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排序方式: 共有239条查询结果,搜索用时 31 毫秒
51.
52.
J. L. Bailly S. Banerjee F. Bruyant B. Buschbeck C. Caso H. Dibon B. Epp A. Ferrando F. Fontanelli T. Gemesy A. Gurtu R. Hamatsu Ph. Herquet T. Hirose J. Hrubec Yu. Ivanysherkov E. P. Kistenev N. Khalatyan S. Kitamura T. Kreuzberger V. Kubik P. Lipa P. K. Malhotra M. Markytan I. S. Mittra L. Montanet G. Neuhofer G. Pinter P. Porth R. Raghavan T. Rodrigo J. B. Singh S. Squarcia U. Trevisan K. Takahashi L. A. tikhonova T. Yamagata G. Zholobov J. Zoll S. A. Zotkin NA EHS - RCBC Collaboration 《Zeitschrift fur Physik C Particles and Fields》1988,40(1):13-24
Two particle correlations of hadrons produced in 360 GeV/cpp interactions are investigated in the transverse plane and in rapidity. The data were obtained at the European hybrid spectrometer equipped with a rapid cycling bubble chamber. The observed transverse and rapidity correlations are compared with the one string LUND-and a two string dual parton-model. These models predict in general stronger correlations in the transverse plane and much weaker correlations in rapidity than found in the data. The LUND-FRITIOF-and multichain dual parton models provide a better reproduction of the data, although the agreement is not yet satisfactory. Only the UA5 cluster model GENCL shows agreement with the data. 相似文献
53.
Kenji Yamagata Fumi Okabe Hiroshi Maruoka Yoshinobu Tagawa 《Journal of heterocyclic chemistry》2005,42(4):543-549
The reaction of 2‐acylamino‐4,5‐dihydro‐3‐furancarbonitriles 1 with sodium iodide in N,N‐dimethyl‐formamide gave the corresponding 1‐acyl‐2‐oxo‐3‐pyrrolidinecarbonitriles 2 in good yields. Successive treatment of 1 with titanium(IV) chloride and potassium carbonate resulted in the formation of N‐acyl‐1‐cyanocyclopropanecarboxamides 4 . The same compounds 2 were also obtained by treatment of 4 with sodium iodide. The starting compounds 1 were synthesized by the reaction of 2‐amino‐4,5‐dihydro‐3‐furan‐carbonitrile with acyl chlorides in pyridine. 相似文献
54.
Morita H Ishioka N Takatsu H Shinzato T Obara Y Nakahata N Kobayashi J 《Organic letters》2005,7(3):459-462
[structure: see text] Two novel alkaloids with an unprecedented fused-pentacyclic skeleton, daphmanidins C (1) and D (2), have been isolated from the leaves of Daphniphyllum teijsmanii, and the structures were elucidated on the basis of spectroscopic data. The relative stereochemistry of 1 and 2 was assigned by combination of NOESY correlations and a simulation analysis. Daphmanidin C (1) elevated activity of NGF biosynthesis. 相似文献
55.
Itoh K Nishizawa T Yamagata J Fujii M Osaka N Kudryashov I 《The journal of physical chemistry. B》2005,109(1):264-270
Raman microspectroscopy was applied to study the polymerization kinetics of the Langmuir-Blodgett (LB) films of 10,12-pentacosadiynoic acid (DA) adsorbed on surface enhanced Raman scattering (SERS) active Ag island films. A two-dimensional (2D) Raman microscopic image measured at 1520 cm(-1) exhibits bright and dim spots with the diameter of several hundred nanometers. Raman microscopic spectra, measured by defocusing the excitation laser light (532 nm, diameter of ca. 10 mum) on the samples at room temperature, proved the occurrence of the surface processes consisting of the formation of polydiacetylene (PDA) in the blue phase, its conversion to the red phase, and subsequent bleaching. These reactions were negligible under the same condition for the DA-LB films prepared on a smooth (i.e., SERS-inactive) Ag film, indicating that the 532-nm-induced polymerization and the bleaching process are enhanced by the SERS-active substrates. At low temperatures below -50 degrees C, the Raman microscopic measurements proved the formation of the blue phase and its conversion to the red phase with much lower reaction rates compared to the corresponding rates at room temperature. The bleaching, however, was much suppressed at the low temperatures. The kinetic analyses of the formation of the blue phase and its conversion to the red phase were performed by using the intensity changes of the Raman bands due to the blue (1477 cm(-1)) and red (1517 cm(-1)) phases as a function of the irradiation time. The results strongly suggested the existence of at least two processes taking place simultaneously on the SERS-active substrates; that is, one of the processes is a sequential reaction, DA-monomers --> PDA in the blue phase --> PDA in the red phase, and the other is another sequential reaction, DA-monomers --> PDA in the red phase --> degradation species (probably amorphous carbon). Thus, even at the low temperatures, there occurs the surface reaction consisting of the formation of PDA and its degradation. The reaction can be ascribed to a process taking place at the highly SERS-active site, which gives the bright spot (so-called "hot spot") on the 2D Raman image, as proved by the confocal Raman microscopic measurement in the following paper. 相似文献
56.
57.
Y. Arimoto N. Shimakura K. Yonehara T. Yamagata M. Tanaka 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,8(3):305-308
The spin-exchange cross-section, , was measured for a 6.33 keV/amu He ion incident on a polarized Rb atom. The result is cm2, which is unexpectedly an order of magnitude smaller than the theoretical value cm2 evaluated by the semiclassical impact parameter method assuming formation of a single molecular state.
Received 11 September 1999 and Received in final form 28 December 1999 相似文献
58.
Dr. Takeshi Fujita Yutaro Kobayashi Dr. Ikko Takahashi Ryutaro Morioka Dr. Tomohiro Ichitsuka Prof. Dr. Junji Ichikawa 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(2):e202103643
Nickel-catalyzed reductive cross-coupling of allylic difluorides with aryl iodides was achieved via allylic C−F bond activation. Based on this protocol, a series of γ-arylated monofluoroalkenes were synthesized in moderate to high yields with high Z-selectivities. Mechanistic studies suggest that the C−I bonds of the aryl iodides and the C−F bonds of the allylic difluorides were cleaved via oxidative addition and β-fluorine elimination, respectively, where the oxidative addition of less reactive C−F bonds was avoided to permit their transformation. 相似文献
59.
Tsuneo Okubo Daisuke Suzuki Tomoyo Yamagata Akihiro Katsuno Masashi Mizutani Hiroshi Kimura Akira Tsuchida 《Colloid and polymer science》2011,289(7):807-816
Drying dissipative patterns were observed at 25 °C, 33 °C, and 45 °C on a cover glass, a watch glass, and a Petri glass dish
during the course of dryness of colloidal crystals of the thermo-sensitive gels of poly(N-isopropylacrylamide) (PNIPA). Two kinds of broad rings, i.e., transparent ring at the outside edge and the ring in the inner
area from the edge, were observed. Sizes of the former were the same as those of the initial liquids irrespective of gel concentration,
whereas sizes of the latter decreased as gel concentration decreased. These broad rings were composed mainly of the monomeric
and the agglomerated gel particles, respectively. Formation of the monodispersed agglomerated particles and their ordered
arrays in the inner area of the dried film were observed especially on a Petri glass dish and a watch glass. The important
role of the electrical double layers formed around the agglomerated particles is supported for the ordering of the agglomerated
particles. The essential differences in the drying patterns between PNIPA gel spheres and the typical colloidal particles
did not appear. 相似文献
60.