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排序方式: 共有1080条查询结果,搜索用时 12 毫秒
101.
Yasukazu Sugiyama Kento Yamada Daiki Kaneko Yuya Kusagawa Dr. Toshitaka Okamura Prof. Dr. Takaaki Sato 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2024,136(6):e202317290
A reductive (3+2) annulation of lactams through iridium-catalyzed hydrosilylation and photoredox coupling with α-bromoacetic acid was developed. The iridium-catalyzed hydrosilylation of the lactam carbonyl group and subsequent elimination provide a transient cyclic enamine, which undergoes iridium-catalyzed photoredox coupling with α-bromoacetic acid in a one-pot process. The developed conditions show high functional-group tolerance and provide cyclic N,O-acetals containing a quaternary carbon center. The resulting N,O-acetals undergo a variety of acid-mediated nucleophilic addition reactions via iminium ions to give substituted cyclic amines. The developed sequence including reductive (3+2) annulation and acid-mediated nucleophilic addition was successfully applied to the four-step total synthesis of (±)-eburnamonine. 相似文献
102.
103.
Hiroshi Yabuno Hiroyuki Kaneko Masaharu Kuroda Takeshi Kobayashi 《Nonlinear dynamics》2008,52(1-2):137-149
A technique for dimensional reduction of nonlinear delay differential equations (DDEs) with time-periodic coefficients is
presented. The DDEs considered here have a canonical form with at most cubic nonlinearities and periodic coefficients. The
nonlinear terms are multiplied by a perturbation parameter. Perturbation expansion converts the nonlinear response problem
into solutions of a series of nonhomogeneous linear ordinary differential equations (ODEs) with time-periodic coefficients.
One set of linear nonhomogeneous ODEs is solved for each power of the perturbation parameter. Each ODE is solved by a Chebyshev
spectral collocation method. Thus we compute a finite approximation to the nonlinear infinite-dimensional map for the DDE.
The linear part of the map is the monodromy operator whose eigenvalues characterize stability. Dimensional reduction on the
map is then carried out. In the case of critical eigenvalues, this corresponds to center manifold reduction, while for the
noncritical case resonance conditions are derived. The accuracy of the nonlinear Chebyshev collocation map is demonstrated
by finding the solution of a nonlinear delayed Mathieu equation and then a milling model via the method of steps. Center manifold
reduction is illustrated via a single inverted pendulum including both a periodic retarded follower force and a nonlinear
restoring force. In this example, the amplitude of the limit cycle associated with a flip bifurcation is found analytically
and compared to that obtained from direct numerical simulation. The method of this paper is shown by example to be applicable
to systems with strong parametric excitations. 相似文献
104.
Katayama M Matsuda Y Kobayashi K Kaneko S Ishikawa H 《Biomedical chromatography : BMC》2006,20(8):800-805
A new, simple and sensitive pre-column fluorescence derivatization high-performance liquid chromatographic method for the determination of the oxidative DNA stress marker, 8-oxo-7,8-dihydro-2'-deoxyguanosine, was developed. Solid-phase extraction using an Oasis HLB cartridge avoided troublesome sample preparation steps, interference from charged species and frequent and essential electrode maintenance in electrochemical procedures. 8-Oxo-7,8-dihydro-2'-deoxyguanosine and other guanine compounds were selectively derivatized with glyoxal reagents (phenylglyoxal, 3,4-methylenedioxyglyoxal, 2-naphtylglyoxal and 6-methoxynaphthylglyoxal) at 40-60 degrees C. Derivatization with 6-methoxynaphthylglyoxal at 40 degrees C for 30 min gave the strongest fluorescence product. The fluorescence derivatives from reaction with 6-methoxynaphthylglyoxal were separated on a Capcell Pak C18 SG 120A column (4.6 mm i.d. x 150 mm, 5 microm) with acetonitrile-5 mM phosphate buffer (pH 6.0; 3:7, v/v) as mobile phase. The detection wavelength of the fluorescence derivative of 8-oxo-7,8-dihydro-2'-deoxyguanosine was lambda(ex) 400 nm and lambda(em) 510 nm. The detection limit of 8-oxo-7,8-dihydro-2'-deoxyguanosine was 1 ng/mL using 50 mL of urine. The calibration graphs were linear up to 30 microg/mL for 8-oxo-7,8-dihydro-2'-deoxyguanosine. The relative standard deviation of 20 ng/mL of 8-oxo-7,8-dihydro-2'-deoxyguanosine was 7.0%. The proposed method was compared with the enzymatic ELISA 8-oxo-7,8-dihydro-2'-deoxyguanosine analysis method (8-OH-dG Check, JaICA, Shizuoka, Japan). The correlation coefficient was 0.79 (n = 20) and y = 0.85x + 5.34. The proposed method was applied to the monitoring of 8-oxo-7,8-dihydro-2'-deoxyguanosine in urine from male heavy smokers. 相似文献
105.
106.
107.
When perfect recall is not satisfied, the informational contents of mixed and behavior strategies differ and are more than what the information partition describes. First, we consider two kinds of additional information strategies may carry, and show that such information leads to theperfect recall refinement of a given information partition. This does not, however, imply that the strategies compensate fully for the lack of perfect recall. We give a necessary and sufficient condition on an information partition, calledA-loss, for the informational content of mixed strategies to fully compensate for the lack of perfect recall. The informational content of behavior strategies never fully compensates. 相似文献
108.
The behavior of tip vortex in an axial fan without casing wall (called open axial fan) was discussed and analyzed. The velocity measurement was performed by using two-components Laser Doppler Velocimetry (LDV) system. The detailed velocity and vorticity distribution inside blade passage and downstream of rotor were obtained. Thus the structure of tip vortex and its behavior were graphically visualized by experimental fluid dynamics (EFD). The tip vortex flow trace was indicated with the calculation of vorticity. As a result, it was found that tip vortex was generated at blade tip region near leading edge and it extended to downstream of blade exit with its core tending inward to hub direction. In addition, leading edge vortex was also found at the forepart of the experimental open fan. 相似文献
109.
Bungo Ochiai Jun‐ichi Nakayama Masayuki Mashiko Yoshiro Kaneko Tomomi Nagasawa Takeshi Endo 《Journal of polymer science. Part A, Polymer chemistry》2005,43(23):5899-5905
This article describes the polyaddition of bifunctional five‐membered cyclic carbonates and diethylenetriamine. The polyaddition proceeded via the selective addition of the primary amino group to the cyclic carbonates to give poly(hydroxyurethane)s bearing a secondary amine structure in the main chain. The resulting poly (hydroxyurethane) having a secondary amine structure was crosslinked by a reaction with a bifunctional dithiocarbonate to give a networked poly(hydroxyurethane–mercaptothiourethane). © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 5899–5905, 2005 相似文献
110.
Hideaki Kaneko Richard D. Noren Peter A. Padilla 《Journal of Computational and Applied Mathematics》1997,80(2):351-349
In this paper, we analyse the iterated collocation method for Hammerstein equations with smooth and weakly singular kernels. The paper expands the study which began in [16] concerning the superconvergence of the iterated Galerkin method for Hammerstein equations. We obtain in this paper a similar superconvergence result for the iterated collocation method for Hammerstein equations. We also discuss the discrete collocation method for weakly singular Hammerstein equations. Some discrete collocation methods for Hammerstein equations with smooth kernels were given previously in [3, 18]. 相似文献