LaSrBO4型复合氧化物的合成及其CO氧化活性研究

LaSrBO4(B=Cu、Ni、 Co、 Fe、 Mn、 Cr ) was studied with respect to their preparation, characteristics and catalytic oxidation activity by means of XRD, XPS, electric conductivity and activity evaluation. Results showed that the calcination temperature has great influence on the formation of the phases of such samples, and was associated with the radius of B ion. The greater the B ion radius, the higher the calcination temperature required for the formation of the phases. It was also found that the activity and the relative content of adsorptive oxygen and lattice oxygen on the sample surf are, the activation energy of electron conduction and the CO oxidation activity may vary with different B ions, and demonstrate a dual-peak pattern with the increase in the number of 3d electrons of the B ion.     

Numerical blow-up analysis of the explicit L1-scheme for fractional ordinary differential equations

Numerical Algorithms - This paper deals with the blow-up behavior of numerical solutions to nonlinear fractional ordinary differential equations with a dissipative term. Based on the positivity...     

A Review of Results on Axially Symmetric Navier-Stokes Equations,with Addendum by X. Pan and Q. Zhang

In this paper, we give a brief survey of recent results on axially symmetric Navier-Stokes equations (ASNS) in the following categories: regularity criterion, Liouville property for ancient solutions, decay and vanishing of stationary solutions. Some discussions also touch on the full 3 dimensional equations. Two results, closing of the scaling gap for ASNS and vanishing of homogeneous D solutions in 3 dimensional slabs will be described in more detail.In the addendum, two new results in the 3rd category will also be presented, which are generalizations of recently published results by the author and coauthors.     

The critical exponent of degenerate parabolic systems

The Cauchy problemu _t=u +v ^p ,v _t =v +u ^q is studied, wherex R ^N , 0 <t < and ,,p andq, are positive exponents. It is proved that ifp,q 1 and 1 <pq < 1 + 2 max(p + ,q + )/n then every nontrivial non-negative solution is not global in time; whereaspq > 1 + 2 max(p + , q + )/n then there exist both positive global solutions and non-global solutions. In addition, the decaying in time of solutions tou _t,=u inR ⁿ × (0, ), an equation which occurs naturally in our study of above systems, is studied and solutions with the fastest decaying in time are constructed.     

Regularity of minimizers of non-isotropic integrals of the calculus of variations

The regularity of the minimizers of a special type of non-isotropic variational minimization problem is studied. The particularity of the potential of energy is that it has different growth rate with respect to different parts of the derivatives of the function. In particular, the model treated in this paper can be described as $$\Phi (Du) = |\partial _1 u|^2 + |\partial _2 u|^2 + |\partial _3 u|^2 + |\partial _3 u - |^p .$$ By using a result of P.Marcellini (cf. [4]) and perturbation method, it is proved that the minimizer of the Dirichlet boundary value problem is a function of W _loc ^{1, ∞} .     

烯烃聚合均相催化剂研究进展

均相催化剂产生于５０年代末期，但由于活性很低而末引起重视。８０年代初，由于发现ＭＡＯ具有良好的助催化能力而使均相催化剂得到了很大发展，涌现了多种催化体系，广泛地使α－烯烃及其衍生物立体选择性聚合，开辟了配位聚合研究的新领域，本文对均相催化剂的产生，发展及现状作了综述评述。     

激光光散射研究丙烯酰胺-二甲基二烯丙基氯化铵共聚物的溶液行为

用激光光散射技术表征了阳离子含量受控的丙烯酰胺 二甲基二烯丙基氯化铵共聚物 (简称P(AM DMDAAC) )在 0 1mol LNaCl溶液中的基本参数和溶液行为 .表观基本参数 : Mw ,app =5 0 4× 10 5g·mol- 1 、app =39 9nm和A2 ,APP =1 5× 10 - 4cm3·mol·g- 2 .动态光散射研究结果表明 ,扩散系数Dt 与角度、浓度皆呈非线性依赖关系 ,当C >C 或在较大的散射角域 ,Dt 偏离线性关系所预示的理论值而向减小的方向发展 ,表明存在缔合物 ;流体力学半径Rh 分布有大、小两个范围 ,并随温度升高向小尺寸方向发展 ,证明了体系中存在缔合行为以及升温的解缔合作用 .在一定条件下 ,“亚稳定性”的存在有力地旁证了体系的缔合行为     

Measurements of HO2 uptake coefficient on aqueous (NH4)2SO4 aerosol using aerosol flow tube with LIF system

The γ(HO₂) was elevated with increase of Cu(II) concentrations in aqueous (NH₄)₂SO₄ aerosol. The threshold of Cu(II) concentration was 10^-3 mol/L for the dramatic increase of γ(HO₂) to 0.1, suggesting sensitive γ(HO₂) value to concentration of transition metal ions in aerosol.