排序方式: 共有48条查询结果,搜索用时 0 毫秒
41.
Taichi Kano Dr. Yukako Yamaguchi Keiji Maruoka Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(27):6678-6687
Amino sulfonamide catalyst : A distal proton of the axially chiral amino sulfonamide (S)‐ 1 realized the opposite diastereoselectivity in Mannich and cross‐aldol reactions compared with that observed in proline‐catalyzed reactions. The reactions catalyzed by (S)‐ 1 proceeded smoothly to give the anti‐Mannich and syn‐aldol adducts in excellent enantioselectivity (see scheme).
42.
Pinky A. Bautista Tokiya Abe Masahiro Yamaguchi Yukako Yagi Nagaaki Ohyama 《Optical Review》2005,12(1):7-14
Histological structures of a pathological tissue sample convey information relevant to the diagnosis of the disease that might have afficted the person. To reveal the morphology of these structures clearly, pathological tissues are stained. In this paper, a digital staining methodology for pathological tissue samples is introduced. Digital staining implies the application of digital processing techniques to transform the image of an unstained sample to its stained image counterpart. In the method, the transmittance spectra of the unstained and Hematoxylin and Eosin (H&E) stained multispectral images (16 bands) of specific tissue components are utilized. Two experiments were conducted to probe the possibility of the digital staining framework: the linear mapping of spectral transmittances, and the classification of spectral transmittances in conjunction with the linear mapping of specific transmittance data sets. The method classified the four tissue components, e.g. nucleus, cytoplasm, red blood cells, and the white region (region devoid of tissue structures), while the misclassifications between components with spectral transmittances that are closely similar were not completely rectified. © 2005 The Optical Society of Japan 相似文献
43.
Yasuda T Yoshimura Y Yabuki H Nakazawa T Ohsawa K Mimaki Y Sashida Y 《Chemical & pharmaceutical bulletin》2003,51(12):1426-1428
During the course of our systematic investigation of the metabolism of flavonoids, the polymethoxyflavone nobiletin, occurring in the fruits of Citrus depressa, was orally administered to rats. The urinary metabolites were separated and identified by three-dimensional HPLC equipped with a photodiode array detector and the structure was determined by spectroscopic methods to be 4'-hydroxy-3',5,6,7,8-pentamethoxyflavone (1). 相似文献
44.
Sadao Nishigaki Hashime Kanazawa Yukako Kanamori Misuzu Ichiba Keitaro Senga 《Journal of heterocyclic chemistry》1982,19(6):1309-1312
A new synthesis of certain pyrimido[5,4-e]-as-triazine 4-oxides and their ring transformation to pyrrolo-[3,2-d]pyrimidines by the 1,3-dipolar cycloaddition reaction is described. Thus, reaction of 6-hydrazino-1,3-dimethyluracil ( 1 ) with triethyl orthoformate gave 6-ethoxymethylenehydrazino-1,3-dimethyluracil ( 2 ). Treatment of 2 with arylamines gave 6-arylaminomethylenehydrazino-1,3-dimethyluracils ( 3a-e ). Nitrosative cyclization of 3a-e with sodium nitrite afforded 3-arylaminofervenulin 4-oxides ( 6a-e ). Reaction of 6a-e with acetylenic esters yielded 7-alkoxycarbonyl-6-arylamino-1,3-dimethylpyrrolo[3,2-d]pyrimidine-2,4(1H,3H-diones ( 15a-e and 16 ). 相似文献
45.
[reaction: see text] Ring-closing metathesis of ene-ynamide using the second-generation Grubbs' catalyst produced nitrogen-containing heterocycles, which have dienamide moieties, in high yields. Diels-Alder reaction of the cyclized product and dienophile proceeded smoothly to afford a bi- or tricyclic compound. 相似文献
46.
[reaction: see text] The use of 1-tert-butoxy-2-tert-butoxycarbonyl-1,2-dihydroisoquinoline (BBDI) as tert-butoxycarbonylation reagent for aromatic and aliphatic amine hydrochlorides and phenols in the absence of a base has been demonstrated. The reactions proceed chemoselectively in high yield under mild conditions. 相似文献
47.
Matsui F Matsushita T Kato Y Hashimoto M Inaji K Guo FZ Daimon H 《Physical review letters》2008,100(20):207201
Up until now there has been no direct method for detecting the electronic and magnetic structure of each atomic layer at the surface, which is an essential analysis technique for nanotechnology. For this purpose, we have developed a new method, diffraction spectroscopy, based on the photon energy dependence of the angular distribution of Auger electron emission. We have applied this method to analyze the magnetic structure of a Ni ultrathin film on a Cu(001) surface around the spin reorientation transition. Atomic-layer resolved x-ray absorption and magnetic circular dichroism spectra were obtained. Surface and interior core-level shifts and magnetic moments are determined for each atomic layer individually. 相似文献
48.