全文获取类型
收费全文 | 2136篇 |
免费 | 47篇 |
专业分类
化学 | 1484篇 |
晶体学 | 30篇 |
力学 | 28篇 |
数学 | 82篇 |
物理学 | 559篇 |
出版年
2022年 | 17篇 |
2021年 | 14篇 |
2020年 | 23篇 |
2019年 | 28篇 |
2018年 | 17篇 |
2017年 | 16篇 |
2016年 | 40篇 |
2015年 | 39篇 |
2014年 | 35篇 |
2013年 | 92篇 |
2012年 | 81篇 |
2011年 | 90篇 |
2010年 | 57篇 |
2009年 | 56篇 |
2008年 | 105篇 |
2007年 | 97篇 |
2006年 | 99篇 |
2005年 | 99篇 |
2004年 | 100篇 |
2003年 | 83篇 |
2002年 | 92篇 |
2001年 | 70篇 |
2000年 | 49篇 |
1999年 | 26篇 |
1998年 | 27篇 |
1997年 | 19篇 |
1996年 | 29篇 |
1994年 | 21篇 |
1993年 | 21篇 |
1992年 | 25篇 |
1991年 | 28篇 |
1990年 | 29篇 |
1989年 | 24篇 |
1988年 | 28篇 |
1987年 | 27篇 |
1986年 | 21篇 |
1985年 | 48篇 |
1984年 | 38篇 |
1983年 | 29篇 |
1982年 | 28篇 |
1981年 | 37篇 |
1980年 | 24篇 |
1979年 | 40篇 |
1978年 | 33篇 |
1977年 | 17篇 |
1976年 | 31篇 |
1975年 | 19篇 |
1974年 | 13篇 |
1973年 | 13篇 |
1967年 | 14篇 |
排序方式: 共有2183条查询结果,搜索用时 0 毫秒
71.
T. Kawabata T. Adachi M. Fujiwara K. Hatanaka Y. Ishiguro M. Itoh Y. Maeda H. Matsubara H. Miyasako Y. Nozawa T. Saito S. Sakaguchi Y. Sasamoto Y. Shimizu T. Takahashi A. Tamii S. Terashima H. Tokieda N. Tomida T. Uesaka M. Uchida Y. Yasuda N. Yokota H. P. Yoshida J. Zenihiro 《Few-Body Systems》2013,54(1-4):93-97
The alpha inelastic scattering from 24Mg was measured to obtain the isoscalar natural-parity excitation strengths and to search for the α-condensed states. The multipole decomposition analysis for the measured cross sections was performed. The strength distributions for the ${{\Delta}L=0{-}3}$ were successfully obtained and the possible candidates for the α-condensed states around the 16O core were found. 相似文献
72.
The initial stage of cubic silicon carbide (3C-SiC) growth on a Si(0 0 1) surface using dimethylsilane (DMS) as a source gas was observed using scanning tunneling microscopy (STM) and reflection high-energy electron diffraction (RHEED). It was found that the dimer vacancies initially existing on the Si(0 0 1)-(2 × 1) surface were repaired by the Si atoms in DMS molecules, during the formation of the c(4 × 4) surface. From the STM measurement, nucleation of SiC was found to start when the Si surface was covered with the c(4 × 4) structure but before the appearance of SiC spots in the RHEED pattern. The growth mechanism of SiC islands was also discussed based on the results of RHEED, STM and temperature-programmed desorption (TPD). 相似文献
73.
Neuhauser RG Shimizu KT Woo WK Empedocles SA Bawendi MG 《Physical review letters》2000,85(15):3301-3304
We find a correlation between the dynamics of fluorescence intermittency and spectral diffusion in the spectroscopy of single CdSe nanocrystal quantum dots (QD). A statistical analysis of the data suggests two populations of blinking events: blinking followed by large spectral diffusion shifts and blinking with small or no spectral shifts. Although unexpected from earlier studies, the correlation between blinking and spectral shifting is consistent with a model of QD ionization as the mechanism for the blinking event, followed by a redistribution of local electric fields that results in spectral shifting. 相似文献
74.
Hiroshi Yasuoka Susumu Sasaki Takashi Imai Tadashi Shimizu Yutaka Ueda Koji Kosuge 《Phase Transitions》2013,86(4):183-199
The nuclear quadrupole resonance (NQR) technique has been utilized to characterize the local oxygen coordination of inequivalent Cu sites in YBa2Cu3O6+x(0 ≤ x ≤ 0.91). Essentially, four distinct NQR lines which correspond to 2, 3,4 oxygen coordinated Cu sites in the Cu-O chains and 5 oxygen coordinated Cu sites in the Cu-O planes have been observed. The zero-field NQR frequencies of these are centered at about 30.1, 24.0, 22.0 and 31.5 MHz for 63Cu, respectively. For the antiferromagnetic ordered state (x ≤ 0.3), antiferromagnetic nuclear resonance (AFNR) has been observed at 90 MHz with quadrupole splittings associated with the moment-bearing Cu sites in the Cu-O planes. The relative intensities of these resonance lines depend on the oxygen content, and this gives us a microscopic understanding of the Cu chemistry of this system. 相似文献
75.
