全文获取类型
收费全文 | 918篇 |
免费 | 78篇 |
专业分类
化学 | 765篇 |
晶体学 | 6篇 |
力学 | 3篇 |
数学 | 16篇 |
物理学 | 206篇 |
出版年
2023年 | 15篇 |
2022年 | 16篇 |
2021年 | 21篇 |
2020年 | 22篇 |
2019年 | 30篇 |
2018年 | 25篇 |
2017年 | 22篇 |
2016年 | 31篇 |
2015年 | 32篇 |
2014年 | 41篇 |
2013年 | 35篇 |
2012年 | 64篇 |
2011年 | 64篇 |
2010年 | 31篇 |
2009年 | 29篇 |
2008年 | 63篇 |
2007年 | 43篇 |
2006年 | 49篇 |
2005年 | 44篇 |
2004年 | 34篇 |
2003年 | 24篇 |
2002年 | 27篇 |
2001年 | 30篇 |
2000年 | 19篇 |
1999年 | 9篇 |
1998年 | 3篇 |
1997年 | 5篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 5篇 |
1993年 | 8篇 |
1992年 | 8篇 |
1991年 | 6篇 |
1990年 | 8篇 |
1989年 | 4篇 |
1988年 | 7篇 |
1987年 | 5篇 |
1986年 | 8篇 |
1985年 | 25篇 |
1984年 | 10篇 |
1983年 | 5篇 |
1982年 | 9篇 |
1981年 | 7篇 |
1980年 | 4篇 |
1979年 | 11篇 |
1978年 | 3篇 |
1977年 | 3篇 |
1975年 | 3篇 |
1974年 | 5篇 |
1973年 | 7篇 |
排序方式: 共有996条查询结果,搜索用时 15 毫秒
91.
Kensuke Okusa Yuki Suita Yukio Otsuka Mineo Tahara Tohru Ikegami Nobuo Tanaka Masayoshi Ohira Masakazu Takahashi 《Journal of separation science》2010,33(3):348-358
The effectiveness of several basic compounds for testing silica‐based stationary phases was reviewed by applying them to recent columns for reversed‐phase HPLC. Most octadecylsilylated (C18) stationary phases, prepared as a base‐deactivated material from high‐purity silica gel with endcapping, provided excellent peak shape and column efficiency for the bases including benzylamine and amitriptyline that once caused problems and were subsequently employed for testing silanol activities. However, a cyclic tertiary amine, dextrometorphan, was eluted as an acceptable peak from only a few columns at neutral pH. Such a more sensitive probe is expected to contribute to further improvement of the stationary phase for reversed‐phase HPLC. 相似文献
92.
Yuta Marushima Yuri Uchiumi Kenichi Ogu Akiko Hori 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(8):o406-o409
Two C2‐symmetric meso‐alkynylporphyrins, namely 5,15‐bis[(4‐butyl‐2,3,5,6‐tetrafluorophenyl)ethynyl]‐10,20‐dipropylporphyrin, C50H42F8N4, (I), and 5,15‐bis[(4‐butylphenyl)ethynyl]‐10,20‐dipropylporphyrin, C50H50N4, (II), show remarkable π–π stacking that forms columns of porphyrin centers. The tetrafluorophenylene moieties in (I) show intermolecular interactions with each other through the F atoms, forming one‐dimensional ribbons. No significant π–π interactions are observed in the plane of the phenylene and tetrafluorophenylene moieties in either (I) or (II). The molecules of both compounds lie about inversion centers. 相似文献
93.
Matsuda H Nakamura S Fujimoto K Moriuchi R Kimura Y Ikoma N Hata Y Muraoka O Yoshikawa M 《Chemical & pharmaceutical bulletin》2010,58(12):1617-1621
The methanolic extract and its 1-butanol-soluble fraction from the flower buds of Camellia sasanqua THUNB. were found to show inhibitory activities on the release of β-hexosaminidase from rat basophile leukemia (RBL-2H3) cells. From the 1-butanol-soluble fraction, five new acylated oleanane-type triterpene saponins, sasanquasaponins I-V, were isolated together with a known saponin and their chemical structures were elucidated on the basis of chemical and physicochemical evidence. The principal saponin constituents, sasanquasaponins I-III, with an acyl group at the 22-position of the aglycon part showed the inhibitory effects on the release of β-hexosaminidase and some structure-activity relationships were reported. 相似文献
94.
