Liquid-crystalline cationic complexes of lanthanides with azomethines containing the alkyl sulfate anion as the counterion
were synthesized. The temperatures of existence of the mesophase of the complexes with the alkyl sulfate anion were by 80–100°C
lower than those of similar complexes with the Cl− and NO3− counterions.
Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 2, pp. 387–389, February, 1999. 相似文献
Actively mode-locked electron-beam-sustained-discharge CO laser producing a train of ∼5-15 ns (FWHM) spikes following with repetition rate 10 MHz for both single-line and multiline mode of operation in the mid-IR range of ∼5 μm was experimentally studied. Total laser pulse duration was ∼0.5 ms for both mode-locked and free-running laser. Specific output energy in multiline CO laser mode of operation was up to 20 Jl−1 Amagat−1 and the laser efficiency up to 3.5%. The active mode-locking was achieved for single-line CO laser mode of operation in spectral range 5.2-5.3 μm. This sort of radiation can be used for pumping an optical parametric amplifier for optical stochastic cooling in relativistic heavy ion collider, for laser ablation, and for studying vibrational and rotational relaxation of CO and NO molecules. 相似文献
Hydroxy‐mediated methoxy formation or stabilization is probably an important process in many methanol adsorption systems. Hydrogen atoms originating from the scission of the methanol O? H bond react with the substrate and form water. This process may result 1) in the production of additional surface defects as reactive centers for methoxy formation and 2) in the stabilization of methoxy groups by suppression of methanol formation.
The catalytic effect of VSi2 on initial stages of the liquid-phase oxidation of cyclooctene by molecular oxygen was studied. The vanadium disilicide influences
on the oxidation process in the presence of hydroperoxide. VSi2 takes part in a radical formation stage by catalysis of hydroperoxide decomposition reaction. The catalyst was investigated
before and after reaction using FTIR spectroscopy. From the data obtained, the kinetic model of the catalytic oxidation process
was proposed and the equation for the reaction rate was derived. The equation has described all observed dependences of reaction
rate on the concentration of reactants and content of catalyst.
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The theory of thermal stresses based on the heat conduction equation with the Caputo time-fractional derivative of order 0 < α ≤ 2 is used to investigate axisymmetic thermal stresses in a cylinder. The solution is obtained applying the Laplace and
finite Hankel integral transforms. The Dirichlet and two types of Neumann problems with the prescribed boundary value of the
temperature, the normal derivative of the temperature, and the heat flux are considered. Numerical results are illustrated
graphically. 相似文献