弹光调制傅里叶变换光谱相位校正及DSP实现

弹光调制傅里叶变换光谱仪(PEM-FTS)具有调制速度快、信息量大的特点,但采样位置偏差会导致干涉图存在相位误差,影响复原光谱的准确性。因此,必需采用一种运算速度高的相位校正方案。以300 K黑体为辐射源,通过弹光调制干涉具产生干涉数据,并在TMS320C6713DSP芯片上,采用Mertz法对弹光调制干涉图进行相位校正。首先提取出一幅完整周期的双边干涉图,经过切趾处理后,以零光程差点为中心计算小双边干涉图的相位误差,再通过插值补零得到整幅干涉图的相位误差,求出整体干涉图的频谱并进行相位修正。采用二范数定义校正后反演光谱的精度,以计算定时器周期寄存器值的方法设置DSP定时器,以统计代码的运行时间,并通过观察链接命令文件.cmd中程序与数据的分配存储情况,来对比分析Mertz法与模平方法的校正结果。实验结果表明,在DSP上实现相位校正时,Mertz法相位校正方案具有运算速度快、占用存储空间少、误差较小等特点,并且Mertz相位校正法的运算时间较模平方法快20倍,适用于对PEM-FTS干涉图进行高速准确的相位校正。     

An Antibacterial Nonenzymatic Glucose Sensor Composed of Carbon Nanotubes Decorated with Silver Nanoparticles

A glucose sensor composed of silver nanoparticles decorated carbon nanotubes (Ag‐NPs/CNTs) prepared by ion implantation is described. Ag‐NPs with size of 2–4 nm are uniformly distributed in the CNTs after ion implantation. This process provides a strong combination between Ag‐NPs and CNTs and can effectively prevent the Ag‐NPs from aggregation. A linear range of 125 µM to 10 mM towards glucose determination was obtained. The Ag‐NPs/CNTs electrode shows minimal interferences from co‐existence species such as uric acid and ascorbic acid and an antibacterial rate of 94 % towards E. coli.     

门诊100例血硒临床分析

临床观察了内科门诊100例血硒化验结果。结果表明,此100例患者血硒均存在不同程度的硒缺乏。低血硒都存在各种不同程度的疾病,如:冠心病、肝病、糖尿病、胃病、癌症、反复呼吸道感染以及各种感染、反复口腔溃疡、免疫功能低下、重金属中毒等。硒缺乏已经严重影响了本地区大多数人的身体健康。     

用HI-13串列加速器质谱装置测量182Hf的研究

¹⁸²Hf的半衰期为(8.90±0.09)Ma, 是一个接近灭绝的放射性核素. 超新星爆炸是自然界中已知的惟一能产生¹⁸²Hf的途径. 因此¹⁸²Hf是研究近1亿年来在地球附近可能发生的超新星事件的理想核素. 另外, ¹⁸²Hf是核工程中特别感兴趣的一个长寿命放射性核素. 精确测量超痕量的¹⁸²Hf对反应堆的设计和核天体物理学以及其他研究领域都是非常重要的. 用加速器质谱有可能实现对超低含量¹⁸²Hf的测量. 在中国原子能科学研究院的HI-13加速器质谱装置上对¹⁸²Hf的测量方法以及样品的化学去钨方法进行了研究, 分别得到了空白样品以及系列标准样品的¹⁸²Hf和¹⁸³W的能量-飞行时间双维谱. ¹⁸²W对¹⁸²Hf计数的贡献是通过测量¹⁸³W的计数归一扣除的. 目前本工作对¹⁸²Hf的测量灵敏度为4.15±10^－11 (¹⁸²Hf/¹⁸⁰Hf比值).     

Analysis and optimization of a new photonic crystal filters in near ultraviolet band

Transmission characteristics of one-dimensional (1D) photonic crystals (PCs) heterostructures containing defective are studied using the transfer matrix method. The key is to search the best combination style for different 1D PCs to form heterostructures. It is shown that the non-transmission range over near ultraviolet and visible range can be substantially enlarged and the phenomenon of narrow band PC filter in near ultraviolet can be realized by adjusting the repeat cycle counts of various photonic crystals. The theoretical results on multiple heterostructures containing TiO₂/SiO₂ multilayer films are presented. With a perfect omni-directional and high peak transmission filters for TE modes, this structure opens a promising way to fabricate ultra-narrow band PC filters with wide non-transmission range in near ultraviolet and visible range.     

