全文获取类型
收费全文 | 554篇 |
免费 | 57篇 |
国内免费 | 86篇 |
专业分类
化学 | 300篇 |
晶体学 | 4篇 |
力学 | 58篇 |
数学 | 203篇 |
物理学 | 132篇 |
出版年
2024年 | 2篇 |
2023年 | 7篇 |
2022年 | 18篇 |
2021年 | 18篇 |
2020年 | 14篇 |
2019年 | 27篇 |
2018年 | 23篇 |
2017年 | 12篇 |
2016年 | 25篇 |
2015年 | 20篇 |
2014年 | 21篇 |
2013年 | 23篇 |
2012年 | 37篇 |
2011年 | 42篇 |
2010年 | 34篇 |
2009年 | 31篇 |
2008年 | 43篇 |
2007年 | 41篇 |
2006年 | 35篇 |
2005年 | 27篇 |
2004年 | 14篇 |
2003年 | 15篇 |
2002年 | 17篇 |
2001年 | 15篇 |
2000年 | 13篇 |
1999年 | 8篇 |
1998年 | 10篇 |
1997年 | 19篇 |
1996年 | 27篇 |
1995年 | 16篇 |
1994年 | 14篇 |
1993年 | 6篇 |
1992年 | 1篇 |
1991年 | 3篇 |
1990年 | 1篇 |
1989年 | 4篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 5篇 |
1985年 | 3篇 |
1984年 | 2篇 |
1983年 | 1篇 |
排序方式: 共有697条查询结果,搜索用时 71 毫秒
131.
In this paper, we prove the global existence and asymptotic behavior, as time tends to infinity, of solutions in Hi (i=1, 2) to the initial boundary value problem of the compressible Navier–Stokes equations of one‐dimensional motion of a viscous heat‐conducting gas in a bounded region with a non‐autonomous external force and a heat source. Some new ideas and more delicate estimates are used to prove these results. Copyright © 2008 John Wiley & Sons, Ltd. 相似文献
132.
Yuming Wei 《Journal of Computational and Applied Mathematics》2009,231(1):134-142
In this paper, we investigate the existence of triple positive solutions for nonlinear differential equations boundary value problems with increasing homeomorphism and positive homomorphism operator. By using fixed point theorems in cones, we establish results on the existence of three positive solutions with suitable growth conditions imposed on the nonlinear term. As applications, two examples are given to demonstrate our result. The conclusions in this paper essentially extend and improve the known results. 相似文献
133.
In this paper, we consider one-dimensional compressible isentropic Navier-Stokes equations with the viscosity depending on density and with the free boundary. The viscosity coefficient μ is proportional to ρθ with θ>0, where ρ is the density. The existence, uniqueness, regularity of global weak solutions in H1([0,1]) have been established by Xin and Yao in [Z. Xin, Z. Yao, The existence, uniqueness and regularity for one-dimensional compressible Navier-Stokes equations, preprint]. Furthermore, under certain assumptions imposed on the initial data, we improve the regularity result obtained in [Z. Xin, Z. Yao, The existence, uniqueness and regularity for one-dimensional compressible Navier-Stokes equations, preprint] by driving some new a priori estimates. 相似文献
134.
Xiao Y Fisher K Smith MC Newton WE Case DA George SJ Wang H Sturhahn W Alp EE Zhao J Yoda Y Cramer SP 《Journal of the American Chemical Society》2006,128(23):7608-7612
Nitrogenase catalyzes a reaction critical for life, the reduction of N(2) to 2NH(3), yet we still know relatively little about its catalytic mechanism. We have used the synchrotron technique of (57)Fe nuclear resonance vibrational spectroscopy (NRVS) to study the dynamics of the Fe-S clusters in this enzyme. The catalytic site FeMo-cofactor exhibits a strong signal near 190 cm(-)(1), where conventional Fe-S clusters have weak NRVS. This intensity is ascribed to cluster breathing modes whose frequency is raised by an interstitial atom. A variety of Fe-S stretching modes are also observed between 250 and 400 cm(-)(1). This work is the first spectroscopic information about the vibrational modes of the intact nitrogenase FeMo-cofactor and P-cluster. 相似文献
135.
