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31.
H. Ueno D. Kameda D. Nagae M. Takemura K. Asahi K. Shimada K. Takase T. Sugimoto T. Nagatomo M. Uchida T. Arai T. Inoue A. Yoshimi T. Kawamura K. Narita 《The European physical journal. Special topics》2007,150(1):185-186
Ground-state magnetic-dipole moments (μ) of 30-32Al and
electric quadrupole moments (Q) of 31,32Al have been measured
with the β-NMR method using spin-polarized radioactive-isotope
beams produced in projectile-fragmentation reactions. Beams of
30-32Al were obtained by using RIKEN projectile-fragment
separator RIPS after the fragmentation of 40Ar projectiles at an
energy of E = 95A MeV on a 93Nb target. The obtained
μexp[30-32Al] and
values agree well with shell-model calculations within the sd
shell using the USD interaction. Also, Qexp[31Al]
was found to be small. Thus, we can conclude that these aluminum
isotopes are located outside the island of inversion. 相似文献
32.
Takayoshi Tsuzuki Natsumi Sakaguchi Dr. Takashi Kudoh Satoshi Takano Masato Uehara Dr. Takashi Murayama Prof. Dr. Takashi Sakurai Dr. Minako Hashii Prof. Dr. Haruhiro Higashida Karin Weber Prof. Dr. Andreas H. Guse Dr. Tomoshi Kameda Dr. Takatsugu Hirokawa Dr. Yasuhiro Kumaki Prof. Dr. Barry V. L. Potter Dr. Hayato Fukuda Dr. Mitsuhiro Arisawa Prof. Dr. Satoshi Shuto 《Angewandte Chemie (International ed. in English)》2013,52(26):6633-6637
33.
Yoko Kameda 《Tetrahedron》2006,62(41):9751-9757
(4R,8R)-4,8-Dimethyldecanal, a common aggregation pheromone of Tribolium flour beetles, has been synthesized from (R)-2,3-O-isopropylideneglyceraldehyde in 11 steps and 7% overall yield. The key step in the synthesis is the highly diastereoselective chelation-controlled radical reaction of ethyl (4S,5R)-4-benzyloxy-5,6-(isopropylidenedioxy)-2-methylenehexanoate with ethyl (R)-5-iodo-3-methylpentanoate performed in the presence of 7 equiv of MgBr2·OEt2. 相似文献
34.
Tamiko Takahashi Hiroaki Kameda Tomoyo Kamei Jyunichi Koyanagi Fabio Pichierri Kenji Omata Miyuki Ishizaki Hiroshi Nakamura 《Tetrahedron: Asymmetry》2013,24(17):1001-1009
Optically active 1-fluoroindan-1-carboxylic acid (FICA) was designed and prepared as its methyl ester for determining the absolute configuration of chiral molecules by both 1H and 19F NMR spectroscopies. Enantiomerically pure isomers of FICA methyl esters (FICA Me esters) were obtained by chromatographic separation using HPLC with a Daicel Chiralcel OJ-H column. The absolute configuration of the (+)-FICA Me ester was deduced to be (S) by X-ray crystallographic analysis of the (+)-FICA amide of (R)-α-phenethylamine. Both enantiomers were derived to the diastereomeric esters of chiral secondary alcohols by an ester exchange reaction. In the 1H NMR spectra, the signs of ΔδH (δR ? δS) were consistent on each side of the FICA molecular plane. Therefore, the concept of the modified Mosher’s method could be successfully applied to the FICA-based procedure. Moreover, the consistency in the signs of ΔδF (δR ? δS) values suggests that the FICA method would be reliable in assigning the absolute configurations of secondary alcohols based on 19F NMR spectroscopy. 相似文献
35.
Toshiaki Yoshioka Tomohito Kameda Masashi Ieshige Akitsugu Okuwaki 《Polymer Degradation and Stability》2008,93(10):1822-1825
Flexible poly(vinyl chloride) (PVC) was found to be dechlorinated in NaOH/ethylene glycol (EG) solution at moderate temperature and at atmospheric pressure. The degree of dechlorination increased over time with all particle sizes and with decreasing particle size. Decreased particle size resulted in an increased effective surface area, increasing the contact between the material and OH− in the NaOH/EG solution, which contributed to the high degree of dechlorination. The dechlorination of flexible PVC in NaOH/EG solution was expressed as a first-order reaction and proceeded under chemical reaction control. Diisononyl-phthalate (DINP) in the flexible PVC powder decomposed readily into phthalic acid and isononyl alcohol in a short time. For the dechlorination of the flexible PVC, the substitution (SN2) of chloride by the hydroxyl group was considered to be preferential to the elimination (E2) of hydrogen chloride. 相似文献
36.
