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141.
Rate constants of the reactions of O(3P) atoms with Br2 and NO2 over the temperature range 220-950 K
The kinetics of the reactions of Br2 and NO2 with ground state oxygen atoms have been studied over a wide temperature range, T = 220-950 K, using a low-pressure flow tube reactor coupled with a quadrupole mass spectrometer: O + NO2 → NO + O2 (1) and O + Br2 → Br + BrO (2). The rate constant of reaction (1) was determined under pseudo–first-order conditions, either monitoring the kinetics of O-atom or NO2 consumption in excess of NO2 or of the oxygen atoms, respectively: k1 = (6.1 ± 0.4) × 10−12 exp((155 ± 18)/T) cm3 molecule−1 s−1 (where the uncertainties represent precision at the 2σ level, the estimated total uncertainty on k1 being 15% at all temperatures). The temperature dependence of k1, found to be in excellent agreement with multiple previous low-temperature data, was extended to 950 K. The rate constant of reaction (2) determined under pseudo–first-order conditions, monitoring the kinetics of Br2 consumption in excess of O-atoms, showed upward curvature at low and high temperatures of the study and was fitted with the following three-parameter expression: k2 = 9.85 × 10−16 T1.41 exp(543/T) cm3 molecule−1 s−1 at T = (220-950) K, which is recommended from the present study with an independent of temperature conservative uncertainty of 15% on k2. 相似文献
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The modern intracavity laser method has been applied to study electronic spectra of the hafnium monohalides molecules. Results of new investigation of HfF and HfBr molecules are presented: the bands at 589.3, 590.6, and 593.1 nm observed in intracavity laser spectra of HfF4 have been assigned to the bands of HfF or ionized HfF; new molecular constants of the HfBr molecule have been obtained. Spectroscopic studies of HfCl and Hfl molecules are discussed, and the most reliable molecular constants of HfCl, HfBr, and Hfl molecules are recommended. 相似文献
146.
Russell Johnson Yuri Latushkin Roland Schnaubelt 《Journal of Dynamics and Differential Equations》2014,26(2):243-266
We prove the reduction principle and study other attractivity properties of the center and center-unstable manifolds in the vicinity of a steady-state solution for quasilinear systems of parabolic partial differential equations with fully nonlinear boundary conditions on bounded or exterior domains. 相似文献
147.
Oleg G. Sinyashin Irina P. Romanova Gulshat G. Yusupova Valery I. Kovalenko Yuri Y. Efremov Irina I. Vandyukova 《Phosphorus, sulfur, and silicon and the related elements》2013,188(1)
Abstract Data on the structure of cycloadducts of organophosphorus dipolar reagents and fullerenes arc absent, to our knowledge. We died the reactions and the shucturc of cycloadducts of phosphorylated azidcs and nitrile oxide with [60]fullcrcnc. The cycloaddition of diphcnylphosphinic llzide to fullcrme has bcm determined to lead to the 1 -[(N-diphenylphosphoryl)amino]-2-hydroxy[6O]hllcrme (l), the mixhuc of phosphorylated aziridinofullcrcne (2) and derivative of fullerne (3) with one aziridine fragment and one aminohydmxy-fragment, or to product (4), depending on the conditions of don . 相似文献
148.
Elena B. Averina Yuri V. Samoilichenko Yulia A. Volkova Yuri K. Grishin Victor B. Rybakov Andrei G. Kutateladze Mikhail E. Elyashberg Tamara S. Kuznetsova Nikolai S. Zefirov 《Tetrahedron letters》2012,53(12):1472-1475
Revised regiochemistry for the heterocyclization of electrophilic alkenes with tetranitromethane (TNM) in the presence of triethylamine, providing rapid access to nitroisoxazoles, is reported. The formation of 5-nitroisoxazoles previously incorrectly assigned as 3-nitro regioisomers, has now been established unambiguously by X-ray crystallography. Empirical computations with ACD/CNMR Predictor, based both on hierarchical ordering of spherical environments (HOSE) and an algorithm of artificial neural networks (ANN), and also Density Functional Theory computations of the 13C NMR chemical shifts for the 3- versus 5-nitroisoxazoles are shown to consistently match the spectra of the experimentally observed 5-regioisomers. 相似文献
149.
Ishibashi Chiaki Ichiyama Mai Ishida Naoya Kitamura Naoto Idemoto Yasushi 《Journal of Solid State Electrochemistry》2022,26(3):663-682
Journal of Solid State Electrochemistry - The stable structures associated with the second charge of MgCo2−xMnxO4 (x = 0, 0.5), where Mg is removed from the stable first-discharge... 相似文献
150.
The dynamic Hartree-Fock theory with point-like interaction is used to calculate the speed of sound and damping factor of a zero-sound wave propagating in a degenerate Fermi gas. This wave propagates slower than Fermi velocity. It is shown, that if the interaction is weak and density is small, then the damping of such a wave can be small. A possibility of discovering such waves in ultracold Fermi gases is discussed. 相似文献