全文获取类型
收费全文 | 2048篇 |
免费 | 345篇 |
国内免费 | 226篇 |
专业分类
化学 | 1445篇 |
晶体学 | 15篇 |
力学 | 96篇 |
综合类 | 8篇 |
数学 | 286篇 |
物理学 | 769篇 |
出版年
2024年 | 9篇 |
2023年 | 55篇 |
2022年 | 56篇 |
2021年 | 55篇 |
2020年 | 71篇 |
2019年 | 69篇 |
2018年 | 71篇 |
2017年 | 62篇 |
2016年 | 90篇 |
2015年 | 74篇 |
2014年 | 95篇 |
2013年 | 127篇 |
2012年 | 157篇 |
2011年 | 169篇 |
2010年 | 98篇 |
2009年 | 129篇 |
2008年 | 122篇 |
2007年 | 118篇 |
2006年 | 117篇 |
2005年 | 102篇 |
2004年 | 73篇 |
2003年 | 59篇 |
2002年 | 56篇 |
2001年 | 64篇 |
2000年 | 52篇 |
1999年 | 63篇 |
1998年 | 35篇 |
1997年 | 45篇 |
1996年 | 47篇 |
1995年 | 33篇 |
1994年 | 19篇 |
1993年 | 26篇 |
1992年 | 30篇 |
1991年 | 28篇 |
1990年 | 22篇 |
1989年 | 10篇 |
1988年 | 9篇 |
1987年 | 10篇 |
1986年 | 9篇 |
1985年 | 8篇 |
1984年 | 9篇 |
1983年 | 6篇 |
1982年 | 10篇 |
1981年 | 5篇 |
1980年 | 4篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1976年 | 4篇 |
1974年 | 3篇 |
1973年 | 5篇 |
排序方式: 共有2619条查询结果,搜索用时 15 毫秒
101.
采用常压金属有机化学汽相沉积(MOCVD)技术以Al2O3为衬底在GaN膜上生长了InxGa1-xN薄膜。以卢瑟福背散射/沟道技术、光透射谱、光致发光光谱对InxGa1-xN/GaN/AI2O3样品进行了测试。研究了InxGa1-xN薄膜的弯曲因子及斯托克斯移动。结果表明,采用光透射谱、光致发光光谱得到的InxGa1-xN薄膜的禁带宽度一致,InxGa1-xN薄膜并不存在斯托克斯移动。InxGa1-xN薄膜的In组分分别为0.04,0.06,0.24,0.26时,其弯曲因子分别为3.40,2.36,1.82,3.70。随In组分变化。InxGa1-xN薄膜的弯曲因子的变化并没有一定的规律,表明InxGa1-xN薄膜的禁带宽度随In组分的变化关系复杂。 相似文献
102.
103.
Peter Gregorčič Rok Petkovšek Janez Možina Griša Močnik 《Applied Physics A: Materials Science & Processing》2008,93(4):901-905
We present an optodynamic measurement of a laser-induced cavitation bubble and its oscillations based on a scanning technique
using a laser beam-deflection probe. The deflection of the beam was detected with a fast quadrant photodiode which was built
into the optical probe. The applied experimental setup enabled us to carry out one- or two-dimensional scanning of the cavitation
bubble, automatic control of the experiment, data acquisition and data processing. Shadow photography was used as a comparative
method during the experiments. 相似文献
104.
Utilisation of Anagrus nilaparvatae is a promising and effective method for planthoppers manipulation. Twenty-seven components of remote lemongrass (Cymbopogon distans) oil were identified by GC/MS and nine volatiles were selected for behavioural experiments. In this study, we noted that the remote lemongrass oil was attractive to female A. nilaparvatae at concentrations of 0.1 and 1 mg/L. α-Pinene, β-pinene, eucalyptol, carveol and D-carvone attracted female wasps in the dose-dependent bioassays. Blend 1 (a mixture of eucalyptol, D-carvone, carveol, α-pinene, and β-pinene with ratios of remote lemongrass oil volatiles of 625:80:11:5:3) attracted female wasps at 10 mg/L, while blend 2 (a mixture of the same five volatiles at the same loading ratio) attracted them at 0.1 and 1 mg/L. These results suggested that plant essential oils could be attractants for natural enemies to control pests. The ratios of volatiles in the mixtures affect the attractiveness of the synthetic mixtures. 相似文献
105.
