太阳能电池特性的自动测量

利用C8051F020单片机实现了对光电池的开路电压、短路电流、串联内阻、最佳负载、最佳输出功率等重要参数的自动测量和数据处理,并在液晶屏上自动显示相应的曲线.结合实际应用的情况,还测量了串联光电池和并联光电池的参数.     

Typical transient effects in a piezoelectric semiconductor nanofiber under a suddenly applied axial time-dependent force

Based on the mechanical motion equation, Gauss' s law, and the current continuity condition, we study a few typical transient effects in a piezoelectric semiconductor(PS) fiber to realize the startup and turning-off functions of common piezotronic devices. In this study, the transient extensional vibration induced by a suddenly applied axial time-dependent force is examined in a cantilevered n-type ZnO nanofiber. Neither the magnitude of the loadings nor the doping concentration significantly affects the propagation caused by disturbance of the axial displacement.However, both of the factors play an important role in the propagation caused by disturbance of the electron concentrations. This indicates that the electromechanical coupling effect can be expected to directly determine the electronic performance of the devices. In addition, the assumption of previous simplified models which neglect the charge carriers in Gauss' s law is discussed, showing that this assumption has a little influence on the startup state when the doping concentration is smaller than 10~(21) m~(-3).This suggests that the screening effect of the carriers on the polarized electric field is much reduced in this situation, and that the state is gradually transforming into a pure piezoelectric state. Nevertheless, the carriers can provide a damping effect, which means that the previous simplified models do not sufficiently describe the turning-off state. The numerical results show that the present study has referential value with respect to the design of newly multifunctional PS devices.     

三环己基锡邻(二茂铁甲酰基)苯甲酸酯配位聚合物的微波固相合成、晶体结构及性能

在微波辐射下, 邻二茂铁甲酰基苯甲酸与三环己基氢氧化锡反应, 合成了结构新颖的含铁锡多核配合物. 紫外光谱、 红外光谱、 核磁共振谱、 元素分析和X射线晶体衍射表征结果表明, 配合物的中心锡与配基原子形成五配位畸变三角双锥构型, 通过配体的羧基氧和羰基氧原子分别与锡原子连接形成一维链配位聚合物. 热分析结果表明, 配合物在163 ℃以下具有较好的热稳定性. 其溶液在电极上能准可逆电子转移, 对人体细胞HT-29, MCF-7, HepG2, KB和A549的体外抗癌活性均高于对照药顺铂, 具有潜在应用价值.     

Type I quasi-phase-matched blue second harmonic generation with different polarizations in periodically poled LiNbO3

First-order type I quasi-phase-matched (QPM) blue second-harmonic generation was demonstrated in periodically poled LiNbO₃ with period of 14.5 μm using d₃₁. 52 μJ of harmonic blue light at 0.473 μm was generated pumped by 114 μJ 35 ps pulse laser at 0.946 μm at 150 °C with a conversion efficiency of 45.6%. The average conversion efficiencies of 41.3% and 19% were also obtained at 150 °C, respectively, in the conventional first- and third-order QPM blue second-harmonic generation at 0.473 μm. The temperature acceptance bandwidths of 20 mm length periodically poled LiNbO₃ with first-order grating periods of 14.5 and 4.5 μm are 2.0 and 0.9 °C, respectively. The larger acceptance bandwidths and grating period for than those for enhance the frequency conversion efficiency, which shows the polarization dependence of quasi-phase matching.     

Tunable Smart Surface of Gold Nanoparticles Achieved by Light‐Controlled Molecular Recognition Effection

Thermosensitive poly(N‐isopropylacrylamide) (PNIPAm)‐coated gold nanoparticles (AuNPs) were prepared by self‐assembly of the azobenzene‐terminated PNIPAm on the surface of the α‐cyclodextrin (α‐CD)‐capped AuNPs via the host–guest molecular recognition between α‐CD and azobenzene. Reversible attachment–detachment of azobenzene‐terminated PNIPAm on the surface of α‐CD‐capped AuNPs was achieved when subjected to visible and UV light irradiation alternately, which endowed thermosensitive AuNPs with tunable smart properties.

     

Polarization-dependent coupling in a 1x4 waveguide array in lithium niobate fabricated by femtosecond pulses

We demonstrate a 1×4 waveguide array produced by an IR femtosecond laser in z-cut lithium niobate (LiNbO₃). The polarization dependence of light coupling in this waveguide structure is experimentally investigated. The coupling constants of the waveguide array are obtained by measuring the ratio of output power of each waveguide for extraordinary rays and ordinary rays, and the variation of coupled power in each waveguide as a function of the waveguide length are demonstrated. PACS 42.65.Re; 77.84.Dy; 42.82.Et     

Magnetoresistance and Kondo Effect in Nodal-Line Semimetal VAs_2

We performed calculations of the electronic band structure and the Fermi surface,measured the longitudinal resistivity ρxx(T,H),Hall resistivity ρxy(T,H),and magnetic susceptibility as a function of temperature at various magnetic fields for VAs₂ with a monoclinic crystal structure.The band structure calculations show that VAs₂ is a nodal-line semimetal when spin-orbit coupling is ignored.The emergence of a minimum at around11 K in ρxx(T) measured at H=0 demonstrates that some additional magnetic impurities(V⁴⁺,S=1/2)exist in VAs₂ single crystals,inducing Kondo scattering,evidenced by both the fitting of ρxx(T) data and the susceptibility measurements.It is found that a large positive magnetoresistance(MR) reaching 649% at 10 K and 9 T,its nearly quadratic field dependence,and a field-induced up-turn behavior of ρxx(T) also emerge in VAs₂,although MR is not so large due to the existence of additional scattering compared with other topological nontrivial/trivial semimetals.The observed properties are attributed to a perfect charge-carrier compensation,which is evidenced by both the calculations relying on the Fermi surface and the Hall resistivity measurements.These results indicate that the compounds containing V(3d³4s²) element can be as a platform for studying the influence of magnetic impurities to the topological properties.     

WO3基气敏传感器*

气敏传感器已在生物、化学、航空、军事等领域获得了广泛的应用。鉴于WO₃基气敏传感器是检测H₂S、NO_x、O₃和NH₃等气体最有前景的新型氧化物气敏传感器之一,本文以不同的敏感气体为分类依据系统阐述了近年来WO₃基气敏传感器的研究进展,详细探讨了制备方法及贵金属掺杂对上述各种气体气敏性能的影响,并指出了目前WO₃基气敏传感器在研究过程中存在的问题。