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991.
Experimental Mechanics - Background: Experimental modelling techniques are still rare for composite structures under complex thermal environments. Objective: In this paper, by taking a... 相似文献
992.
Carina I. Jette Z. Jaron Tong Ryan G. Hadt Brian M. Stoltz 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(5):2049-2054
Herein, we report a Cu-catalyzed enantioselective allylic alkylation using a γ-butyrolactone-derived silyl ketene acetal. Critical to the development of this work was the identification of a novel mono-picolinamide ligand with the appropriate steric and electronic properties to afford the desired products in high yield (up to 96 %) and high ee (up to 95 %). Aryl, aliphatic, and unsubstituted allylic chlorides bearing a broad range of functionality are well-tolerated. Spectroscopic studies reveal that a CuI species is likely the active catalyst, and DFT calculations suggest ligand sterics play an important role in determining Cu coordination and thus catalyst geometry. 相似文献
993.
994.
Cihang Yu Dr. Agnes Kütt Prof. Dr. Gerd-Volker Röschenthaler Dr. Tomas Lebl Dr. David B. Cordes Prof. Dr. Alexandra M. Z. Slawin Prof. Dr. Michael Bühl Prof. Dr. David O'Hagan 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(45):20077-20081
We report the synthesis of all-cis 1,2,4,5-tetrakis (trifluoromethyl)- and all-cis 1,2,3,4,5,6-hexakis (trifluoromethyl)- cyclohexanes by direct hydrogenation of precursor tetrakis- or hexakis- (trifluoromethyl)benzenes. The resultant cyclohexanes have a stereochemistry such that all the CF3 groups are on the same face of the cyclohexyl ring. All-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)cyclohexane is the most sterically demanding of the all-cis hexakis substituted cyclohexanes prepared to date, with a barrier (ΔG) to ring inversion calculated at 27 kcal mol−1. The X-ray structure of all-cis 1,2,3,4,5,6-hexakis(trifluoromethyl)cyclohexane displays a flattened chair conformation and the electrostatic profile of this compound reveals a large diffuse negative density on the fluorine face and a focused positive density on the hydrogen face. The electropositive hydrogen face can co-ordinate chloride (K≈103) and to a lesser extent fluoride and iodide ions. Dehydrofluorination promoted decomposition occurs with fluoride ion acting as a base. 相似文献
995.
Cyclopentane and methylcyclopentane oxidation was investigated in a jet-stirred reactor at atmospheric pressure, over temperatures ranging from 900 to 1250 K, for fuel-lean, stoichiometric, and fuel-rich mixtures at a constant residence time of 70 ms. The initial mole fraction of both fuels was kept constant at 1000 ppm. The reactants were highly diluted by a flow of nitrogen to ensure thermal homogeneity. Samples of the reacting mixture were analyzed online and off-line by Fourier transform infrared spectroscopy and gas chromatography. A detailed kinetic mechanism consisting of 590 species involved in 3469 reactions was developed, and simulation results were compared to these new experimental data and previously reported ignition delays. Reaction pathways analysis as well as sensitivity analyses were performed to get insights into the differences observed during the oxidation process of cyclopentane and methylcyclopentane. 相似文献
996.
Acoustical Physics - The paper studies the propagation of low-frequency harmonic pressure waves in a fracture formed by hydraulic fracturing and perpendicular to the wellbore in a porous and... 相似文献
997.
Physics of Atomic Nuclei - The article presents a review of resonance reaction studies made by TTIK method. 相似文献
998.
Wang C. Cheng S. Y. Zhao W. W. Yang X. N. Zhou K. Z. Tian J. J. Jiang D. F. Ma P. H. 《Crystallography Reports》2020,65(7):1156-1160
Crystallography Reports - This paper reports on the supramolecular self-assembly of cyclopentano cucurbit[5]uril (CyP5Q[5]), L-phenylalanine (L-Phe), and cadmium ions. The crystal structure is... 相似文献
999.
Russian Physics Journal - An exact problem of the electromagnetic wave propagation in a multilayer heteronanostructure with complex values of the dielectric constant (permittivity) is solved. The... 相似文献
1000.
Chernyaev A. P. Bliznyuk U. A. Borshchegovskaya P. Yu. Nikitina Z. K. Gordonova I. K. Studenikin F. R. Ipatova V. S. 《Physics of Particles and Nuclei Letters》2020,17(4):611-614
Physics of Particles and Nuclei Letters - Chilled minced trout has been treated by 1-MeV electron-beam irradiation using the UELR-1-25-T-001 industrial electron accelerator. The results of the... 相似文献