Synthesis,structure and photoluminescence of two porous metal-organoboron frameworks with rtl topology

Rigid trigonal tris(3-pyridylduryl)borane L was synthesized through four steps in good overall yield from readily available 1,2,4,5-tetramethylbenzene and was used to construct two porous cadmium(II) complexes Cd(L)X2.G(X = Cl,Br;G = guset molecules),1(Cd(L)Cl2.EtOH.iPrOH.3H2O) and 2(Cd(L)Br2.MeOH.C7H8.3H2O),under mild reaction conditions.1 and 2 are isostructural and featured with 3D porous metal-organoboron framewoks with rtl topology,in which L acts as a 3-connected node while a dicadmium motif serves as...     

T1 THEOREM FOR BESOV SPACES ON NONHOMOGENEOUS SPACES

Suppose μ is a Radon measure on Rd, which may be non doubling. The only condition assumed on μ is a growth condition, namely, there is a constant Co ＞ 0 such that for all x ∈ supp(μ) and r ＞ 0,μ(B(x,r)) ≤ Corn, where 0 ＜ n ≤ d. We prove T1 theorem for non doubling measures with weak kernel conditions. Our approach yields new results for kernels satisfying weakened regularity conditions, while recovering previously known Tolsa's results. We also prove T1 theorem for Besov spaces on nonhomogeneous spaces with weak kernel conditions given in [7].     

基于等角度与等时间采样技术扫描成像系统

为满足扫描成像系统对图象配准精度,从理论上分析了在等时间采样方式下,遥感仪器对扫描系统速度稳定度的要求.探讨了等角度这一新型采样方式应用于未来遥感仪器的可行性.并将这两种采样方式成功应用于自行研制的短波红外成像仪.扫描图象表明等角度采样可以避免等时采样所产生的图象畸变.     

Hamilton半群的结构

每个子半群是左理想的半群，称为左Ｈａｍｉｌｔｏｎ半群，本文给出左Ｈａｍｉｌｔｏｎ半群的刻划，并将左Ｈａｍｉｌｔｏｎ半群表示为有向森林，最后给出左Ｈａｍｉｌｔｏｎ半群同构的充要条件。     

From micro-to nanosized particles:Selected characterization methods and measurable parameters

Airborne microand nanoparticles-aerosols-play an important role in many natural phenomena and in a variety of industrial processes,as well as the public health issue. They may be of natural or anthropogenic origin;their presence in an environment might be intentional or due to undesirable release. In any case,merely the particle detection and characterization,ideally in real-time,provide an insight into the potential burden allowing also controlling and abatement measures. Due to the broad size range it is ...     

Photoactivity of titanium dioxide/carbon felt composites prepared with the assistance of supercritical carbon dioxide: Effects of calcination temperature and supercritical conditions

TiO2-coated carbon felt(TCF)composite catalysts have been prepared via a supercritical treatment of titanium tetraisopropoxide(TTIP)as the precursor.The physical properties of the catalysts were characterized by means of thermogravimetric and differential thermal analysis(TG–DTA),X-ray diffraction(XRD),fluorescence spectroscopy,scanning electron microscopy (SEM),and BET surface areas techniques.The photocatalytic activities of the materials were evaluated using the degradation of Congo red(CR)as a probe rea...     

Coral reef-like polyanaline nanotubes prepared by a reactive template of manganese oxide for supercapacitor electrode

Coral reef-like PANI nanotubes composed of nanopaticles were successfully synthesized by a reactive template of manganese oxide.The structure was characterized by using SEM,TEM,and FT-IR,and the supercapacitive behaviors of these nanotubes were investigated with cyclic voltammetry（CV）,and charge-discharge tests,respectively.A maximum specific capacitance of 533 F/g could be achieved in 1mol/L aqueous H₂SO₄ with the potential range of -0.2 to 0.8 V（vs.the saturated calomel electrode） in a half-cell setup configuration for PANI electrode,suggesting its potential application in the electrode material for electrochemical capacitors.     

海岸波浪场模型研究进展

从建模原理、波浪在近岸区域传播的众多机制、模型的类别、优势、局限性以及模型在未来的发展趋势等方面,综述了在海岸工程实践中广泛运用的以下两大类海岸波浪场预测模型的最新研究进展:(1)能量平衡模型.它一般用来预测海洋深水波候,已发展到相当完善的阶段,例如,最为著名的WAM3G模型.这种模型在海岸工程中的作用就在于可以模拟施加在波浪上的随时间变化的风场效应.(2)质量、动量守恒模型.它在海岸工程中应用最为普遍,并且内容丰富,数值技巧多样.目前包含了以下代表性的模型:缓坡方程、抛物型方程、非线性浅水方程、高阶Boussinesq型方程、Green-Naghdi理论.      

用激光三角法重构混凝土断裂面三维轮廓与断裂能分析

采用基于激光三角法的测试方法对混凝土断面表面轮廓进行了三维重构,初步的断面分析结果表明,相对于传统断面分析方法,本试验方法实现了断面的无损、快速和准确的测量分析,在测量到的断面基础上,给出了本试验所得到的混凝土材料断裂能与分维的关系。     

结构静动力屈曲问题研究进展

近几十年来，结构的静动力屈曲问题一直是力学工作者极为关注的一个前沿课题．本文总结和综述了这一研究领域的几个基本问题：屈曲问题的分类、动态屈曲问题的特点及其特征量；介绍了屈曲问题的处理方法和目前已取得的成果；总结评述了人们关心的热点问题；屈曲问题的模型分析和实验技术、动态屈曲判别准则．