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61.
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Frieder W. Lichtenthaler Jürgen Klotz Katsumi Nakamura 《Tetrahedron: Asymmetry》2003,14(24):3973-3986
The dimethyl esters of the 2,6-anhydro-3-deoxy-hept-2-enaric acids with
-xylo,
-lyxo,
-arabino,
-lyxo- and
-ribo-configuration were synthesized from
-galactose and
-mannose, respectively, and further characterized by their di-O-acetyl and di-O-benzoyl derivatives. Comparison of their physical data with those of Daucus carota derived products revealed (−)-daucic acid to have
-lyxo-configuration 46 rather than the previously assigned
-xylo stereochemistry 1. Dimethyl daucate 43 could be converted by acid-induced ring contraction and dehydration into naturally occurring (+)-osbeckic acid 47, thereby proving its (S)-configuration. Configurational identity in the pyranoid rings of (−)-daucic acid and KDO, together with available biosynthetic evidence on chelidonic acid 4, a leaf closing factor, suggests a joint, KDO 8-P-based pathway for their biosynthesis in plants. 相似文献
64.
Base-catalyzed reaction of 5-acylmethyl-2,5-di--butyl-4-oxa-2-cyclopentenones selectively derived from 4-alkyl-2,6-di--butylphenols three steps involving oxygenation, acetylation, and acid-treatment gave 3-alkyl-2,5-di--butyl-2,4-cyclopentadienones in excellent yield. 相似文献
65.
Phenols are deprotected with weak bases from their tert-butoxycarbonyl (Boc) derivatives. Boc deprotection with bases can avoid side reactions during the deprotection with acids. We note the lability of the Boc to bases and are able to utilize it as a new cleavage condition for synthetic studies. 相似文献
66.
Annaraj J Suh Y Seo MS Kim SO Nam W 《Chemical communications (Cambridge, England)》2005,(36):4529-4531
A mononuclear nonheme ferric-peroxo complex bearing a macrocyclic tetradentate N4 ligand, [(TMC)Fe(III)-O2]+, was prepared and used in mechanistic studies of aldehyde deformylation; a catalytic aldehyde deformylation by a nonheme iron(II) complex, [Fe(II)(TMC)]2+, and molecular oxygen is reported as well. 相似文献
67.
3-Epi-6,7-dideoxyxestobergsterol A (2), an analogue of xestobergsterol A, has been synthesized from dehydroepiandrosterone (3) in 15 steps. The key synthetic intermediate, 15beta,16alpha-dioxypregn-17(20)E-ene derivative 8, was prepared from the corresponding 15beta,16beta-epoxide 6 by treating with acetic acid and titanium tetraisopropoxide. The 23-oxo side chain was constructed stereoselectively by orthoester Claisen rearrangement of 8 followed by introduction of an isobutyl group. Basic treatment of the 15,23-diketone 12 followed by deprotection gave the title compound 2. 相似文献
68.
Y Nishikawa T Shindo K Ishii H Nakamura T Kon H Uno J Matsumoto 《Chemical & pharmaceutical bulletin》1989,37(5):1256-1259
A new series of oxopyridinecarboxamide derivatives 3a--g and 5a were synthesized and evaluated for their antiallergic activity. 1,4-Dihydro-7-methyl-4-oxo-1,8-naphthyridine-3-carboxamides 3a and 5a exhibited potent antiallergic activity (inhibitory rates of 80.7 and 88.3%, respectively, at 20 mg/kg, p.o.) in the rat passive cutaneous anaphylaxis (PCA) test and also exhibited much more potent in vitro inhibitory activity than caffeic acid against the enzyme 5-lipoxygenase (5-LO). Their in vitro antihistamine activity, however, was weaker than that of ketotifen. Compounds 3a and 5a are viewed as promising candidates for antiallergic agents. 相似文献
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