Preparation and photocrosslinking behaviors of polyesters derived from trans-2,2′-dihydroxystilbene

The monomer, trans-2,2′-dihydroxystilbene (DHS), has been prepared by asymmetric photocleavage (254 nm) of coumarin dimer acid derived from coumarin dimer. Four new polyesters are successfully synthesized by interfacial polycondensation of the DHS with adipoyl chloride, azelaoyl chloride, sebacoyl chloride, and dodecanedioyl dichloride, respectively. The reduced viscosities of the polyesters decrease from 0.32 to 0.11 dL/g as the number of methylene unit in diacid chlorides increases from 4 to 10. From DSC investigation, it is found that the polyesters are semi-crystalline polymers with T_m = 39–192°C. Under 350 nm light, photocrosslinking behavior in solution and film-state is investigated by UV spectral change with irradiation time (350 nm). The photoreactive stilbene chromophores in the main chain dimerize to form cyclobutane derivatives, and lead to crosslinking of the polyesters. Photosensitivity in the film state has also been evaluated by their characteristic curves. Polyester from dodecanedioyl dichloride ( 5d ) exhibits the highest initial reaction rate and ultimate crosslinking ratio. © 1995 John Wiley & Sons, Inc.     

Transient conjugated mixed-convective heat transfer in a vertical plate channel with one wall heated discretely

 This study presents a numerical solution of the unsteady conjugated mixed-convection heat transfer in a vertical plate channel with one wall suddenly subjected to either isoflux or isothermal discrete heat sources. The effects of the dimensionless heat source length H ₁, the dimensionless spacing between heat sources H ₂, the dimensionless channel length L, the dimensionless heated-plate thickness B _l, the wall-to-fluid conductivity ratio K and the ratio of Grashof number to Reynolds number Gr/Re on the interface heat flux, Nusselt number and bulk fluid temperature are discussed in detail. Results show that the discrete heating can cause the heat transfer direction conversely from the fluid to the heated plate during the transient period, which is more significant for the cases with larger L and H ₂. For the system with isoflux discrete heat sources, the time required to reach the steady-state is shorter for larger H ₂. While the trend is reverse for system with isothermal discrete heat sources. Additionally, a higher ratio of the input energy is axially conducted through the plate wall from heated sections to unheated regions for a larger H ₂ and B _l or smaller L. Received on 9 November 1998     

Circular Dichroism Measurements on C-Terminal Fragment of Heat Shock Protein from Rat

The secondary structure of the C-terminal fragment (10 kDa) of rat hsc70 (a. a. #546–646) was analyzed according to circular dichroism spectra. In the pH range 5–9 and at concentrations of Na+ up to 0.18 M, the protein is estimated to contain 32-34% a helix, 18–16% of β sheet, approximately 25% for both turns and disordered structures. This protein is most stable at pH between 6 and 7 in solution with 0.055 M Na⁺ concentration. However, all T_m are relatively large (57–73 °C) and alterations from one condition to another are small. Thus, the C-fragment (10 kDa) of hsc70 is a stably folded protein under physiological conditions.     

Remarks on the Convergence Rate of the Spectral Distributions of Wigner Matrices

In this remark, we show that under the assumption of the finite fourth moment elements in the empirical spectral distribution of a large Wigner matrix converges to the Wigner semicircular law in probability of the order O(n ^–1/3).     

Combined heat and mass transfer in laminar gas stream flowing over an evaporating liquid film

A numerical analysis was carried out to study the detailed heat and mass transfer characteristics in laminar gas stream flowing over a falling liquid water film by solving the respective governing equations for the liquid film and gas stream together. It was observed that the cooling of the liquid film is mainly caused by the latent heat transfer connected with the vaporization of the liquid film. Significant liquid cooling results for the system with a high inlet liquid temperature, high gas stream velocity or a low liquid flowrate. Additionally, the predicted Nusselt and Sherwood numbers were correlated.     

Electronic structure of semiconducting crystals under high stress

We present a calculation of the band structure of semiconducting crystals under arbitrarily high stress, in which all input parameters are determined from the properties of the unstressed crystal alone. The method is applied to obtain the band structure of Ge and Si at high stress, and the strain dependence of the energies and matrix elements of a number of critical-point transitions are presented.