We propose a fundamental interconnection method using a polarization alignment system for waveguides having different spatial
modes. In addition, as an example for the verification of the fundamental operation, we demonstrate an interconnection between
a photonic crystal fiber and a laser that have obviously different spatial modes. The polarization alignment system operates
synergistically with a self-written waveguide formed with a double phaseconjugate mirror. This technique enables us to interconnect
a photonic crystal fiber with a laser source without complicated and time-consuming optical alignment. In this method, although
it is not necessary to perform an external control for interconnection, the waveguide most suitable for connection is formed
autonomously in a Sn2P2S6:Sb crystal developed for this purpose. There was a marked reduction in the polarization dependence of coupling efficiency,
compared with that observed using a stand-alone double phase-conjugate mirror. 相似文献
95.
We give a formula for the Fourier coefficients of the image of the Saito-Kurokawa lifting over a totally real number field $K$ , and we prove the image of the lifting satisfies a generalization of the Maass relation. We also give an explicit form of a Siegel series of degree 2 for any finite extension of ${\mathbb {Q}}_p$ . 相似文献
96.
97.
Hiroshi Yamaguchi Xiaodong Niu Xinrong Zhang Yuta Ito 《ournal of non Newtonian Fluid Mechanics》2010,165(7-8):385-393
An experimental study investigated the effects of glass fiber suspensions on the onset of instability in the non-Newtonian fluid flow in the concentric spherical gaps between an inner rotating hemisphere and an outer stationary whole sphere. Glass fibers with different aspect ratios were mixed with a macromolecule polymeric solution to obtain different suspension fluids. For comparison, the pure macromolecule polymeric fluid was also investigated. The torques on the inner sphere were measured for various spherical gaps and various rotational Reynolds numbers. The onset of instability of the polymeric fluid flows was delayed by adding glass fibers to the polymeric solution for all tested gap ratios. 相似文献
98.
Shuhei Kudo Emiko Otsuka Atsushi Suzuki 《Journal of Polymer Science.Polymer Physics》2010,48(18):1978-1986
We report the swelling behavior of chemically crosslinked polyvinyl alcohol (PVA) gels with different degrees of hydrolysis in water, several organic solvents, and their mixed solvents. The gels were dried after gelation and were put into their respective solvents. The gel volume in pure water decreased with increasing temperatures, and the total changes increased with decreasing degrees of hydrolysis. The swelling ratio depends on the solvent and its concentration. In the cases of mixed solvents of methanol–water, ethanol–water, and acetone–water, the gels shrank continuously with increasing concentrations of solvents and reached the collapsed state in the pure organic solvent. In the case of dimethyl sulfoxide (DMSO), on the other hand, the gels shrunk, swelled, and finally reached the swollen state in pure DMSO. Results of measurements using Fourier Transform infrared spectroscopy (FTIR) and X‐ray diffraction (XRD) suggested that crosslinks and microcrystallites were formed due to hydrogen bonds during the drying process after gelation. The hydrogen bonds were partly destroyed in a rich solvent, but the residual hydrogen bonds had an essential role in determining the swelling behavior in a poor solvent. The swelling behavior and the possible phase transition of the present system are discussed in terms of the solubility of polymers with different degrees of hydrolysis in given mixed solvents and in terms of the formation and destruction of physical crosslinks in the chemical PVA gels. © 2010 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 48: 1978–1986, 2010 相似文献
99.
100.
Chiral separations of 1-aminoindan (AI) by cyclodextrin electrokinetic chromatography (CDEKC) were investigated on microfluidic quartz chips. By using a microchip electrophoresis (MCE) instrument equipped with a linear-imaging UV detector, the separation process of the enantiomeric compounds was observed. When sulfated beta-cyclodextrin was employed as a chiral selector, the baseline separation of AI could be achieved within 1 min with a high repeatability. The relative standard deviation of the migration time was less than 6%. The fastest separation was achieved in 14 s, utilizing a separation length of only 6.1 mm. These results show that the MCE analysis employing a linear imaging UV detector has a significant potential for fast chiral analysis. 相似文献