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41.
42.
The CuX2-mediated reaction of enynal units, including ortho-alkynylbenzaldehydes, with alkynes gives a variety of haloaromatic compounds stereoselectively in good to high yields. 2,2′-Binaphthyl skeletons are also readily prepared by the reaction of ortho-alkynylbenzaldehydes and diynes. The method was applied to the synthesis of poly-substituted tetracene derivatives. 相似文献
43.
Tashiro Shinichi Miki Satoshi Murphy Anthony B. Tanaka Manabu Kisaka Yuji Kimura Fumiaki Suwa Tomone Takahashi Yoshikazu 《Plasma Chemistry and Plasma Processing》2022,42(1):229-245
Plasma Chemistry and Plasma Processing - In arc welding, a groove is often used between metal pieces being welded. In tungsten inert gas welding of high-manganese stainless steels with arc voltage... 相似文献
44.
Size, shape, and density‐controlled metal nanostructure, Au nanodot lattices fabricated by electron beam lithography, were embedded in thin organic solar cell consisting of PC71BM:PCPDTBT. The effects of their size and density on device performance were examined. Even though dipole res‐onances of Au nanodots were consistent with the absorption range of the active materials, there were no improvements in device performance under any sizes and densities. In addition, under high volume density of Au nanodots to PEDOT:PSS layer, the device performance was deteriorated. These results indicated that not only size and density but also other factors which determine light scattering characteristics greatly affect the device performance of solar cells. (© 2015 WILEY‐VCH Verlag GmbH &Co. KGaA, Weinheim) 相似文献
45.
Reaction of lithium alpha-sulfinyl carbanions of 1-chloroalkyl p-tolyl sulfoxides with ketones or aldehydes at low temperature gave adducts in almost quantitative yields. Treatment of the adducts derived from ketones with trifluoroacetic anhydride (TFAA) in the presence of NaI in acetone gave alpha-sulfanyl allylic alcohols in good to quantitative yields. On the other hand, treatment of the adducts derived from aldehydes with TFAA and NaI resulted in the formation of alpha-sulfanyl ketones and/or alpha-sulfanyl allylic alcohols. These reactions offer a good method for the synthesis of the above-mentioned compounds from ketones and aldehydes with carbon-carbon bond-formation in two steps and in good yields. 相似文献
46.
Kou Hiroya Yusuke Ichihashi Yoshihiro Suwa Tetsuro Ikai Kiyofumi Inamoto Takayuki Doi 《Tetrahedron letters》2010,51(29):3728-3731
The C2-side chain hydroxyl group of 1,3-cycloalkanedione discriminates between two ketones depending on its chirality. It chooses one ketone to form hydrogen bond with the oxygen atom of the TBDPS-oxymethyl group, but chooses the other ketone upon conversion to the isopropyl acetal. Two optically pure diastereomers, whose absolute configuration at the angular position is opposite for each other, were thus synthesized from this single chiral source through simple operations. This method may be applied for the synthesis of a variety of compounds with asymmetric quaternary centers. 相似文献
47.
