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41.
Matsuda H Nakamura S Fujimoto K Moriuchi R Kimura Y Ikoma N Hata Y Muraoka O Yoshikawa M 《Chemical & pharmaceutical bulletin》2010,58(12):1617-1621
The methanolic extract and its 1-butanol-soluble fraction from the flower buds of Camellia sasanqua THUNB. were found to show inhibitory activities on the release of β-hexosaminidase from rat basophile leukemia (RBL-2H3) cells. From the 1-butanol-soluble fraction, five new acylated oleanane-type triterpene saponins, sasanquasaponins I-V, were isolated together with a known saponin and their chemical structures were elucidated on the basis of chemical and physicochemical evidence. The principal saponin constituents, sasanquasaponins I-III, with an acyl group at the 22-position of the aglycon part showed the inhibitory effects on the release of β-hexosaminidase and some structure-activity relationships were reported. 相似文献
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We propose a fundamental interconnection method using a polarization alignment system for waveguides having different spatial
modes. In addition, as an example for the verification of the fundamental operation, we demonstrate an interconnection between
a photonic crystal fiber and a laser that have obviously different spatial modes. The polarization alignment system operates
synergistically with a self-written waveguide formed with a double phaseconjugate mirror. This technique enables us to interconnect
a photonic crystal fiber with a laser source without complicated and time-consuming optical alignment. In this method, although
it is not necessary to perform an external control for interconnection, the waveguide most suitable for connection is formed
autonomously in a Sn2P2S6:Sb crystal developed for this purpose. There was a marked reduction in the polarization dependence of coupling efficiency,
compared with that observed using a stand-alone double phase-conjugate mirror. 相似文献
44.
Hiroshi Yamaguchi Xiaodong Niu Xinrong Zhang Yuta Ito 《ournal of non Newtonian Fluid Mechanics》2010,165(7-8):385-393
An experimental study investigated the effects of glass fiber suspensions on the onset of instability in the non-Newtonian fluid flow in the concentric spherical gaps between an inner rotating hemisphere and an outer stationary whole sphere. Glass fibers with different aspect ratios were mixed with a macromolecule polymeric solution to obtain different suspension fluids. For comparison, the pure macromolecule polymeric fluid was also investigated. The torques on the inner sphere were measured for various spherical gaps and various rotational Reynolds numbers. The onset of instability of the polymeric fluid flows was delayed by adding glass fibers to the polymeric solution for all tested gap ratios. 相似文献
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Polymerization of optically active disubstituted acetylene monomers by Pd catalyst bearing bulky phosphine ligand 下载免费PDF全文
Yuta Goto Yu Miyagi Natsuhiro Sano Fumio Sanda 《Journal of polymer science. Part A, Polymer chemistry》2017,55(18):3011-3016
Chloro- and aryl-substituted acetylene monomers having an optically active group were polymerized by a Pd catalyst [(tBu3P)PdMeCl] bearing a bulky phosphine ligand, and by MoCl5 for comparison. The corresponding disubstituted acetylene polymers with Mn's = 2000–19,500 and 6900–10,800 were obtained in 29–83% and 11–62% yields when the Pd and Mo catalysts were used, respectively. The formation of polyacetylenes, poly[(R)- 1p ], poly[(R)- 1m ], and poly[(S)- 2p ] were confirmed by SEC and the presence of a Raman scattering peak based on the alternating double bonds of the main chain. Pd-based poly[(R)- 1m ] exhibited CD signals around 350 nm assignable to a certain secondary structure, while Mo-based poly[(R)- 1m ] did not. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2017 , 55, 3011–3016 相似文献
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Fujiwara Y Domingo V Seiple IB Gianatassio R Del Bel M Baran PS 《Journal of the American Chemical Society》2011,133(10):3292-3295
A direct functionalization of a variety of quinones with several boronic acids has been developed. This scalable reaction proceeds readily at room temperature in an open flask using inexpensive reagents: catalytic silver(I) nitrate in the presence of a persulfate co-oxidant. The scope with respect to quinones is broad, with a variety of alkyl- and arylboronic acids undergoing efficient cross-coupling. The mechanism is presumed to proceed through a nucleophilic radical addition to the quinone with in situ reoxidation of the resulting dihydroquinone. This method has been applied to complex substrates, including a steroid derivative and a farnesyl natural product. 相似文献
50.
Saito S Nakano Y Hikichi A Suzuki R Yoshimoto K Maeda M Aoyama M Shibukawa M 《The Analyst》2011,136(13):2697-2705
Novel fluorescent probes have been developed for the ultratrace detection of heavy metal ions by capillary electrophoresis using laser-induced fluorescence detection. Based on a molecular design, the probes are composed of an octadentate chelating moiety, a macrocyclic DOTA (tetraazacyclododecanetetraacetic acid) and an acyclic DTPA (diethylenetriaminepentaacetic acid) frame, a spacer and a fluorophore (fluorescein). These were chosen on the basis of their ability to form kinetically inert and highly emissive complexes, and to prevent a quenching effect even with heavy and paramagnetic metal ions. Addition of a cationic polymer, polybrene, in the separation buffer provided high resolution and simultaneous detection of Ca(2+), Mg(2+), Cu(2+), Zn(2+), Ni(2+), Co(2+), Mn(2+), Cd(2+) and Pb(2+). The direct fluorescence detection of these metal ions with high sensitivity at lower ppt levels, typically 2-7 × 10(-11) M (potentially sub-ppt), was successfully achieved. While separation of anionic compounds using a counter cation ("Ion Association (IA)" mode) is typically controlled by the ion association equilibrium constants, K(ass), it was found that differences in the mobilities, μ(ep(IAC)), of the ion association complexes formed between the probe complexes and counter cations are the driving forces for separation in this new method. This suggests that each of the polybrene-probe complexes has different chemical structures among metal ions, which were able to be determined by CD spectra in this investigation. This novel separation mode was termed the "Ion Association Complex (IAC)" mode, distinct from the IA mode. 相似文献