Enzymatic oxidative polymerization of 4,4′-biphenyldiol was performed in an aqueous organic solvent using horseradish peroxidase as catalyst. In the polymerization using a mixture of 1,4-dioxane and phosphate buffer (pH 7.0) (80:20 vol-%) as solvent, the monomer was quantitatively consumed to give powdery polymeric materials in a high yield. The resulting polymer is soluble in polar solvents such as N,N-dimethylformamide, dimethyl sulfoxide, and acetone. The molecular weight of the methylated product is 7.3 × 103. The polymer exhibits high thermal stability under nitrogen. 相似文献
Various poly- and oligosaccharides having a well-defined structure have successfully been synthesized via enzymatic polymerization of glycosyl fluoride monomers. All of the reaction proceeded under perfect control of regio- and stereochemistry. The relative direction of the synthetic cellulose (parallel or antiparallel) could be controlled in vitro in the enzyme-promoted propagation system, and based on these findings, a new concept “allos-selectivity” has been proposed. 相似文献
Optical Review - This paper proposes a method to improve the modulation transfer function (MTF) of aerial images by combining an aerial imaging optical system by retro-reflection with conjugated... 相似文献
The polymerization behavior of phenolic azosulfonates and triazene by means of enzymatic polymerization using horseradish peroxidase was studied. While for the latter one, only oligomerization was observed, sodium 4‐hydroxybenzenediazosulfonate was successfully homopolymerized. The obtained polymer had an average molecular weight of Mn = 3 000 with a polydispersity index of 1.51. This is the first example of a homopolymer bearing an azosulfonate function in every monomer unit.