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41.
Rui Hong Yi-Xin Jiang Jie Leng Ming-Jin Liu Kai-Zhi Shen Qiang Fu Jie Zhang 《高分子科学》2021,39(6):756-769
General-purpose plastics with high strength and toughness have been in great demand for structural engineering applications. To achieve the reinforcement and broaden the application scope of high-density polyethylene(HDPE), multi-flow vibration injection molding(MFVIM) and ultrahigh molecular weight polyethylene(UHMWPE) are synergistically employed in this work. Herein, the MFVIM has better shear layer control ability and higher fabrication advantage for complex parts than other analogous novel injection molding technologies reported.The reinforcing effect of various filling times and UHMWPE contents as well as the corresponding microstructure evolution are investigated.When 5 wt% UHMWPE is added, MFVIM process with six flow times thickens the shear layer to the whole thickness. The tensile strength and modulus increase to 2.14 and 1.39 times, respectively, compared to neat HDPE on the premise of remaining 70% impact strength. Structural characterizations indicate that the enhancement is attributed to the improvement of shish-kebab content and lamellae compactness, as well as related to the corresponding size distributions of undissolved UHMWPE particles. This novel injection molding technology with great industrial prospects provides a facile and effective strategy to broaden the engineering applications of HDPE materials. Besides, excessive UHMWPE may impair the synergistic enhancement effect, which is also reasonably explained. 相似文献
42.
43.
Determination of phthalate esters in liquor samples by vortex‐assisted surfactant‐enhanced‐emulsification liquid–liquid microextraction followed by GC–MS
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Geng Leng Wenjin Chen Mingfang Zhang Fang Huang Qiming Cao 《Journal of separation science》2014,37(6):684-690
A novel method using vortex‐assisted surfactant‐enhanced‐emulsification liquid–liquid microextraction has been developed for the extraction of phthalate esters (PAEs) in Chinese liquor samples prior to analysis by GC–MS. In the proposed method, a high‐density extraction solvent (carbon tetrachloride) was dispersed into samples with the aid of a surfactant (Triton X‐100) and vortex agitation, resulting in a short extraction equilibrium (30 s). After centrifugation, a single microdrop of solvent was easily collected for GC–MS analysis. Key factors that affected the extraction efficiency were optimized. Under the optimum conditions, linearity was found in the range from 0.05 to 50 μg/L. Coefficients of determination varied from 0.9938 to 0.9971. LODs, based on an S/N of 3, ranged from 4.9 to 13 ng/L. Enrichment factors varied from 140 to 184. Reproducibility and recoveries were assessed by testing a series of three liquor samples that were spiked with different concentration levels. Finally, the proposed method was successfully applied to the determination of PAEs in 16 Chinese liquor samples. In this work, high‐density‐solvent vortex‐assisted surfactant‐enhanced‐emulsification liquid–liquid microextraction was applied for the first time for the extraction of PAEs in Chinese liquor samples and was proved to be simple, rapid, and sensitive. 相似文献
44.
Yueqin Yu Suhua Li Caifeng Leng Taizai Xiong Kunshan Yuan Shaopeng Yan Fuqiang Jia 《Polymer Science Series B》2014,56(2):191-197
Block copolymers comprising thermosensitive poly(N-isopropylacrylamide) (PNIPAM) and hydrophobic poly(n-butyl acrylate) (PBA) blocks, were synthesized using the reversible addition-fragmentation chain transfer polymerization (RAFT), their thermosensitive behavior was studied by ultraviolet spectrophotometer (UV) and dynamic light scattering (DLS). The lower critical solution temperature (LCST) was strongly correlated to the hydrophobic/hydrophilic ratio of the copolymers. Their micellization and self-assembly behavior in dilute aqueous solution were studied by surface tension (SFT), DLS and TEM. The resulting block copolymers reversibly formed or deformed micellar assemblies during their LCSTs. The critical micelle concentration (CMC) was controlled by the composition of PBA and PNIPAM, indicating the successful formation of the block copolymers. 相似文献
45.
Howard Yi Fan Sim Jaslyn Ru Ting Chen Charlynn Sher Lin Koh Dr. Hiang Kwee Lee Dr. Xuemei Han Gia Chuong Phan-Quang Jing Yi Pang Dr. Chee Leng Lay Dr. Srikanth Pedireddy Dr. In Yee Phang Prof. Edwin Kok Lee Yeow Prof. Xing Yi Ling 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(39):17145-17151
The electrochemical nitrogen reduction reaction (NRR) offers a sustainable solution towards ammonia production but suffers poor reaction performance owing to preferential catalyst–H formation and the consequential hydrogen evolution reaction (HER). Now, the Pt/Au electrocatalyst d-band structure is electronically modified using zeolitic imidazole framework (ZIF) to achieve a Faradaic efficiency (FE) of >44 % with high ammonia yield rate of >161 μg mgcat−1 h−1 under ambient conditions. The strategy lowers electrocatalyst d-band position to weaken H adsorption and concurrently creates electron-deficient sites to kinetically drive NRR by promoting catalyst–N2 interaction. The ZIF coating on the electrocatalyst doubles as a hydrophobic layer to suppress HER, further improving FE by >44-fold compared to without ZIF (ca. 1 %). The Pt/Au-NZIF interaction is key to enable strong N2 adsorption over H atom. 相似文献
46.