Hisayuki Horai Masanori Arita Shigehiko Kanaya Yoshito Nihei Tasuku Ikeda Kazuhiro Suwa Yuya Ojima Kenichi Tanaka Satoshi Tanaka Ken Aoshima Yoshiya Oda Yuji Kakazu Miyako Kusano Takayuki Tohge Fumio Matsuda Yuji Sawada Masami Yokota Hirai Hiroki Nakanishi Kazutaka Ikeda Naoshige Akimoto Takashi Maoka Hiroki Takahashi Takeshi Ara Nozomu Sakurai Hideyuki Suzuki Daisuke Shibata Steffen Neumann Takashi Iida Ken Tanaka Kimito Funatsu Fumito Matsuura Tomoyoshi Soga Ryo Taguchi Kazuki Saito Takaaki Nishioka 《Journal of mass spectrometry : JMS》2010,45(7):703-714
MassBank is the first public repository of mass spectra of small chemical compounds for life sciences (<3000 Da). The database contains 605 electron‐ionization mass spectrometry(EI‐MS), 137 fast atom bombardment MS and 9276 electrospray ionization (ESI)‐MSn data of 2337 authentic compounds of metabolites, 11 545 EI‐MS and 834 other‐MS data of 10 286 volatile natural and synthetic compounds, and 3045 ESI‐MS2 data of 679 synthetic drugs contributed by 16 research groups (January 2010). ESI‐MS2 data were analyzed under nonstandardized, independent experimental conditions. MassBank is a distributed database. Each research group provides data from its own MassBank data servers distributed on the Internet. MassBank users can access either all of the MassBank data or a subset of the data by specifying one or more experimental conditions. In a spectral search to retrieve mass spectra similar to a query mass spectrum, the similarity score is calculated by a weighted cosine correlation in which weighting exponents on peak intensity and the mass‐to‐charge ratio are optimized to the ESI‐MS2 data. MassBank also provides a merged spectrum for each compound prepared by merging the analyzed ESI‐MS2 data on an identical compound under different collision‐induced dissociation conditions. Data merging has significantly improved the precision of the identification of a chemical compound by 21–23% at a similarity score of 0.6. Thus, MassBank is useful for the identification of chemical compounds and the publication of experimental data. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
48.
Otsuki J Suwa K Narutaki K Sinha C Yoshikawa I Araki K 《The journal of physical chemistry. A》2005,109(35):8064-8069
The isomerization behaviors of 2-(phenylazo)imidazole (Pai-H) and 1-N-methyl-2-(phenylazo)imidazole (Pai-Me) have been investigated. The crystal structure of trans-Pai-Me was determined, revealing that key structures around the azo group are nearly identical among azobenzene, Pai-H, and Pai-Me. Pai-Me undergoes reversible cis/trans photoisomerization, whereas Pai-H responds poorly to irradiation. The quantum yields of trans-to-cis isomerization of Pai-Me on 454 and 355 nm excitation are 0.35 +/- 0.03 and 0.25 +/- 0.03, respectively, in toluene. The wavelength-dependent isomerization quantum yield is well-known for azobenzene, but these values are substantially higher than those of azobenzene. The activation energy of thermal cis-to-trans isomerization of Pai-Me in toluene is 79.0 +/- 3.5 kJ mol(-1), which is lower than that of azobenzene by 15 kJ mol(-1). The thermal cis-to-trans isomerization of Pai-H is even faster. Density functional theory calculations were performed, revealing that the energy gaps between the azo n-orbital and the highest pi-orbital of azoimidazoles are much narrower than that of azobenzene. Finally, a preliminary study suggested that metal ions can modulate the absorption spectrum of Pai-Me without a loss of the gross photochromic behavior. 相似文献
49.
[reaction: see text] The Stille coupling of N-acyl-2-iodoanilines with the 1-(tributylstannyl)-1-substituted allenes affected the successive one-step formation of the 2-methyl-3-substituted indoles. Alternatively, the other type of 2-alkyl-3-substituted indoles could be synthesized in a one-pot operation, which consists of the Stille coupling reaction with the 1-(tributylstannyl)-1,3-disubstituted allenes, followed by TBAF treatment. This procedure could be applied to the synthesis of indomethacin. 相似文献
50.
Y. Masada K. Hashimoto T. Inoue Y. Sumida T. Kishi Y. Suwa 《Journal of separation science》1979,2(7):400-404
A novel method is described for the preparation of stable glass capillary columns (glass open tubular columns), including the etching and formation of a polymer film on the inner glass capillary surfaces. The approach used here is based on low-temperature plasma etching and polymerization. Under the influence of a field of radio frequency discharge, low pressure gases of fluoric compounds, introduced into the glass capillary tube, generate excited fluorine radicals which etch the inner surface. The plasma of organosilicone monomer in the glass capillary yields a uniform polymerized film on the inner surface. The resultant material functions as a good stationary phase for glass capillary gas chromatography (GC2). The inner surfaces treated with such a plasma, can be studied by means of a scanning electron microscope (SEM). The flexibility of this method permits the use of various stationary phases and surface modification. 相似文献