Transient binary nucleation from ethanol-hexanol vapour

We study condensation of ethanol-hexanol vapour by numerical solution of kinetic equations. The number of droplets formed in unit volume is computed within self-consistent classical model. It is shown that formation of ethanol-rich droplets prevails at the initial stage of nucleation process, but in the stationary state formation of droplets near the saddle point (on cluster formation energy surface) plays the dominant role. Presented at the 6th Joint Seminar “Development of Materials Science in Research and Education”, Karlštejn, Czech Republic, 17–19 September 1996. This work was supported by Grant No. A1010615 of the Grant Agency of the Academy of Sciences of the Czech Republic.     

多级制造系统的最优化模型及其应用

多级制造系统是现代制造业的主要加工方式，系统的每一级的加工速度和加工周期是系统设计的主要决策变量，正确确定这两个变量是系统得到优化的主要目标。本文导出了系统优化的基本模型，它包括系统各级的生产时间、等待时间、生产速度、生产成本以及系统的循环时间、总成本、产品利润和利润率等，并给出了一个应用实例。     

Quadratic Functionals with General Boundary Conditions

The purpose of this paper is to give the Reid ``Roundabout Theorem' for quadratic functionals with general boundary conditions. In particular, we describe the so-called coupled point and regularity condition introduced in [16] in terms of Riccati equation solutions. Accepted 27 February 1996     

Double-diffusive convection for a heated cylinder submerged in a salt-stratified fluid layer

Double-diffusive convection due to a cylindrical source submerged in a salt-stratified solution is numerically investigated in this study. For proper simulation of the vortex generated around the cylinder, a computational domain with irregular shape is employed. Flow conditions depend strongly on the thermal Rayleigh number, Ra _T , and the buoyancy ratio, R _ρ. There are two types of onset of instability existing in the flow field. Both types are due to either the interaction of the upward temperature gradient and downward salinity gradient or the interaction of the lateral temperature gradient and downward salinity gradient. The onset of layer instability due to plume convection is due to the former, whereas, the onset of layer instability of layers around the cylinder is due to the latter. Both types can be found in the flow field. The transport mechanism of layers at the top of the basic plume belongs to former while that due to basic plume and layer around the cylinder are the latter. The increase in Ra _T reinforces the plume convection and reduces the layer numbers generated around the cylinder for the same buoyancy ratio. For the same Ra _T , the increase of R _ρ suppresses the plume convection but reinforces the layers generated around the cylinder. The profiles of local Nusselt number reflects the heat transfer characteristics of plume convection and layered structure. The profiles of averaged Nusselt number are between the pure conduction and natural convection modes and the variation is due to the evolution of layers. Received on 13 September 1996     

Time-resolved synchrotron X-ray study of crystalline phase transition in poly(aryl ether ketone ketone) containing alternated terephthalic/isophthalic moieties

Unique crystallization and melting behavior in poly(aryl ether ketone ketone) containing alternated terephthalic and isophthalic moieties were studied by time-resolved synchrotron x-ray methods. Recently, this material has been shown to exhibit three polymorphs (forms I, II, and III). In this work, we further investigated their distinctive thermal properties and found that form I is the dominating and the most thermally stable phase while form II is favored by fast nucleation conditions and is the least stable phase. On the other hand, form III represents a minor intermediate phase that usually coexists with form I and can be transferred from form II and to form I. Structural and morphological changes in form I have been followed by simultaneous wide-angle x-ray diffraction (WAXD)/small-angle x-ray scattering (SAXS) measurements during cold- or melt-crystallization and subsequent melting. In all cases, a larger dimensional change was found in the crystallographic a-axis than the b-axis during heating and cooling. This may be due to the greater lateral stress variation with respect to temperature along the a direction of the primary lamellae which is induced by either the formation of secondary lamellae or the preferential chain-folding direction in poly(aryl ether ketone ketone)s. During the phase transitions of form II ← III in the cold-crystallized specimen and form III ← I in the melt-crystallized samples, lamellar variables (long period, lamellar thickness, and invariant) obtained from SAXS remain almost constant. This indicates that the density distribution in the long spacing is independent of the melting in form II or III. For melt-crystallization, the corresponding changes in unit-cell dimensions and lamellar morphology during the annealing-induced low endotherm are most consistent with the argument that these changes are due to the melting of thin lamellar population. © 1995 John Wiley & Sons, Inc.     

Parasupersymmetric quantum mechanics of arbitrary order withN parasupercharges

Parasupersymmetric quantum mechanics is generalized to the case of an arbitrary number of parasuperchanrgesN and the order of paraquantizationp. We show that parasuperpotentials can be explicitly expressed via a single arbitrary function. Institute of Mathematics, Ukrainian Academy of Sciences, Kiev. Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 48, No. 9, pp. 1291–1294, September, 1996.     

聚类分析在髁突骨密度分析中的应用

本研究应用聚类分析的方法，对人离休髁突×片进行数字图像技术处理所获得的影像密度数值做了详细分析，取得人髁突不同区的骨密度分布及不同年龄阶段髁突密度变化的情况。该方法避免了人为因素的影响，其结果较客观地反映了髁突的骨质密度；为研究病理状态时髁突骨密度的改变提供参考。     

Decomposability of matrix polynomials with coefficients possessing quasi-simple structure

The decomposability of matrix polynomials with commuting coefficients of quasi-simple structure into regular factors and the solvability of the corresponding matrix polynomial one-sided equations are investigated.Translated from Ukrainskii Matematicheskie Zhurnal, Vol. 44, No. 12, pp. 1716–1718, December, 1992.     

Selective saturation and inversion of multiple resonances in high-resolution solid-state 13C experiments using slow spinning CP/MAS and tailored DANTE pulse sequences.

Taking advantage of the long 13C T1 values generally encountered in solids, selective saturation and inversion of more than one resonance in 13C CP/MAS experiments can be achieved by sequentially applying several DANTE pulse sequences centered at different transmitter frequency offsets. A new selective saturation pulse sequence is introduced composed of a series of 90 degrees DANTE sequences separated by interrupted decoupling periods during which the selected resonance is destroyed. Applications of this method, including the simplification of the measurement of the principal values of the 13C chemical shift tensor under slow MAS conditions, are described. The determination of the aromaticity of coal using a relatively slow MAS rate is also described.