微通道板选通X射线皮秒分幅相机

本文报道的超高速摄影机可在1.2ns内连续拍摄12幅图象,每幅图象的曝光时间为100ps,空间分辨率201p/mm,它具有几何畸变小、动态范围大等特点。对MCP皮秒选通的数值模拟考虑了电子渡越时间及弥散影响。变象管研制着重解决了微通道板上微带线的欧姆损耗问题。     

基于分子间侧向氢键作用的电光材料制备及性能

通过重氮耦合和酯化等反应制备了一系列侧向含有酰胺基团的偶氮苯类非线性光学生色团, 并将其与聚合物进行掺杂或通过分子间的侧向氢键作用制备了主客体型及超分子型的电光薄膜材料. 生色团的结构通过核磁共振谱(¹H NMR, NMR)、 红外光谱(IR)、 质谱(MS)和元素分析(EA)等进行了表征, 结果表明, 生色团形成了分子间的氢键作用. 通过紫外-可见(UV-Vis) 光谱研究了材料的极化性能. 相比主客体型电光薄膜材料, 由分子间侧向氢键作用形成的超分子型电光薄膜材料无需与聚合物基体材料复合, 更有利于提高材料的生色团含量、 极化取向度及稳定性. 通过Teng-Man简单反射法研究了主客体型和超分子型电光材料的二阶非线性光学性质, 结果表明, 基于分子间侧向氢键作用形成的超分子体系具有更大的电光系数.     

内禀退相干下Tavis-Cummings模型中原子的纠缠演化与贝尔不等式破坏

通过求解系统的Milburn方程，研究了两个二能级原子和单模场相互作用系统中原子间纠缠和贝尔不等式破坏随时间的演化特性，讨论了偶极相互作用、场与原子的失谐量对纠缠度以及贝尔不等式破坏的影响.结果表明：原子间偶极-偶极相互作用对纠缠度和贝尔不等式破坏有显著影响，失谐量增大会使两原子的纠缠度和贝尔不等式破坏变大，并且两原子所能达到稳定的纠缠受偶极相互作用系数与失谐量两者之差的影响.同时还发现两原子的纠缠与贝尔不等式破坏并不是单调的函数关系，很小的纠缠也可以产生贝尔不等式破坏. 关键词： Milburn理论 偶极-偶极相互作用 失谐量 贝尔不等式破坏     

Kinetics and mechanism of oxidation of 2-Aminoethanol and 3-Amino-1-propanol by diperiodatoargentate(III) in alkaline medium

The kinetics of oxidation of 2-aminoethanol and 3-amino-1-propanol by diperiodatoargentate(III) (DPA) were carried out spectrophotometrically in alkaline medium in the temperature range of 293.2-308.2 K. The reaction showed first order with respect to [DPA] and each reductant. The observed rate constant (k _obs) decreased with the increase of [IO₄ ^-] and increased with the increase of [OH^-]. Increasing ionic strength of the medium decreased the rate. Investigations of the reaction at different temperatures allowed the determination of the activation parameters for the slow step of proposed mechanism. The proposed mechanism and the derived rate laws found consistent with the observed kinetics.     

Oligoepicatechins from the Leaves of Machilus konishii

Epicatechin ( 3 ) and five oligomers ( 2 , 4 , 5 , 10 , 11 ) together with five other type compounds were isolated and characterized from n‐BuOH and EtOAc soluble fractions of the ethanol extract of the leaves of Machilus konishii Hayata. Their structures were elucidated by means of MS and NMR spectroscopic analyses. Dehydrodiepicatechin A ( 11 ) is the first occurrence as a natural product although it has been prepared from epicatechin. The stereochemistry of 11 is elucidated for the first time on the basis of 1D NOESY and chemical model analyses. Tiliroside ( 7 ) and kaempferol 3‐O‐α‐L‐(2″,4″‐di‐E‐p‐coumaroyl)‐rhamnopyranoside ( 8 ) showed moderate inhibitory activity against α‐glucosidase.