全文获取类型
收费全文 | 15721篇 |
免费 | 1776篇 |
国内免费 | 1659篇 |
专业分类
化学 | 12011篇 |
晶体学 | 213篇 |
力学 | 740篇 |
综合类 | 137篇 |
数学 | 1509篇 |
物理学 | 4546篇 |
出版年
2024年 | 31篇 |
2023年 | 203篇 |
2022年 | 407篇 |
2021年 | 531篇 |
2020年 | 526篇 |
2019年 | 538篇 |
2018年 | 426篇 |
2017年 | 461篇 |
2016年 | 684篇 |
2015年 | 657篇 |
2014年 | 812篇 |
2013年 | 1115篇 |
2012年 | 1372篇 |
2011年 | 1443篇 |
2010年 | 1033篇 |
2009年 | 909篇 |
2008年 | 1134篇 |
2007年 | 957篇 |
2006年 | 900篇 |
2005年 | 777篇 |
2004年 | 652篇 |
2003年 | 570篇 |
2002年 | 603篇 |
2001年 | 412篇 |
2000年 | 322篇 |
1999年 | 289篇 |
1998年 | 213篇 |
1997年 | 174篇 |
1996年 | 143篇 |
1995年 | 129篇 |
1994年 | 87篇 |
1993年 | 94篇 |
1992年 | 86篇 |
1991年 | 93篇 |
1990年 | 53篇 |
1989年 | 41篇 |
1988年 | 49篇 |
1987年 | 40篇 |
1986年 | 34篇 |
1985年 | 32篇 |
1984年 | 20篇 |
1983年 | 17篇 |
1982年 | 19篇 |
1981年 | 9篇 |
1980年 | 9篇 |
1979年 | 6篇 |
1978年 | 6篇 |
1975年 | 6篇 |
1971年 | 6篇 |
1970年 | 7篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
11.
Jun‐Hwan Ahn Choon‐Hwa Lee Yeong‐Deuk Shin Jae‐Suk Lee 《Journal of polymer science. Part A, Polymer chemistry》2004,42(4):933-940
To study living anionic polymerization, 3‐(triethylsilyl)propyl isocyanate (TEtSPI) monomer was synthesized by hydrosilylation of allylamine with triethylsilane and treatment of the resulting amine with triphosgene. The polymerization of TEtSPI was performed with sodium naphthalenide (Na‐Naph) as an initiator and in the absence and presence of sodium tetraphenylborate (NaBPh4) as an additive in tetrahydrofuran (THF) at ?78 and at ?98 °C. A highly stabilized amidate anion for living polymerization of isocyanates was generated for the first time with the combined effect of the bulky substituent and the shielding action of the additive NaBPh4, extending the living character at least up to 120 min at ?98 °C. Even the anion could exist at ?78 °C for 10 min. A block copolymer, poly(n‐hexyl isocyanate)‐b‐poly[(3‐triethylsilyl)propyl isocyanate]‐b‐poly(n‐hexyl isocyanate), was synthesized with quantitative yields and controlled molecular weights via living anionic polymerization in THF at ?78 °C for TEtSPI and ?98 °C for n‐hexyl isocyanate, respectively, with Na‐Naph with three times of NaBPh4 as a common ion salt. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 933–940, 2004 相似文献
12.
Dong‐Cheol Shin Yun‐Hi Kim Hong You Jae Gyu Jin Soon‐Ki Kwon 《Journal of polymer science. Part A, Polymer chemistry》2004,42(22):5636-5646
A poly(p‐phenylenevinylene) (PPV) derivative containing a bulky (2,2‐diphenylvinyl)phenyl group in the side chain, EHDVP‐PPV, was synthesized by Gilch route. The reduced tolane‐bisbenzyl (TBB) defects, as well as the structure of the polymer, was confirmed by various spectroscopic methods. The intramolecular energy transfer from the (2,2‐diphenylvinyl)phenyl side group to the PPV backbone was studied by UV‐vis and photoluminescence (PL) of the obtained polymer and model compound. The polymer film showed maximum absorption and emission peaks at 454 and 546 nm, respectively, and high PL efficiency of 57%. A yellow electroluminescence (λmax = 548 nm) was obtained with intensities of 6479 cd/m2 when the light‐emitting diodes of ITO/PEDOT/EHDVP‐PPV/LiF/Al were fabricated. The maximum power efficiency of the devices was 0.729 lm/W with a turn‐on voltage of 3.6 V. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 5636–5646, 2004 相似文献
13.
Dong Jun Kang Tae-Ho Lee Byeong-Soo Bae 《Journal of Sol-Gel Science and Technology》2004,31(1-3):113-116
Fluorinated inorganic-organic hybrid materials (HYBRIMER) were successfully prepared from fluoroalkylsilanes (FASs) containing fluoro-alkyl functions and methacryloxypropyltrimethoxysilane (MPTMS) through a sol-gel process. The influence of concentration and fluoro-alkyl chain lengths of FASs on the physical characteristics of the fluorinated HYBRIMER films was examined. Larger fluorine contents lowered the refractive index within a range, which was closely dependent on the fluoro-alkyl chain lengths of FASs. Thermo-optic coefficients (TOC) were negative values, and the values grew with increasing fluorine contents and fluoro-alkyl chain lengths. Also, the thermal stability is enhanced by addition of fluorine in the HYBRIMER. 相似文献
14.
15.
16.
Young Hee Geum Young Ik Kim Kang Sup Lee 《Journal of Applied Mathematics and Computing》2007,25(1-2):109-118
A parametric boundary equation is established for the principal period-2 bulb in the cubic Mandelbrot set. Using its geometry, an efficient escape-time algorithm which reduces the construction time for the period-2 bulbs in the cubic Mandelbrot set is introduced and the implementation graphic results display the fascinating fractal beauty 相似文献
17.
We investigate the connection between the entanglement system in Minkowski spacetime and the black hole using the scaling analysis. Here we show that the entanglement system satisfies the Bekenstein entropy bound. Even though the entropies of two systems are the same form, the entanglement energy is different from the black hole energy. Introducing the Casimir energy of the vacuum energy fluctuations rather than the entanglement energy, it shows a feature of the black hole energy. Hence the Casimir energy is more close to the black hole than the entanglement energy. Finally, we find that the entanglement system behaves like the black hole if the gravitational effects are included properly. 相似文献
18.
The notion of balanced bipartitions of the vertices in a tree T was introduced and studied by Reid (Networks 34 (1999) 264). Reid proved that the set of balance vertices of a tree T consists of a single vertex or two adjacent vertices. In this note, we give a simple proof of that result. 相似文献
19.
M.V. Nazarov J.H. Kang E.-J. Popovici B.S. Tsukerblat 《Solid State Communications》2005,133(3):183-186
Samples of yttrium oxide doped with trivalent europium have been prepared by ceramic techniques, under different synthesis conditions; barium chloride (BaCl2) and sodium tetraborate (Na2B4O7) were tested as flux. The improvement of luminescence properties in dependence on substitution of Eu3+ for Y3+ in the host lattice, under electron and UV excitations is demonstrated. The lattice parameter as a quantitative assessment of activator incorporation degree is proposed. The obtained results are discussed with respect to the employed processing method. 相似文献
20.