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排序方式: 共有426条查询结果,搜索用时 375 毫秒
21.
Ejaz Mohsin Azad Muhammad Muzammil Shah Atta ur Rehman Afaq S. Kamran Song Jung-il 《Cellulose (London, England)》2022,29(3):1775-1790
Cellulose - This study focuses on the synergistic effects of hydroxide based nanoparticles namely aluminum trihydrate (ATH) and zirconium hydroxide (ZHO) on the mechanical characteristics, thermal... 相似文献
22.
The electrochemical CO2 reduction (CO2RR) is a sustainable approach to mitigate the increased CO2 emissions and simultaneously produce value-added chemicals and fuels. Metal-nitrogen-carbon (M-N-C) based single-atom catalysts (SACs) have emerged as promising electrocatalysts for CO2RR with high activity, selectivity, and stability. To design efficient SACs for CO2RR, the key influence factors need to be understood. Here, we summarize recent achievements on M-N-C SACs for CO2RR and highlight the significance of the key constituting factors, metal sites, the coordination environment, and the substrates, for achieving high CO2RR performance. The perspective views and guidelines are provided for the future direction of developing M-N-C SACs as CO2RR catalysts. 相似文献
23.
Synthesis and Isolation of the Titanium–Scandium Endohedral Fullerenes—Sc2TiC@Ih‐C80, Sc2TiC@D5h‐C80 and Sc2TiC2@Ih‐C80: Metal Size Tuning of the TiIV/TiIII Redox Potentials
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Katrin Junghans Dr. Kamran B. Ghiassi Nataliya A. Samoylova Qingming Deng Marco Rosenkranz Prof. Marilyn M. Olmstead Prof. Alan L. Balch Dr. Alexey A. Popov 《Chemistry (Weinheim an der Bergstrasse, Germany)》2016,22(37):13098-13107
The formation of endohedral metallofullerenes (EMFs) in an electric arc is reported for the mixed‐metal Sc–Ti system utilizing methane as a reactive gas. Comparison of these results with those from the Sc/CH4 and Ti/CH4 systems as well as syntheses without methane revealed a strong mutual influence of all key components on the product distribution. Whereas a methane atmosphere alone suppresses the formation of empty cage fullerenes, the Ti/CH4 system forms mainly empty cage fullerenes. In contrast, the main fullerene products in the Sc/CH4 system are Sc4C2@C80 (the most abundant EMF from this synthesis), Sc3C2@C80, isomers of Sc2C2@C82, and the family Sc2C2 n (2 n=74, 76, 82, 86, 90, etc.), as well as Sc3CH@C80. The Sc–Ti/CH4 system produces the mixed‐metal Sc2TiC@C2 n (2 n=68, 78, 80) and Sc2TiC2@C2 n (2 n=80) clusterfullerene families. The molecular structures of the new, transition‐metal‐containing endohedral fullerenes, Sc2TiC@Ih‐C80, Sc2TiC@D5h‐C80, and Sc2TiC2@Ih‐C80, were characterized by NMR spectroscopy. The structure of Sc2TiC@Ih‐C80 was also determined by single‐crystal X‐ray diffraction, which demonstrated the presence of a short Ti=C double bond. Both Sc2TiC‐ and Sc2TiC2‐containing clusterfullerenes have Ti‐localized LUMOs. Encapsulation of the redox‐active Ti ion inside the fullerene cage enables analysis of the cluster–cage strain in the endohedral fullerenes through electrochemical measurements. 相似文献
24.
As generalizations of annihilators and associated primes, we introduce the notions of weak annihilators and weak associated primes, respectively. We first study the properties of the weak annihilator of a subset X in a ring R. We next investigate how the weak associated primes of a ring R behave under passage to the skew monoid ring R*M. Let R be a semicommutative ring, and M an ordered monoid and φ: M → Aut(R) a compatible monoid homomorphism. Then we can describe all weak associated primes of the skew monoid ring R*M in terms of the weak associated primes of R in a very straightforward way. 相似文献
25.
Experimental results on the extrapolated ultimate enhancement factors of o-, m-, and p-xylene protons at 1.53 mT are obtained for MC800 asphalt solutions. The ultimate enhancement factors are found such as ?26.9, ?25.7, and ?11.7 for o-, m-, and p-xylene, respectively. These results show that the solvent proton Overhauser effect cannot reach the extrapolated enhancement of ?330 in the extreme narrowing case because of occurrence of small scalar interactions in addition to the dipole–dipole interactions between solvent protons and asphalt electrons. The ortho, meta, and para positions of the –CH3 group change the nature of the interactions. The nuclear magnetic resonance (NMR) signal enhancements exhibit a sensitive behavior depending on the chemical environment differing from isomer to isomer. The solvation or association of asphalt in xylene isomers at room temperature is revealed. Quantum chemical calculations for the xylene isomers with the electronic and optical properties; absorption wavelengths, excitation energy, atomic charges, dipole moment and frontier molecular orbital energies, molecular electrostatic potential; are carried out using the density functional theory (DFT) method (B3LYP) with the 6-311G(d,p) basis set by the standard Gaussian 09 software package program. The relative importance of scalar and translational dipolar interaction parameters determined in dynamic nuclear polarization experiments is explained by the electronic structure of HOMO–LUMO of the xylene isomers. 相似文献
26.