Prof. Dr. Jun-Long Li Yan-Qing Liu Wen-Lin Zou Rong Zeng Xiang Zhang Dr. Yue Liu Prof. Dr. Bo Han Yu He Hai-Jun Leng Prof. Dr. Qing-Zhu Li 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(5):1879-1886
Fluorinated ketones are widely prevalent in numerous biologically interesting molecules, and the development of novel transformations to access these structures is an important task in organic synthesis. Herein, we report the multicomponent radical acylfluoroalkylation of a variety of olefins in the presence of various commercially available aromatic aldehydes and fluoroalkyl reagents through N-heterocyclic carbene organocatalysis. With this protocol, over 120 examples of functionalized ketones with diverse fluorine substituents have been synthesized in up to 99 % yield with complete regioselectivity. The generality of this catalytic strategy was further highlighted by its successful application in the late-stage functionalization of pharmaceutical skeletons. Excellent diastereoselectivity could be achieved in the reactions forging multiple stereocenters. In addition, preliminary results have been achieved on the catalytic asymmetric variant of the olefin difunctionalization process. 相似文献
47.
Pan Li Shijun Xu Chunyang Yu Zi‐Ying Li Jianping Xu Zi‐Mu Li Lingyi Zou Xuebing Leng Shan Gao Zhiqiang Liu Xiaoyun Liu Shaodong Zhang 《Angewandte Chemie (International ed. in English)》2020,59(18):7113-7121
Considerable efforts have been made to increase the topological complexity of mechanically interlocked molecules over the years. Three‐dimensional catenated structures composed of two or several (usually symmetrical) cages are one representative example. However, owing to the lack of an efficient universal synthetic strategy, interlocked structures made up of dissymmetric cages are relatively rare. Since the space volume of the inner cavity of an interlocked structure is smaller than that outside it, we developed a novel synthetic approach with the voluminous reductant NaBH(OAc)3 that discriminates this space difference, and therefore selectively reduces the outer surface of a catenated dimer composed of two symmetric cages, thus yielding the corresponding catenane with dissymmetric cages. Insight into the template effect that facilitates the catenation of cages was provided by computational and experimental techniques. 相似文献
48.
Jinhui Yang Juan Zhao Junqiang Song Jianping Wu Chengwu Zhao Hongze Leng 《Entropy (Basel, Switzerland)》2022,24(3)
The prediction of chaotic time series systems has remained a challenging problem in recent decades. A hybrid method using Hankel Alternative View Of Koopman (HAVOK) analysis and machine learning (HAVOK-ML) is developed to predict chaotic time series. HAVOK-ML simulates the time series by reconstructing a closed linear model so as to achieve the purpose of prediction. It decomposes chaotic dynamics into intermittently forced linear systems by HAVOK analysis and estimates the external intermittently forcing term using machine learning. The prediction performance evaluations confirm that the proposed method has superior forecasting skills compared with existing prediction methods. 相似文献
49.
为克服机器学习方法在油藏单井产量预测中的过拟合问题,提高油田生产中的产量预测精度,提出一种基于条件生成式对抗网络(CGAN)的油藏单井产量预测模型。该模型使用长短期记忆、全连接等基础神经网络,构建生成和判别网络模型。生成网络模型以产量影响因素为条件输入,生成预测产量数据,利用对数损失函数评价预测数据与真实数据之间的偏差,通过条件生成式对抗网络的博弈训练,并结合贝叶斯超参数优化算法,优化模型结构,综合提高模型的泛化能力。基于Eclipse数值模拟软件建立同一井网条件下不同地质和生产条件下的油藏单井产量数据库,以地质与生产条件等产量影响因素作为模型的条件输入,进行油藏单井产量预测。结果表明:与全连接神经网络(FCNN)、随机森林(RF)以及长短期记忆神经网络(LSTM)模型的预测结果相比,CGAN模型在测试集上的平均绝对百分比误差分别提升了2.59%、 0.81%以及1.72%,并且过拟合比最小(1.027)。说明CGAN降低了机器学习产量预测模型的过拟合程度,提高了模型的泛化能力与预测精度,验证了所提算法的优越性,对指导油田高效开发和保障我国能源战略安全具有重要意义。 相似文献
50.
Zixin Yang Lili Han Qi Yang Xianghe Ren Syed Zaheer Ud Din Xiaoyan Zhang Jiancai Leng Jiabao Zhang Baitao Zhang Kejian Yang Jingliang He Chunlong Li Jun Wang 《中国光学快报(英文版)》2021,(3):64-68
Two-dimensional(2 D) Te nanosheets were successfully fabricated through the liquid-phase exfoliation(LPE) method. The nonlinear optical properties of 2 D Te nanosheets were studied by the open-aperture Z-scan technique. Furthermore, the continuous wave mode-locked Nd:YVO_4 laser was successfully realized by using 2 D Te as a saturable absorber(SA) for the first time, to the best of our knowledge. Ultrashort pulses as short as 5.8 ps were obtained at 1064.3 nm with an output power of 851 m W. This primary investigation indicates that the 2 D Te SA is a promising photonic device in the fields of ultrafast solid-state lasers. 相似文献