A series of experiments were carried out to study the degradation of methylene blue by the irradiation of ultrasound onto TiO(2) in aqueous solution. A statistically significant decrease in the concentration of methylene blue was observed after 60 min irradiation. While the reduction was 22% of the initial concentration without H(2)O(2), addition of H(2)O(2) significantly enhanced the degradation of methylene blue for the TiO(2) containing system (85% reduction of the initial concentration). The addition of H(2)O(2) had no effect on the methylene blue degradation when the system contained Al(2)O(3). The degradation ratio of methylene blue was dependent on the amount of TiO(2) and also the specific surface area of TiO(2) in the solution. The effects of radical scavenging agents on the degradation of methylene blue were also investigated for the system with TiO(2). It was found that the radical scavenging agents dimethyl sulfoxide (DMSO), methanol, and mannitol suppressed the degradation, with DMSO being the most effective. The effect of pH on the degradation of methylene blue was further investigated. An U-shaped change in the concentration of methylene blue in the presence of TiO(2) was observed along with the change in pH values (pH 3-12), and the highest degradation ratio was observed at around pH 7. In conclusion, ultrasound irradiation of TiO(2) in aqueous solution resulted in significant generation of hydroxyl radicals, and this process may have potential for the treatment of organic dyes in wastewater. 相似文献
76.
Temperature dependence of the ESR signal intensity in amorphous SiGe films annealed at various temperatures is investigated. As a result, it is found that spins undergo a ferromagnetic interaction and the Curie-Weiss θ in the relation χ = C/ (T-θ) distributes between 40 and 135 K. The ferromagnetic behavior suggests that spins are inhomogeneously distributed and closely located together. 相似文献
77.
The contribution of backscattered electrons (BE) to Auger electrons (AE) and secondary electrons (SE) was studied by depositing Be onto a polycrystalline or deposited Cu substrate. The effects of backscattering on SE and maximum escape depth of SE were obtained by using the so called δ-η method. This method was also applied to the AE and the effects of BE on AE were experimentally evaluated. The AE yield versus primary energy curve which was corrected for BE was compared with other experiments and theories and considerably good agreement was obtained. From this analysis, the excitation efficiencies of AE by primary electrons and by BE could also be obtained. The absolute AE yield of Be (KVV) was estimated by “area” measurements. The changes of plasma losses, the elastic peaks, the energy distribution of BE, and the true SE were also observed as a function of deposited film thickness, and the results are discussed. 相似文献
78.
K. Hirose M. Ejima T. Fujibayashi Y. Fujii K. Futatsukawa O. Hashimoto T. Ishikawa S. Kameoka H. Kanda F. Kato S. Kinoshita T. Kinoshita T. Kon O. Konno K. Maeda A. Matsumura Y. Miura F. Miyahara H. Miyase T. Nakabayashi S.N. Nakamura H. Nomura K. Nonaka A. Ohtani Y. Okayasu M. Oyamada A. Sasaki H. Shimizu T. Takahashi T. Tamae H. Tamura T. Terasawa H. Tsubota K. Tsukada D. Uchida M. Ukai M. Wakamatsu T. Watanabe H. Yamauchi H. Yamazaki K. Yawata 《Physics letters. [Part B]》2009
79.
Abstract Polymers of bis(trimethylsilyl) fumarate, di-tert-amyl fumarate, and methyl tert-amyl fumarate were prepared by radical polymerization at 60 or 120°C. The polymers were converted into poly(dimethyl fumarate) via thermolysis or hydrolysis and subsequent methylation to determine the tacticity using 13C-NMR spectroscopy. The probabilities of meso addition (P m) were revealed to be 0.66 (60°C) for the bis(trimethylsilyl) ester, 0.60 (60°C) and 0.52 (120°C) for the di-tert-amyl ester, and 0.54 (60 and 120°C) for the methyl tert-amyl ester. From the temperature dependence of the P m values, the differences in activation enthalpies and entropies for the meso and racemo additions were evaluated. The microstructure of poly(dimethyl fumarate) derived from poly(maleic anhydride) was also examined. The opening and addition modes in propagation of the fumaric and maleic derivatives were discussed based on the results obtained in the present and previous work. 相似文献
80.
Hidemasa Azuma Yuzuru Katagiri Shinichi Yamabe 《Journal of polymer science. Part A, Polymer chemistry》1996,34(8):1407-1414
Transition states (TSs) of radical addition homopolymerization reactions of methyl acrylate, methyl methacrylate, dimethyl itaconate, and N-methyl itaconimide were examined with two-unit radical models using MOPAC (PM3 UHF) semiempirical method. Calculated activation energies (Eas) show good correlations with experimental values. Calculated activation entropies (−ΔS‡s) are found to be well proportional to Eas. The entropy terms play an important role as well as Ea in radical additions. Ea depends on the angle (θrs) between reaction points of radical and of monomer at TS. The bond length between reaction points at TS is constant regardless of monomers studied. The geometries and thermodynamical properties calculated here for TS indicate the importance of steric effects caused by substituted group(s) rather than electronic perturbation energies reported previously. © 1996 John Wiley & Sons, Inc. 相似文献