Photopyroelectric spectroscopy of Sb<Subscript>2</Subscript>O<Subscript>3</Subscript> - ZnO ceramics
A. Zakaria Z. Rizwan M. Hashim A. Halim Shaari W. Mohmood Mat Yunus 《The European physical journal. Special topics》2008,153(1):33-35
Photopyroelectric spectroscopy is used to study the
band-gap energy of the ceramic (ZnO + xSb2O3), x = 0.1 - 1.5 mol%
and the ceramic (ZnO + 0.4 mol% Bi2O3 + xSb2O3), x = 0 - 1.5 mol% sintered at isothermal temperature, 1280 °C, for 1 and 2 hours. The wavelength of incident light, modulated
at 9 Hz, is kept in the visible range and the photopyroelectric spectrum with
reference to doping level is discussed. The band-gap energy is reduced from
3.2 eV, for pure ZnO, to 2.86, 2.83 eV for the samples without
Bi2O3at 0.1 mol% of Sb2O3 for 1 and 2 hours of
sintering time, respectively. It is reduced to 2.83, 2.80 eV for the samples
with Bi2O3 at 0 mol% of Sb2O3 for 1 and 2 hours of
sintering time, respectively. The steepness factor σA which
characterizes the slop of exponential optical absorption is discussed with
reference to the doping level. The phase constitution is determined by XRD
analysis; microstructure and compositional analysis of the selected areas
are analyzed using SEM and EDX. 相似文献
27.
This paper reports that polarized far-infrared reflectivity measurements have been done on LiGaO2 single crystal along two crystalline taxes at different temperatures. The temperature dependent frequencies of the longitudinal and transverse optical phonon have been obtained from the real part of optical conductivity and the loss function respectively. A small Drude component is observed at frequency below 300 cm^-1 which could arise from Li ions or oxygen deficiencies. The ionicity of LiGaO2 has been studied from the analysis of the Born effective charge of different ions. 相似文献
28.
F. Finster N. Kamran J. Smoller S.-T. Yau 《Communications in Mathematical Physics》2002,230(2):201-244
The Cauchy problem is considered for the massive Dirac equation in the non-extreme Kerr–Newman geometry, for smooth initial
data with compact support outside the event horizon and bounded angular momentum. We prove that the Dirac wave function decays
in at least at the rate t
−5/6. For generic initial data, this rate of decay is sharp. We derive a formula for the probability p that the Dirac particle escapes to infinity. For various conditions on the initial data, we show that p = 0, 1 or 0 < p < 1. The proofs are based on a refined analysis of the Dirac propagator constructed in [4].
Received: 20 August 2001 / Accepted: 22 January 2002
RID="*"
ID="*"Present address: NWF I – Mathematik, Universit?t Regensburg, 93040 Regensburg, Germany.?E-mail: felix.finster@mathematik.uni-regensburg.de
RID="**"
ID="**"Research supported by NSERC grant # RGPIN 105490-1998.
RID="***"
ID="***"Research supported in part by the NSF, Grant No. DMS-0103998.
RID="****"
ID="****"Research supported in part by the NSF, Grant No. 33-585-7510-2-30. 相似文献
29.
Bel R Behnia K Proust C van der Linden P Maude D Vedeneev SI 《Physical review letters》2004,92(17):177003
We present a study of heat and charge transport in Bi(2+x)Sr(2-x)CuO(6+delta) focused on the size of the low-temperature linear term of the thermal conductivity at optimal-doping level. In the superconducting state, the magnitude of this term implies a d-wave gap with an amplitude close to what has been reported. In the normal state, recovered by the application of a magnetic field, measurement of this term and residual resistivity yields a Lorenz number L=kappa(N)rho(0)/T=1.3+/-0.2L(0). The departure from the value expected by the Wiedemann-Franz law is thus slightly larger than our estimated experimental resolution. 相似文献
30.
The first study of the Nernst effect in NbSe2 reveals a large quasiparticle contribution with a magnitude comparable and a sign opposite to the vortex signal. Comparing the effect of the charge density wave (CDW) transition on Hall and Nernst coefficients, we argue that this large Nernst signal originates from the thermally induced counterflow of electrons and holes and indicates a drastic change in the electron scattering rate in the CDW state. The results provide new input for the debate on the origin of the anomalous Nernst signal in high-T(c) cuprates. 相似文献