Effect of fiber content and surface treatment on the mechanical properties of natural fiber composites produced by rotomolding

In this study, natural fibers (agave, coir, and pine) were surface treated with maleated polyethylene (MAPE) with two main objectives: (1) to improve the mechanical properties of natural fiber composites produced by rotational molding and (2) to increase the fiber content in the composite. The rotomolded composites were produced at 0, 10, 20, 30, and 40% wt. of fiber contents (treated or untreated) and characterized in terms of morphology and mechanical properties (hardness, impact, tension, and flexion). The results showed that MAPE surface treatment was more successful for agave and coir than for pine fibers due to their respective chemical composition. In general, surface treatment led to better fiber distribution and a more uniform composite morphology allowing the possibility to use higher fiber contents in rotational molding. At low fiber contents (10 and 20% wt.), the mechanical properties were improved using treated fiber composites (TFC) compared to the neat polymer and untreated fiber composites (UFC). Although the mechanical properties of TFC decreased at high fiber contents (30 and 40% wt.), they were substantially higher (about 160, 400, and 100% for impact, tensile, and flexural properties, respectively) than for UFC.     

Chemical Vapor Deposition of Phase‐Pure Uranium Dioxide Thin Films from Uranium(IV) Amidate Precursors

Homoleptic uranium(IV) amidate complexes have been synthesized and applied as single‐source molecular precursors for the chemical vapor deposition of UO₂ thin films. These precursors decompose by alkene elimination to give highly crystalline phase‐pure UO₂ films with an unusual branched heterostructure.     

Effect of Oil Spill on Birds: A Graphical Assay of the Deepwater Horizon Oil Spill’s Impact on Birds

The Deepwater Horizon oil spill was an ecologically devastating event in the Gulf of Mexico, which saw the estimated release of over 4 million barrels of oil after flowing for three months in 2010. The US Fish and Wildlife Service provided a data set of 7,229 bird records. We aimed to illustrate the important features of the data set utilizing a blend of analytics and graphics executed through traditional and cloud-based software. It is concluded from the graphs that the areas containing the greatest concentration of birds were nearest to the coasts adjacent to New Orleans and the Deepwater platform. Moreover, the result of the logistic regression confirmed what is seen in bar charts, that the Laughing Gull and Brown Pelican, among many others, were most mortally impacted by the oil spill. Furthermore, additional investigation into the morbidity impact on birds over time indicates a lagging effect. A similar lag is present in the oiling of the birds where a separate time series shows the oiled/not visibly oiled birds alternating in frequency over the collection period.     

Catalytic Hydrogen Production by Ruthenium Complexes from the Conversion of Primary Amines to Nitriles: Potential Application as a Liquid Organic Hydrogen Carrier

The potential application of the primary amine/nitrile pair as a liquid organic hydrogen carrier (LOHC) has been evaluated. Ruthenium complexes of formula [(p‐cym)Ru(NHC)Cl₂] (NHC=N‐heterocyclic carbene) catalyze the acceptorless dehydrogenation of primary amines to nitriles with the formation of molecular hydrogen. Notably, the reaction proceeds without any external additive, under air, and under mild reaction conditions. The catalytic properties of a ruthenium complex supported on the surface of graphene have been explored for reutilization purposes. The ruthenium‐supported catalyst is active for at least 10 runs without any apparent loss of activity. The results obtained in terms of catalytic activity, stability, and recyclability are encouraging for the potential application of the amine/nitrile pair as a LOHC. The main challenge in the dehydrogenation of benzylamines is the selectivity control, such as avoiding the formation of imine byproducts due to transamination reactions. Herein, selectivity has been achieved by using long‐chain primary amines such as dodecylamine. Mechanistic studies have been performed to rationalize the key factors involved in the activity and selectivity of the catalysts in the dehydrogenation of amines. The experimental results suggest that the catalyst resting state contains a coordinated amine.     

Effects of Small Signal Injection on Laser Diode Pumped Hybrid Bistable System with Large Delay

Effects of small signal injection on an electro-optical bistable system with a very large delay are theoretically and experimentally investigated from the viewpoint of linear stability analysis. The resonance phenomena and frequency locking are observed when sinusoidal and rectangular small signals are additively injected into the system. Experiments confirm that theoretical results obtained by linear stability analysis are good predictions of the effects of both resonance and frequency-locking phenomena and show the dependence of these phenomena on the system parameters. As an application of the frequency locking phenomenon to the dynamical memory, the phase identification of the memory oscillation using the frame pulse externally injected is successfully executed.     

Cyclization reactions of 4-(3′-butenyl)azetidin-2-one a route to the carbopenam ring system

Cyclization of 4-(3′-butenyl)azetidin-2-one, $\text{2}$ initiated by electrophilic reagents such as I₂, Hg(OAc)₂ results in the formation of bicyclic β-lactams having the carbopenam ring skeleton. Reaction of $\text{2}$ with Br₂ results in simple addition of Br₂ to the double bond, while PhSBr gives a mixture of cyclization and addition products.     

Facile solid-phase synthesis of sulfated tyrosine-containing peptides: Part II. Total synthesis of human big gastrin-II and its C-terminal glycine-extended peptide (G34-Gly sulfate) by the solid-phase segment condensation approach

Application of the fluoren-9-ylmethoxycarbonyl (Fmoc)-based solid-phase segment condensation approach to the preparation of sulfated peptides was investigated through the synthesis of human big gastrin-II, a 34-residue sulfated tyrosine [Tyr(SO3H)]-containing peptide. Highly acid-sensitive 2-chlorotrityl resin (Clt resin) was exclusively employed as an anchor-resin for the preparation of the three peptide segments having the C-terminal Pro residue as well as of the Tyr(SO3H)-containing resin-bound segment. By using the PyBOP-mediated coupling protocol [PyBOP=benzotriazolyloxytris(pyrrolidino)phosphonium hexafluorophosphatel, we successively condensed each segment and constructed the 34-residue peptide-resin without any difficulty. The final acid treatment of the fully protected peptide-resin at low temperature (90% aqueous TFA, 0 degree C for 8 h), which can detach a Tyr(SO3H)-containing peptide from the resin and remove the protecting groups concurrently with minimum deterioration of the sulfate, afforded a crude sulfated peptide. After one-step HPLC purification, a highly homogeneous human big gastrin-II was easily obtained in 14% yield from the protected peptide-resin. The sulfate form of the C-terminal glycine-extended gastrin (G34-Gly sulfate), a posttranslational processing intermediate of gastrin-II, was also successfully prepared with the segment condensation approach (11% yield). These results demonstrated the usefulness of the segment condensation protocol for preparing large Tyr(SO3H)-containing peptides.