106.
Dr. Zhenbo Mo Dr. Takanori Shima Prof. Dr. Zhaomin Hou 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(22):8713-8722
Studies on N2 activation and transformation by transition metal hydride complexes are of particular interest and importance. The synthesis and diverse transformations of a dinitrogen dititanium hydride complex bearing the rigid acridane-based acriPNP-pincer ligands {[(acriPNP)Ti]2(μ2-η1:η2-N2)(μ2-H)2} are presented. This complex enabled N2 cleavage and hydrogenation even without additional H2 or other reducing agents. Furthermore, diverse transformations of the N2 unit with a variety of organometallic compounds such as ZnMe2, MgMe2, AlMe3, B(C6F5)3, PinBH, and PhSiH3 have been well established at the rigid acriPNP-ligated dititanium framework, such as reversible bonding-mode change between the end-on and side-on/end-on fashions, diborylative N=N bond cleavage, the formal insertion of two dimethylaluminum species into the N=N bond, and the formal insertion of two silylene units into the N=N bond. This work has revealed many unprecedented aspects of dinitrogen reaction chemistry. 相似文献
107.
108.
首先制备了α-MnO2纳米花簇、β-MnO2纳米针和δ-MnO2微米颗粒三种不同晶型的MnO2粉末材料,对其结构、形貌及吸附除铵能力进行了表征和测试.结果表明,层间距(7.2Å)大于NH4+直径(2.96Å)和水合NH4+直径(6.62Å)的δ-MnO2相比其他两种晶型的MnO2有更高的NH4+吸附量;接着研究采用KMnO4原位氧化还原法在石墨毡(GF)上直接生长超薄δ-MnO2纳米片(MnO2NPs)阵列构筑了石墨毡载纳米MnO2(MnO2NPs/GF)多级结构材料,制备简单,无须成型造粒就可直接用作除铵净水材料,研究结果表明,MnO2NPs/GF不仅具有较高的吸附量(15 mg·g-1)与良好的选择性,同时还展现了优异的快速吸附和稳定的循环使用性能.MnO2NPs/GF对水中NH4+的吸附符合准二级动力学模型,其吸附等温线符合Langmuir吸附等温式,是吸附-离子交换法除铵的理想材料. 相似文献
109.
J. Říkovská A. Machová W. D. Hamilton J. Dupák Chan Chen Mo M. Finger N. A. Lebedev B. S. Neganov V. N. Pavlov A. F. Shchus 《Czechoslovak Journal of Physics》1979,29(6):620-639
The anisotropy of the angular distribution of gamma-rays from the decay of156Tb, oriented in a gadolinium matrix at low temperatures, has been measured at the angles of 0 and π/2 with respect to the applied magnetic field direction in the range of temperatures from 14·6 to 68·4 mK. The temperature dependence of anisotropy was measured for the first time. The parameters of hyperfine magnetic dipole and electric quadrupole splittings have been determined and the values of the magnetic dipole moment ¦Μ156¦=(9·6±1·3)×10?27 J/T and the electric quadrupole momentQ 156=(2·9±0·9)×10?28 m2 of the156Tb ground state have been calculated. Multipole mixing ratios andB(E2) branching ratios of many gamma-ray transitions occurring in156Gd have been found and the results have been discussed in terms of the rotational-vibration and pairing-plus-quadrupole models. 相似文献
110.
Asymptotic solution for a perturbed mechanism of western boundary undercurrents in the Pacific 总被引:1,自引:0,他引:1 下载免费PDF全文
This paper consider a class of perturbed mechanism for the western
boundary undercurrents in the Pacific. The model of generalized
governing equations is studied. Using the perturbation method, it
constructs the asymptotic solution of the model. And the accuracy of
asymptotic solution is proved by the theory of differential
inequalities. Thus the uniformly valid asymptotic expansions of the
solution are obtained. 相似文献