Surface polaritons and plasmons: Spontaneous emission from an atom near a small body

The results of experiments, in which the probability of spontaneous Raman scattering from a molecule adsorbed at the surface of a silver nanoparticle was found to grow by 14 and more orders of magnitude, are interpreted. The molecule occurs in the field of a surface plasmon, which accounts for an increase in the local field strength and the density of states by 12–13 orders of magnitude. An additional increase by 1–2 orders of magnitude is explained by the antenna effect of a pair of nanoparticles, one being ultimately small and the other, sufficiently large to serve a receiving-transmitting antenna.     

Ultrathin Fe film on Cu(0 0 1): Exchange splitting of image states from first principles

The theoretical investigation of the image states in front of an ultrathin iron film grown on copper has been performed by means of the embedding method and a recently developed procedure for the inclusion of the image potential tail in a first principle calculation. From the electronic response to an applied electric field, the image plane position has been evaluated. This also allows one to obtain useful information about the spin dependent screening properties of the system. Exchange splitting, effective mass, and lifetime of such surface states result in good agreement with recently performed two-photon photoemission experiments [see A.B. Schmidt, M. Pickel, M. Wiemhöfer, M. Donath, M. Weinelt, Phys. Rev. Lett. 95 (2005) 107402].     

The effect of olefinic terminal chains on the mesomorphic properties of 4,4'-disubstituted diphenyldiacetylenes

New diphenyldiacetylenes of the type with A, B = H and/or F; m = 0, 1; n = 1-4; and X = C n H 2n + 1 , F, CF 3 or CN were synthesized and their mesomorphic properties determined by hot stage polarizing microscopy and DSC. When m = 0, all of these compounds showed only a nematic phase except when X = CF 3 when both nematic and smectic A phases were seen. Both clearing and melting temperatures were higher than those reported for substitution with the corresponding alkyl chains but the much larger increase in clearing temperatures produced considerably wider nematic phases. Eutectic mixtures of a few of these olefins yielded nematic materials also having much wider temperature ranges and higher clearing temperatures than the eutectic mixtures of the alkyl compounds, while retaining their high birefringence and low viscosities. Such materials are of interest for beam-steering devices.

Four of the diacetylenes with m = 1 ( A, B = H) were also prepared ( X = C 6 H 13 , F, n = 2, 3). When X was C 6 H 13 ( n = 2), the nematic range was smaller in the 2- than in the 1-olefin but wider than in the alkyl series. When X = F, either no nematic phase or a monotropic one was observed, whereas the 1-olefins gave a much wider nematic phase. Both transition temperatures were lower than those for the corresponding 1-olefin and alkyl analogues. The compound with X = C 6 H 13 and n = 2 had a melting temperature below room temperature.     

Singularities and noncommutative Frobenius manifolds

We prove that the quaternionic miniversal deformations of an A _n singularity have the structure of a noncommutative Frobenius manifold in the sense of the extended cohomological field theory.     

Zeroth-order phase transitions and Zipf law quantization

From the standpoint of thermodynamic averaging of fission microprocesses, we investigate the origin of radioactive release in an NPP after an accident or after resource depletion. The genesis of the NPP release is interpreted as a new thermodynamic phenomenon, a zeroth-order phase transition. This problem setting results in a problem in probabilistic number theory. We prove the corresponding theorem leading to quantization of the Zipf law for the frequency of a zeroth-order phase transition with different values of the jump of the Gibbs thermodynamic potential. We introduce the notion of hole dimension. __________ Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 150, No. 1, pp. 118–142, January, 2007.     

Cauchy problem in the class of monotone increasing functions

The paper establishes some solvability conditions of the Cauchy problem for linear differential equation in the class of monotone increasing functions. The results are applied for clarifying the possibility of flight along a given trajectory under existence of braking forces.     

The centralizer algebra of the diagonal action of the group <Emphasis Type="Italic">GL</Emphasis><Subscript><Emphasis Type="Italic">n</Emphasis></Subscript>(ℂ) in a mixed tensor space

We consider the walled Brauer algebra Br _{k, l}(n) introduced by V. Turaev and K. Koike. We prove that it is a subalgebra of the Brauer algebra and that it is isomorphic, for sufficiently large n ∈ ℕ, to the centralizer algebra of the diagonal action of the group GL_n(ℂ) in a mixed tensor space. We also give the presentation of the algebra Br _{k, l}(n) by generators and relations. For a generic value of the parameter, the algebra is semisimple, and in this case we describe the Bratteli diagram for this family of algebras and give realizations for the irreducible representations. We also give a new, more natural proof of the formulas for the characters of the walled Brauer algebras. Bibliography: 29 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 331, 2006, pp. 170–198.