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Hisao Kameda Eitan Altman Corinne Touati Arnaud Legrand 《Mathematical Methods of Operations Research》2012,76(1):43-65
There are several approaches of sharing resources among users. There is a noncooperative approach wherein each user strives to maximize its own utility. The most common optimality notion is then the Nash equilibrium. Nash equilibria are generally Pareto inefficient. On the other hand, we consider a Nash equilibrium to be fair as it is defined in a context of fair competition without coalitions (such as cartels and syndicates). We show a general framework of systems wherein there exists a Pareto optimal allocation that is Pareto superior to an inefficient Nash equilibrium. We consider this Pareto optimum to be ??Nash equilibrium based fair.?? We further define a ??Nash proportionately fair?? Pareto optimum. We then provide conditions for the existence of a Pareto-optimal allocation that is, truly or most closely, proportional to a Nash equilibrium. As examples that fit in the above framework, we consider noncooperative flow-control problems in communication networks, for which we show the conditions on the existence of Nash-proportionately fair Pareto optimal allocations. 相似文献
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Munetaka Takeuchi Yasuo Kameda Yasuhiro Umebayashi Sari Ogawa Takaaki Sonoda Shin-ichi Ishiguro Miho Fujita Mitsuru Sano 《Journal of Molecular Liquids》2009,148(2-3):99-108
Self-diffusion coefficients of Li+ DLi+, PF6− DPF6− and solvent propylene carbonate (PC) DPC in LiPF6−PC solutions were determined at 298 K by the pulse gradient spin echo (PGSE) NMR technique over the salt concentration range of 0.1–3.0 M (M = mol dm– 3). The order of the diffusion coefficients was found to be DLi+ < DPF6− < DPC over the concentration range examined, and they were monotonically decreased with increasing the salt concentration. Haven ratio Λ/ΛNMR, where Λ and ΛNMR represent the ionic conductivity measured electrochemically and that estimated via the Nernst-Einstein equation using the diffusion coefficient, respectively, was evaluated as the measure of the ion–ion interaction in the LiPF6–PC solutions. Though Λ/ΛNMR values for LiPF6-solutions decrease with increasing the salt concentration, they were greater than those for LiBF4–PC solutions over the whole concentration range examined, which indicates that the ion pair formation ability of PF6– ion is weaker than that of the BF4– ion. The smaller value of the ionic conductivity for the highly concentrated LiPF6–PC solution (above 2.0 M) than that of the LiBF4-solutions can be attributed to the more rapidly increased viscosity relative to the LiBF4-solution. Classic molecular dynamics (MD) simulations for the respective LiPF6 and LiBF4-solution of 0.5 and 1.0 M were also carried out based on the effective pair potentials. Diffusion coefficients, ionic conductivity and Haven ratio for these solutions were calculated from MD trajectories, and they qualitatively agree with those evaluated by experiments. Pair correlation functions gLiO(r) (for Li+–O (PC) pair) and gLiPF6(r) (for Li+–PF6– pair) or gLiBF4(r) (for Li+–BF4– pair) revealed that the lithium ion weakly forms the contact ion pairs with PF6–, whilst strongly with BF4–, which supports the present experimental results. Moreover, the simulation results show that both anions in the contact ion pairs predominantly take the monodentate form, which is in contrast to the multidentate coordination predicted by ab initio calculation in gas phase. 相似文献
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Tomohito Kameda Katsuaki Imai Guido Grause Tadaaki Mizoguchi Toshiaki Yoshioka 《Polymer Degradation and Stability》2009,94(9):1595-1597
The dehydrochlorination of PVC in the presence of NaOH was investigated in different diols. Diethylene glycol (DEG), triethylene glycol (TEG), and propylene glycol (PG) were found to be effective in accelerating the dechlorination of PVC. The dehydrochlorination was promoted in the order TEG > DEG > PG, which was in agreement with the compatibility between PET and the diol. Compatibility resulted in an improved penetration of the PVC particle by the solvent, leading to the acceleration of the dehydrochlorination. The dehydrochlorination of PVC in NaOH/diol followed first-order kinetics, confirming the progress of the reaction under chemical reaction control. The apparent activation energies were 82 kJ mol−1, 109 kJ mol−1, and 151 kJ mol−1 for TEG, DEG, and PG, respectively. The lower the activation energy became the faster the dehydrochlorination of PVC proceeded. 相似文献
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Yamamoto S Zhang Y Yamaguchi T Kameda T Kato K 《Chemical communications (Cambridge, England)》2012,48(39):4752-4754
A novel methodology is presented for evaluating a dynamic ensemble of oligosaccharide conformations by lanthanide-assisted NMR spectroscopy combined with molecular dynamics (MD) simulations. The results obtained using the GM3 trisaccharide demonstrated that pseudocontact shift measurements offer a valuable experimental tool for the validation of MD simulations of highly flexible biomolecules. 相似文献
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The change in the conformation of the flexible O-CH2-CH2-CH2-O segment of poly(trimethylene terephthalate) (PTT) monofilament caused by drawing was investigated by means of the gamma-gauche effect on the 13C solid-state NMR chemical shift of the internal methylene carbon, combined with the NMR relaxations. The conformation around the O-CH2 and CH2-O bonds for as-spun fiber was trans/trans. On drawing, followed by heat treatment, the conformation changed to gauche/gauche. The ratio of gauche/gauche to trans/trans for the drawn PTT fiber was determined quantitatively. 相似文献
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Yamamoto Y Terui N Tachiiri N Minakawa K Matsuo H Kameda T Hasegawa J Sambongi Y Uchiyama S Kobayashi Y Igarashi Y 《Journal of the American Chemical Society》2002,124(39):11574-11575
Paramagnetic NMR and optical studies of the oxidized forms of mesophile Pseudomonas aeruginosa cytochrome c(551) and its quintuple mutant (F7A/V13M/F34Y/E43Y/V78I), and thermophile Hydrogenobacter thermophilus cytochrome c(552) demonstrated that the amino acid side chain packings in the protein interior influence the coordination bond between the heme iron and the axial methionine in the proteins. The strength of heme axial coordinations was found to correlate with the overall protein thermostability. 相似文献
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Tomohito Kameda Saya Ito Toshiaki Yoshioka 《Journal of Dispersion Science and Technology》2017,38(7):1063-1066
We found that activated carbon effectively removed urea from solution and that urea adsorption onto activated carbon followed a pseudo-second-order kinetic model. We classified the urea adsorption on activated carbon as physical adsorption and found that it was best described by the Halsey adsorption isotherm, suggesting that the multilayer adsorption of urea molecules on the adsorption sites of activated carbon best characterized the adsorption system. The mechanism of adsorption of urea by activated carbon involved two steps. First, an amino (–NH2) group of urea interacted with a carbonyl (–C?O) group and a hydroxyl (?OH) group on the surface of activated carbon via dipole–dipole interactions. Next, the –C?O group of the urea molecule adsorbed to the activated carbon interacted with another –NH2 group from a second urea molecule, leading to multilayer adsorption. 相似文献
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