全文获取类型
收费全文 | 15453篇 |
免费 | 1738篇 |
国内免费 | 1659篇 |
专业分类
化学 | 11798篇 |
晶体学 | 217篇 |
力学 | 728篇 |
综合类 | 137篇 |
数学 | 1485篇 |
物理学 | 4485篇 |
出版年
2024年 | 31篇 |
2023年 | 202篇 |
2022年 | 391篇 |
2021年 | 525篇 |
2020年 | 512篇 |
2019年 | 519篇 |
2018年 | 410篇 |
2017年 | 448篇 |
2016年 | 660篇 |
2015年 | 651篇 |
2014年 | 789篇 |
2013年 | 1081篇 |
2012年 | 1336篇 |
2011年 | 1364篇 |
2010年 | 1012篇 |
2009年 | 885篇 |
2008年 | 1110篇 |
2007年 | 943篇 |
2006年 | 888篇 |
2005年 | 778篇 |
2004年 | 660篇 |
2003年 | 562篇 |
2002年 | 610篇 |
2001年 | 411篇 |
2000年 | 318篇 |
1999年 | 293篇 |
1998年 | 222篇 |
1997年 | 177篇 |
1996年 | 148篇 |
1995年 | 136篇 |
1994年 | 93篇 |
1993年 | 97篇 |
1992年 | 94篇 |
1991年 | 96篇 |
1990年 | 58篇 |
1989年 | 51篇 |
1988年 | 50篇 |
1987年 | 38篇 |
1986年 | 34篇 |
1985年 | 33篇 |
1984年 | 19篇 |
1983年 | 19篇 |
1982年 | 19篇 |
1981年 | 13篇 |
1980年 | 11篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1975年 | 6篇 |
1971年 | 6篇 |
1970年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
21.
Young-Bae Seu Taeg-Kyeong Lim Chang-Jin Kim Sun-Chul Kang 《Tetrahedron: Asymmetry》1995,6(12):3009-3014
Optically active epoxy alcohol, (R)-2-butyryloxymethylglycidol3 which is the precursor of a tert-alcohol chiral building block was obtained in high enantiomeric purity, 98.7% e.e., by lipase-catalyzed asymmetric hydrolysis using a phosphate buffer and organic co-solvent system in 95% of chemical yield. 相似文献
22.
23.
A novel copolymer, poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐2,6‐pyridylene‐1,2‐ethenylene) ( P3 ), containing N‐hexyl‐3,7‐phenothiazylene and 2,6‐pyridylene chromophores was synthesized to investigate the effect of protonation, metal complexation, and chemical oxidation on its absorption and photoluminescence (PL). Poly(N‐hexyl‐3,8‐iminodibenzyl‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) and poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) ( P2 ), consisting of 1,3‐divinylbenzene alternated with N‐hexyl‐3,8‐iminodibenzyl and N‐hexyl‐3,7‐phenothiazylene, respectively, were also prepared for comparison. Electrochemical investigations revealed that P3 exhibited lower band gaps (2.34 eV) due to alternating donor and acceptor conjugated units (push–pull structure). The absorption and PL spectral variations of P3 were easily manipulated by protonation, metal chelation, and chemical oxidation. P3 displayed significant bathochromic shifts when protonated with trifluoroacetic acid in chloroform. The complexation of P3 with Fe3+ led to a significant absorption change and fluorescence quenching, and this implied the coordination of ferric ions with the 2,6‐pyridylene groups in the backbone. Moreover, both phenothiazylene‐containing P2 and P3 showed conspicuous PL quenching with a slight redshift when oxidized with NOBF4. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1272–1284, 2004 相似文献
24.
四阶方程两点边值问题Hermite有限元解的渐近展式与外推 总被引:1,自引:0,他引:1
1引言有限元解的渐近展式是提高微分方程数值解精度的重要工具,比如亏量校正和外推就是建立在有限元解的渐近展式的基础之上.许多作者对此进行了大量的研究(见[1]-[4]),特别是文[1],提出了在研究有限元解的渐近展式中十分有用的能量嵌入技巧.本文利用能量嵌入定理得到了四阶方程两点边值问题Hermite有限元解及其二阶平均导数的渐近展式,进一步我们还讨论了它们的Richardson外推公式.考虑四阶方程两点边值问题 相似文献
25.
Kyung Hwa Hong Jong Lyoul Park In Hwan Sul Ji Ho Youk Tae Jin Kang 《Journal of Polymer Science.Polymer Physics》2006,44(17):2468-2474
Polyvinyl alcohol (PVA) nanofibers containing Ag nanoparticles were prepared by electrospinning PVA/silver nitrate (AgNO3) aqueous solutions, followed by short heat treatment, and their antimicrobial activity was investigated for wound dressing applications. Since PVA is a water soluble and biocompatible polymer, it is one of the best materials for the preparation of wound dressing nanofibers. After heat treatment at 155 °C for 3 min, the PVA/AgNO3 nanofibers became insoluble, while the Ag+ ions therein were reduced so as to produce a large number of Ag nanoparticles situated preferentially on their surface. The residual Ag+ ions were reduced by subsequent UV irradiation for 3 h. The average diameter of the Ag nanoparticles after the heat treatment was 5.9 nm and this value increased slightly to 6.3 nm after UV irradiation. It was found that most of the Ag+ ions were reduced by the simple heat treatment. The PVA nanofibers containing Ag nanoparticles showed very strong antimicrobial activity. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 2468–2474, 2006 相似文献
26.
HU Yun & SHEN Yuliang Department of Mathematics Suzhou University Suzhou China 《中国科学A辑(英文版)》2006,(7)
We will be mainly concerned with some important fiber spaces over Teichmuller spaces, including the Bers fiber space and Teichmuller curve, establishing an isomorphism theorem between "punctured" Teichmuller curves and determining the biholomorphic isomorphisms of these fiber spaces. 相似文献
27.
We consider a stowage-planning problem of arranging containers on a container ship in the maritime transportation system. Since containers are accessible only from the top of the stack, temporary unloading and reloading of containers, called shifting, is unavoidable if a container required to be unloaded at the current port is stacked under containers to be unloaded at later ports on the route of the ship. The objective of the stowage planning problem is to minimize the time required for shifting and crane movements on a tour of a container ship while maintaining the stability of the ship. For the problem, we develop a heuristic solution method in which the problem is divided into two subproblems, one for assigning container groups into the holds and one for determining a loading pattern of containers assigned to each hold. The former subproblem is solved by a greedy heuristic based on the transportation simplex method, while the latter is solved by a tree search method. These two subproblems are solved iteratively using information obtained from solutions of each other. To see the performance of the suggested algorithm, computational tests are performed on problem instances generated based on information obtained from an ocean container liner. Results show that the suggested algorithm works better than existing algorithms. 相似文献
28.
In this paper, we give a recursive construction from an LTTS(v + 2) to an LTTS(16v + 2) for v 3. Furthermore, the existence of LTTS(2n + 2) is proved. Thereby, we completely solve the existence problem of LTTS)(v) (large set of pairwise disjoint transitive triple systems of order v). 相似文献
29.
30.
应用密度矩阵方程计算了四能级原子系统中三阶非线性极化率随信号光和探针光频率失谐的变化关系。结果表明,由于量子干涉对信号光强度的敏感性,使四能级原子介质的交叉Kerr非线性作用大大增强,与三能级系统相比,四能级原子介质的Kerr非线性系数可增强两个数量级。 相似文献