全文获取类型
收费全文 | 548篇 |
免费 | 45篇 |
专业分类
化学 | 483篇 |
晶体学 | 6篇 |
力学 | 6篇 |
数学 | 13篇 |
物理学 | 85篇 |
出版年
2024年 | 1篇 |
2023年 | 12篇 |
2022年 | 13篇 |
2021年 | 17篇 |
2020年 | 13篇 |
2019年 | 20篇 |
2018年 | 18篇 |
2017年 | 17篇 |
2016年 | 27篇 |
2015年 | 21篇 |
2014年 | 34篇 |
2013年 | 16篇 |
2012年 | 48篇 |
2011年 | 46篇 |
2010年 | 22篇 |
2009年 | 22篇 |
2008年 | 48篇 |
2007年 | 29篇 |
2006年 | 23篇 |
2005年 | 25篇 |
2004年 | 12篇 |
2003年 | 18篇 |
2002年 | 10篇 |
2001年 | 6篇 |
2000年 | 16篇 |
1999年 | 2篇 |
1998年 | 1篇 |
1996年 | 1篇 |
1993年 | 2篇 |
1992年 | 10篇 |
1991年 | 1篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 2篇 |
1978年 | 3篇 |
1975年 | 2篇 |
1974年 | 5篇 |
1973年 | 3篇 |
1970年 | 1篇 |
1966年 | 1篇 |
排序方式: 共有593条查询结果,搜索用时 0 毫秒
111.
A micelle solution of decyltrimethylammonium bromide (DTAB) was analyzed by electrospray ionization mass spectrometry. Finding an appropriate range of a capillary-skimmer potential was a prerequisite for obtaining a satisfactory spectrum. The mean molecular weight of DTAB aggregates, 10,500, was deduced from a series of mass spectra acquired at different capillary-skimmer potentials. The value was comparable with the micelle weight, previously determined by the light-scattering method. 相似文献
112.
Oh OJ Chang SY Yook CS Yang KS Park SY Nohara T 《Chemical & pharmaceutical bulletin》2000,48(6):879-881
Two 3,4-seco-lupane triterpenoids (1, 2) were isolated from the leaves of Acanthopanax divaricatus var. albeofructus (Araliaceae). Based on the spectroscopic data, the chemical structures of 1 and 2 were characterized as 24-hydroxychiisanogenin and 22alpha-hydroxychiisanogenin, respectively. 1 was a new compound and 2 was isolated for the first time from the natural source, although it had been obtained as an enzymatically hydrolyzed artifact from 22alpha-hydroxychiisanoside. 相似文献
113.
M Endo N Nohara T A Iinuma H Shinoto E Tanaka K Yoshida T Himi A Kagaya A Ogushi S Inoue 《Radioisotopes》1987,36(5):221-226
This paper describes evaluation and correction of count rate characteristics of POSITOLOGICA II, a multi-slice whole body positron emission tomography system. The present study was performed using three phantoms; a 5 cm inner diameter, water-filled lucite cylinder, a 20 cm inner diameter, water-filled lucite cylinder and a chest phantom. After injection of high activity (about 1.85 GBq (50 mCi] of 13N ammonia into each phantom, rates of true coincidence, random coincidence and single photon detections were measured during decay of the isotope through more than two orders of magnitude of activity. At very high levels of activity, count rate characteristics of the system were saturated and limited to 660 kcps of total coincidence rate, which was the sum of rates in on-time and off-time windows, by the FIFO (first-in first-out) output frequency. Below those levels of activity the relationship between count loss and true coincidence rate was not unique but depended on the phantom configurations, suggesting that count loss correction using the above relationship was inadequate for quantitative study. However, the relationship between count loss and single rate was almost independent of the phantom configurations. Thus in conclusion count loss could be corrected using single rate for POSITOLOGICA II. A practical method of count loss correction was also proposed. 相似文献
114.
