crucial for fluorescence of the title complex.     

Sequence-specific Hydrolysis of Single-stranded DNA by PNA-Cerium （Ⅳ） Adduct

A novel artificial site specific cleavage reagent, with peptide nucleic acid （PNA） as sequence-recognizing moiety and cerium （IV） ions as “scissors” for cleaving target DNA, was synthesized. Subsequently, it was employed in the cleavage of target 26-mer single-stranded DNA （ssDNA）, which has 10-mer sequence complementary with PNA recognizer in the hybrids, under physiological conditions. Reversed-phase high-performance liquid chromatogram （RPHPLC） experiments indicated that the artificial site specific cleavage reagent could cleave the target DNA specifically.     

Millimeter-Wave Lange Coupler Design and Its Application in the Monolithic Image Rejection Mixer Design

This paper reports on the design of a Ka-band monolithic Lange coupler and its application in the monolithic fourth-harmonic image rejection mixer. Detailed design and analysis using Ansoft-HFSS simulator have been carried out. The simulated results of the Lange Coupler show the insert loss is better than −3.64 dB; the amplitude balance is less than 0.55 dB and the phase balance is less than 0.65° from the 90° phase difference over the 30 to 40 GHz frequency range. The Lange Coupler is employed in a monolithic image rejection mixer that is fabricated by a commercial 0.18-μm pseudomorphic high electron-mobility transistor (pHEMT) process. The chip size is 1.4 mm × 1.9 mm. The image rejection ratio (IMR) is from 15 to 34 dB in the RF frequency range of 30 to 40 GHz.     

Complete classification of the direction loci for three-wave collinear quadratic parametric interactions in biaxial acentric crystals

One new topological classification of the phase-matching direction loci for sum/difference frequency generation in biaxial acentric crystals is presented. Based on nine fundamental axial wave constant mismatches, 12 locus indices are used to distinguish permissible direction loci. Totally 66 kinds of combined loci belonging to 30 main classes are found and categorized by a set of ternary-digit class symbols or equivalently by sequence numbers. They are well illustrated in a classification diagram, indicative of 170 possible transitions among the loci. By an analysis of the dispersion of refractive indices, the historic “optically well-behaved crystals” are redefined and improved with simplified classification diagrams and corresponding schematic stereographic projections.     

混沌优化水下地形匹配算法研究

为了解决迭代最近点算法的定位精度和实时性问题,提出了一种基于混沌优化搜索的迭代最近点算法.在该算法中,以参考导航系统测量位置为中心规划真实位置的搜索范围,从参考地形图上提取相应的地形高程数据,与对应经纬度位置一起定义成模式类,将模式识别的过程转化成函数优化问题,然后运用混沌优化算法搜索目标函数最小值进行全局寻优,从而获得匹配最近点.仿真结果表明,在保证寻优性能的情况下,可以减少匹配次数,提高识别速度,满足地形匹配精度和实时性的要求.     

The primes contain arbitrarily long polynomial progressions

We establish the existence of infinitely many polynomial progressions in the primes; more precisely, given any integer-valued polynomials P ₁, …, P _k  ∈ Z[m] in one unknown m with P ₁(0) = … = P _k (0) = 0, and given any ε > 0, we show that there are infinitely many integers x and m, with 1 \leqslant m \leqslant x^e1 \leqslant m \leqslant x^\varepsilon, such that x + P ₁(m), …, x + P _k (m) are simultaneously prime. The arguments are based on those in [18], which treated the linear case P _j  = (j − 1)m and ε = 1; the main new features are a localization of the shift parameters (and the attendant Gowers norm objects) to both coarse and fine scales, the use of PET induction to linearize the polynomial averaging, and some elementary estimates for the number of points over finite fields in certain algebraic varieties.     

Schiff碱作为桥配体的双核钌化合物的合成与性质

合成并表征了3个Schiff碱配体及由其桥联的3个双核钌配合物,并通过核磁共振谱、红外光谱、质谱及元素分析等测试手段对配体及化合物进行了表征.电化学测试结果表明,在3个双核配合物中存在着分子内的金属-金属间相互作用,且连接两个金属的桥配体是影响金属间相互作用强弱的关键因素.     

Preparation and Recognition Study on the Peptides in Aqueous Media of Poly(pyridine derivative‐co‐acrylamide)

Three copolymers (bearing metal ion coordinated sites) P1 , P2 and P3 were synthesized and their recognition behavior on predetermined peptide sequences was studied by isothermal titration calorimetry.     

发射方向调制信号的多波束调制技术

为了使单天线接收机通过接收解调信号能实现通信和方向测量功能,提出了一种多波束调制的概念.它利用双波束或多波束的空间特性来实现数字调制和方向调制.设计了一个六元线天线发射阵列,将中间的四元天线两两成对激励,形成双波束,用双波束调制实现数字通信和方向粗测,然后对大间距的二元天线用不同的相差激励,形成有错位的多波束,用多波束调制实现数字通信和方向精测.仿真结果表明这种多波束调制实现了在调制信号设计层面上的数字通信与测向的深度综合.