REBa2Cu3O7-x (RE:钇、钆等稀土元素,REBCO)高温超导体因其具备较高的不可逆场和上临界场等优越性能,一经发现就备受关注。但由于材料本身固有的陶瓷性及弱连接等属性,导致其实际应用起来难度较大。目前,人们已经发展了诸多制备工艺来克服这些困难,实现了REBCO超导体的实际应用。按照前驱膜沉积方法可将REBCO超导薄膜的制备分为物理法和化学法。本文综述了物理气相沉积(PVD-Physical Vapor Deposition)法中多源共蒸发法制备REBCO超导薄膜的技术起源及演变历程,并与金属有机沉积、金属有机化学气相沉积、脉冲激光沉积等不同方法生产的REBCO超导带材进行对比,突出多源共蒸发法制备的REBCO薄膜性能优异、在商业化生产效率上具有更大的优势。最后对多源共蒸发法制备REBCO超导薄膜进行总结及展望,解决多源共蒸发沉积制备REBCO薄膜的成相机理、提高薄膜的钉扎中心等问题对未来第二代高温超导带材的大规模应用具有重要意义。 相似文献
136.
137.
138.
针对通信与雷达系统对双极化与宽带天线的要求,提出了一种基于带状线馈电的双极化蝶形天线。通过两对互相正交的蝶形阵子实现了天线的双极化,并采用一种新型的微带线转异面带状线的巴伦给两对正交蝶形阵子平衡馈电。异面带状线为平衡传输线,满足了蝶形阵子对于平衡馈电的要求。在馈电点处由同轴线对微带线馈电,经渐变微带线转化为异面带状线,最后由两组异面带状线给两对正交蝶形阵子馈电。测得该天线实现了69.23%的阻抗带宽,在6.8~14GHz频带内电压驻波比(VSWR)小于2。为使天线单向辐射且改善天线增益,将天线放置于反射吸收腔内。测得天线在6.8~18GHz的频宽内VSWR基本小于3,天线增益在8~12GHz频带内大于0.11dB,天线前后瓣比大于15dB。因此,所提出的双极化蝶形天线可用于宽带通信系统中。 相似文献
139.
A facile Pd-catalyzed sequential reaction has been developed for the synthesis of δ-carbolines from 2-iodoanilines and N-tosyl-enynamines. This protocol involves Larock heteroannulation/elimination/electrocyclization/oxidative aromatization cascade sequences and allows access to multisubstituted δ-carbolines in moderate to good yields. 相似文献
140.
Yongzheng Duan Yuming Zhou Yiwei Zhang Xiaoli Sheng Shijian Zhou Zewu Zhang 《天然气化学杂志》2012,21(2):207-214
The catalytic properties of PtSn-based catalysts supported on siliceous SBA-15 and Al-modified SBA-15, such as Al-incorporated SBA-15 (AlSBA-15) and alumina-modified SBA-15 (Al2O3/SBA-15), for propane dehydrogenation were investigated. Al2O3/SBA-15 was prepared either by an impregnation method using aluminum nitrate aqueous solution, or by the treatment of SBA-15 with a Al(OC3H7)3 solution in anhydrous toluene. N2-physisorption, FT-IR spectroscopy, solid-state 27Al MAS NMR spectroscopy, hydrogen chemisorption, XRF, NH3 temperature-programmed desorption, X-ray photoelectron spectroscopy and TPO were used to characterize these samples. Among these catalysts, the PtSn-based catalyst supported on Al2O3/SBA-15, which was grafted with Al(OC3H7)3, exhibited the best catalytic performance in terms of activity and stability The possible reason was due to the high Pt metal dispersion and/or the strong interactions among Pt, Sn, and the support. 相似文献