Tomohito Kameda Yuuichi Tsuchiya Takashi Yamazaki Toshiaki Yoshioka 《Solid State Sciences》2009,11(12):2060-2064
This study examined the effect of the interlayer spacing of a Mg–Al layered double hydroxide (Mg–Al LDH) on the ability of the Mg–Al LDH to take up a nonionic organic material. Mg–Al LDHs, intercalated with 1-propanesulfonate (PS?), 1-hexanesulfonate (HS?), and 1-dodecanesulfonate (DS?), were prepared by coprecipitation, yielding PS·Mg–Al LDH, HS·Mg–Al LDH, and DS·Mg–Al LDH, respectively. The increase in the alkyl chain lengths of the Mg–Al LDHs (PS? < HS? < DS?) resulted in the perpendicular orientation of the organic acid anions in the interlayer of Mg–Al LDH, which in turn resulted in more organic acid anions being accommodated in the interlayer space. An organic acid anion with a large molecular length was more easily intercalated in the interlayer of Mg–Al LDH than one with a small molecular length. This was attributed to the hydrophobic interaction between the alkyl chains, affecting the intercalation of the organic acid anions. The uptake of N,N-dimethylaniline (DMA) by Mg–Al LDHs increased in the order PS·Mg–Al LDH < HS·Mg–Al LDH < DS·Mg–Al LDH. The uptake was attributed to the hydrophobic interactions between DMA and the intercalated PS?, HS?, and DS?. Thus, Mg–Al LDH, which has a lot of large interlayer spacings when intercalated with organic acid anions, can take up a large number of DMA molecules from an aqueous solution. 相似文献
37.
Sodium hydroxide-assisted dechlorination of a poly(vinylidene chloride)-containing wrapping film in ethylene glycol solution 总被引:1,自引:0,他引:1
Tomohito Kameda 《Polymer Degradation and Stability》2010,95(12):2663-2665
Poly(vinylidene chloride) (PVDC) wrapping film was dechlorinated using solutions of NaOH in ethylene glycol (EG) at temperatures between 150 and 190 °C. The reaction was comparable to that for PVDC powder; however, it occurred at a lower NaOH concentration, which can be explained by the dissolution of additives present in the wrapping film. Therefore, the best results for the dechlorination of the wrapping film were obtained at a temperature of 190 °C and NaOH concentrations of 0.1 M and 0.5 M, resulting in dechlorination yields of almost 90% after 135 min. For the dechlorination reaction, the activation energy of the PVDC wrapping film (185 kJ mol−1) was determined to be higher than that of PVDC powder; this finding could be attributed to the presence of a stabilizer and the smaller surface area of the PVDC wrapping film. 相似文献
38.
Tomohito Kameda Guido Grause Toshiaki Yoshioka 《Polymer Degradation and Stability》2009,94(1):107-112
The reaction of poly(vinyl chloride) (PVC) in nucleophile (Nu)/ethylene glycol (EG) or Nu/N,N-dimethylformamide (DMF) solution was found to result in the substitution of Cl in PVC with Nu from solution, in addition to the straight elimination of HCl, both of which led to the dechlorination of PVC. Examined Nu− were I−, SCN−, OH−, N3−, and the phthalimide anion. For the Nu/EG solution, elimination was favoured over substitution for all Nu−. The ratio of substitution to dechlorination was notable, descending in the order OH− > SCN− = N3− > phthalimide anion > I−. For the Nu/DMF solution, the ratio of substitution to dechlorination was high, in the order SCN− > N3− > I− > phthalimide anion. In both cases, the orders of the ratios were similar to those of the nucleophilic reactivity constant, I− > SCN− > N3− > phthalimide anion, except for I−. The low ratio for I− was attributable to the elimination of HI after the substitution of Cl in PVC with I in solution, because I− is a strong nucleophile, as well as an excellent leaving group. Comparing the effect of EG and DMF on the substitution of Cl in PVC with Nu in solution, the ratio of substitution to dechlorination was higher for I−, SCN−, N3−, and the phthalimide anion in DMF than in EG. The substitution of Cl in PVC with Nu in solution was found to occur preferentially in DMF versus EG. 相似文献
39.
40.
Malek M Morii M Fukuda S Fukuda Y Ishitsuka M Itow Y Kajita T Kameda J Kaneyuki K Kobayashi K Koshio Y Miura M Moriyama S Nakahata M Nakayama S Namba T Okada A Ooyabu T Saji C Sakurai N Shiozawa M Suzuki Y Takeuchi H Takeuchi Y Totsuka Y Yamada S Desai S Earl M Kearns E Messier MD Stone JL Sulak LR Walter CW Goldhaber M Barszczak T Casper D Gajewski W Kropp WR Mine S Liu DW Smy MB Sobel HW Vagins MR Gago A Ganezer KS Keig WE Ellsworth RW Tasaka S Kibayashi A Learned JG Matsuno S Takemori D 《Physical review letters》2003,90(6):061101
A search for the relic neutrinos from all past core-collapse supernovae was conducted using 1496 days of data from the Super-Kamiokande detector. This analysis looked for electron-type antineutrinos that had produced a positron with an energy greater than 18 MeV. In the absence of a signal, 90% C.L. upper limits on the total flux were set for several theoretical models; these limits ranged from 20 to 130 macro nu(e) cm(-2) s(-1). Additionally, an upper bound of 1.2 macro nu(e) cm(-2) s(-1) was set for the supernova relic neutrino flux in the energy region E(nu)>19.3 MeV. 相似文献