Procedures are described for the determination of arsenite, arsenate and monomethylarsonic acid in aqueous samples. The arsenicals (after reduction of arsenic to the tervalent state) readily react with 2,3-dimercaptopropanol (BAL) to yield their BAL complexes. The products are extracted with benzene and introduced into a gas Chromatograph equipped with a flame-photometric detector for sulphur. One aliquot of sample is treated with stannous chloride solution and potassium iodide solution to reduce arsenate and monomethylarsonic acid, then BAL is added and the complexes are extracted with benzene. The extract is analysed for total inorganic As plus monomethylarsonic acid. Magnesia mixture and phosphate solution are added to another aliquot to remove arsenate by co-precipitation with magnesium ammonium phosphate. The precipitate is filtered off and arsenite determined in the filtrate. The detection limits are 0.02 ng of As for arsenate and arsenite and 0.04 ng of As for monomethylarsonic acid. 相似文献
115.
A new oleanene glucuronide called melilotus-saponin O2 (1) was isolated together with three known ones (soyasaponin I, astragaloside VIII, wistariasaponin D) from the aerial parts of Melilotus officinalis (L.) Pallas (Leguminosae). The structure of 1 was determined to be 3-O-alpha-L-rhamnopyranosyl-(1-->2)-beta-D-xylopyranosyl- (1-->2)-beta-D-glucuronopyranosyl melilotigenin by spectroscopic and chemical methods. 相似文献
116.
Ben T. Nohara 《Nonlinear dynamics》2007,50(1-2):49-60
In this paper, the author derives the modified Schrödinger equation that governs the envelope created by nearly bichromatic waves, which are defined by the waves whose energy is almost concentrated in two closely approached wavenumbers. The stability of the solution of the modified Schrödinger equation for nearly bichromatic waves on deep water is discussed and the fact that the Benjamin–Feir instability occurs in a condition is shown. Moreover, the solutions of the modified Schrödinger equation for nearly bichromatic waves on deep water are obtained and, in a special case, the solution becomes the standing wave solution is shown. 相似文献
117.
Long-Tao Huang Yuta Kitakawa Kodai Yamada Futa Kamiyama Dr. Masahiro Kojima Dr. Tatsuhiko Yoshino Prof. Dr. Shigeki Matsunaga 《Angewandte Chemie (International ed. in English)》2023,62(29):e202305480
Sulfondiimines are diaza-analogues of sulfones with a chiral sulfur center. Compared to sulfones and sulfoximines, their synthesis and transformations have so far been studied to a lesser extent. Here, we report the enantioselective synthesis of 1,2-benzothiazine 1-imines, i.e., cyclic sulfondiimine derivatives from sulfondiimines and sulfoxonium ylides via C−H alkylation/cyclization reactions. The combination of [Ru(p-cymene)Cl2]2 and a newly developed chiral spiro carboxylic acid is key to achieving high enantioselectivity. 相似文献
118.
Yusuke Hioki Dr. Tatsuya Sato Dr. Toyoki Iwao Junya Ikuma Dr. Atsushi Kawamura Dr. Takayuki Ohyoshi Dr. Yuta Tsunematsu Dr. Masaki Kita 《European journal of organic chemistry》2023,26(12):e202300084
The shell-less herbivorous marine mollusk (sea hare) Aplysia kurodai is known to contain a variety of bioactive substances. While these compounds have been thought to originate from sea algae or their associated microbes, most of their origin and acquisition pathways are still unclear. Six new cytotoxic aplaminone derivatives, bromodopamine-terpenoid hybrid molecules, were isolated from A. kurodai. Among them, isoaplaminone had a reverse prenyl group at the C15 aliphatic chain, which is a rare structural feature from the viewpoint of terpenoid biosynthesis. Investigation for chemical components in A. kurodai and the sea algae collected at several different locations revealed that two major aplaminones were contained in the Laurencia complex species at specific sites. Our chemical and ecological studies provide new insights into the origin of marine alkaloid toxins and their dynamism through the food chain. 相似文献
119.
Hiroshige Ryosuke Goto Satoru Tsunoda Chihiro Ichii Risa Shimizu Shota Otsuka Yuta Makino Kosho Takahashi Hideyo Yokoyama Hideshi 《Journal of inclusion phenomena and macrocyclic chemistry》2022,102(9-10):791-800
Journal of Inclusion Phenomena and Macrocyclic Chemistry - Ketoprofen is a nonsteroidal anti-inflammatory drug used as mohrus tape which causes unwanted photosensitivity due to UV irradiation. In... 相似文献
120.