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421.
Kiyooka S Shahid KA Goto F Okazaki M Shuto Y 《The Journal of organic chemistry》2003,68(21):7967-7978
The segments C(1)-C(13) and C(15)-C(21) containing the 13 stereogenic centers required for the frame of (+)-discodermolide were synthesized in good to excellent enantio- and diastereoselectivities from a common racemic aldehyde, derived from 2-methyl-1,3-propanediol. The enantioselective aldol reactions of the racemic aldehyde with a silylketene acetal, derived from ethyl 2-bromopropionate, in the presence of chiral oxazaborolidinones, prepared in situ with N-p-toluenesulfonyl-(R)- and -(S)-valine and BH(3).THF, proceeded under kinetic control to give the stereotriads with a high degree of enantioselectivity. Enantioselective (chiral borane) and diastereoselective (BF(3).OEt(2) and TiCl(4)) aldol reactions with the silylketene acetal, coupled with diastereoselective radical debrominations (Bu(3)SnH, Et(3)B, with or without MgBr(2)), were used iteratively. This aldol reaction strategy for the construction of the polypropionate frame dramatically shortened the steps needed for the construction of the final segments. 相似文献
422.
AHMAD H. Badaruddin ARFAN Muhamma RAMA N. Hasan MALANA M. Aslam MAHBOOB Shahid 《中国化学》2007,25(1):102-104
6,8-Dimethoxy-3-[2-(4-methoxyphenyl)ethyl]isocoumarin was synthesized by condensation of 5,7-dimethoxyhompophthalic acid with 3-(4-methoxyphenyl)propanoyl chloride. The structure of the synthesized compound was confirmed by its mass spectrometric studies. The synthesized compound serves as a model for synthesis of DL-agrimonolide. 相似文献
423.
Shahid Anwar 《Journal of solid state chemistry》2008,181(5):997-1004
The structural variants and their coexistence across the antiferroelectric phase transition in Sr0.60Ca0.40TiO3 ceramic has been studied through transmission electron microscopy (TEM) at room temperature and ∼100 °C. A clear evidence of the presence of superlattice reflections, corresponding to the cell doubling along the c-axis of Pbnm (or b-axis along Pnma), occurring during paraelectric to antiferroelectric transition, has been obtained through selected area electron diffraction, convergent beam electron diffraction and lattice-resolution imaging. Coexistence of the Pbnm and Pbcm phases at room temperature has been observed and attributed to the strain/disorder-induced broadening of the first-order antiferroelectric phase transition. Drastic changes in the domain structure during Pbnm to Pbcm transformation have been observed. This clearly indicates that the antiferrodistortive transition responsible for the occurrence of the antiferroelectric phase is of completely different origin and it is not just an additional follow-up of the already-existing ordering due to a−a−c+ tilt schemes in the Pbnm domain. Thermal cycling studies on microstructural changes indicate some kind of memory mechanism, which retains the memory of the original a−a−c+ tilt schemes in the Pbnm phase. This has been attributed to the symmetry conforming short-range order (SC-SRO) of the point defects. 相似文献
424.
Using ladder operators for the non-linear oscillator with position-dependent effective mass, realization of the dynamic group SU(1,1) is presented. Keeping in view the algebraic structure of the non-linear oscillator, coherent states are constructed using Barut-Girardello formalism and their basic properties are discussed. Furthermore, the statistical properties of these states are investigated by means of Mandel parameter and second order correlation function. Moreover, it is shown that in the harmonic limit, all the results obtained for the non-linear oscillator with spatially varying mass reduce to corresponding results of the linear oscillator with constant mass. 相似文献
425.
Shahid Adeel Khalid Mahmood Zia Muhammad Abdullah Mahwish Salman Mohammad Zuber 《Natural product research》2019,33(14):2060-2072
Natural products with therapeutic nature are nowadays warmly welcomed in textiles. Current study is concerned with isolation of tannin from neem bark (Azadirachta indica) and its application onto silk fabric. For improvement in shades, chemical & bio-mordants have been employed at optimal dyeing conditions. It is found that methanolic extract of pH 5 obtained 8 g dye powder after US Treatment for 30 min has given high color strength if used to dye irradiated silk for 65 min at 75 °C. Bio-mordanting using herbal plants has improved the color characteristics as compared to chemical mordants used. ISO standards for color fastness reveal that herbal based bio-mordants have improved the rating from good to excellent as compared to chemical mordants used. It is concluded that US treatment has not only isolate the colorant for neem bark under mild condition but also given excellent characteristic using bio mordants onto silk fabrics. 相似文献
426.
Kim Kwangsoo Kim Guinyun Shahid Muhammad Zaman Muhammad Yang Sung-Chul Uddin Md. Shuza Naik Haladhra 《Journal of Radioanalytical and Nuclear Chemistry》2018,317(2):1021-1031
Journal of Radioanalytical and Nuclear Chemistry - The excitation functions of 93Nb(p,x) reactions from their respective thresholds to 42.5 MeV were measured at the MC-50 cyclotron of... 相似文献
427.
428.
Zhao Liqing Jiang Yingzi Fang Huiyan Zhang Haichao Cheng Shuang Rajoka Muhammad Shahid Riaz Wu Yiguang 《Applied biochemistry and biotechnology》2019,189(2):448-458
Applied Biochemistry and Biotechnology - For efficiently enhancing the activity of isoeugenol monooxygenase, a whole cell overproducing active aggregate IEM720-18A was successfully fabricated via... 相似文献
429.
Channar Pervaiz Ali Arshad Nasima Farooqi Shahid Iqbal Larik Fayaz Ali Saeed Aamer Hökelek Tuncer Shehzadi Syeda Aaliya Abbas Nasir Flörke Ulrich 《Applied biochemistry and biotechnology》2019,189(1):175-192
Applied Biochemistry and Biotechnology - (E)-2-(3-Hydroxy-4-methoxybenzylidene)hydrazinecarbothioamide 3 was synthesized by reacting thiosemicarbazide with 2-hydorxy-3-methoxybenzaldehyde in dry... 相似文献
430.
Akhtar Muhammad Nadeem AlDamen Murad A. Zierkiewicz Wiktor Michalczyk Mariusz Khalid Muhammad Idrisi Mantasha Shahid M. 《Research on Chemical Intermediates》2020,46(9):4155-4171
Research on Chemical Intermediates - Reaction of FeCl2·4H2O, NaN3 and N,N′-bis(2-hydroxyethyl)-ethylenediamine (heenH2) in a CH3CN/CH2Cl2 solution resulted in a dinuclear complex,... 相似文献