外磁场下XY模型中两量子位热纠缠的性质及其调控研究

在海森堡XY模型中,为了统一研究均匀磁场和非均匀磁场对系统热纠缠的影响,在两个量子位分别施加独立可控的外磁场(B+b)和(B-b). 发现在均匀磁场和低温条件下的纠缠度有一个稳定的平台区并发生纠缠突变. 控制磁场不均匀度b和选择合适的材料就可以获得最有利的纠缠,并大大提高系统退纠缠的临界温度T_c. 调节磁场的B值,可以在更宽的温度范围内实现此体系的纠缠开关. 关键词： 热纠缠度 密度矩阵 XY模型')" href="#">XY模型     

双模最小关联混合态作为量子信道实现量子隐形传态的保真度

基于Braunstein和Kimble提出的B-K方案以双模最小关联混合态作为量子信道实施对未知量子态的隐形传送，并以传送相干态为例进行了研究.结果表明：双模最小关联混合态作为一种广义的Einstein-Podolsky-Rosen型纠缠态在实现量子隐形传态中能很好地担当量子信道的角色，在纠缠度和压缩度选择适当的条件下被传送未知量子态的保真度可以达到1.这是比双模压缩真空态更优越的量子信道. 关键词： 量子隐形传态 双模最小关联混合态 保真度     

基于微极性弹性力学的碳纳米管中波的传播特性

基于微极性弹性理论推导出的碳纳米管的应力-应变关系，使用哈密顿原理建立了碳纳米管的动力学微分方程. 通过求动力学微分方程的波动解，获得碳纳米管中波的频率与波数的关系即弥散关系，另外还得到了波的群速度和特征波面. 对所得结果进行了讨论. 关键词： 微极性弹性力学 碳纳米管 群速度 特征波面     

瞬态荧光方法研究溶剂诱导的三苯胺衍生物的对称性破缺电荷转移动力学

在缺乏特征红外振动的情况下追踪具有四极或八极对称性分子的激发态对称性破缺电荷转移通常是很困难的.本文以一种具有八极对称性的三苯胺衍生物为研究对象,利用飞秒时间分辨瞬态荧光光谱方法获得发光跃迁偶极矩的演化动力学,进而实时表征了其溶剂诱导对称性破缺电荷转移的动力学过程.当该分子处于弱极性甲苯溶液中时,在激发态弛豫过程中其发射偶极矩变化较小;当处于较强极性的四氢呋喃溶液中时,其发射偶极矩在数皮秒内快速减小.在对比单体偶极分子的荧光动力学后,推断八极分子的发光态在强极性溶剂中经历溶剂诱导的结构变化,由激子耦合的八极对称性降低至激发定域的偶极对称性;而在较弱极性的溶剂中,其八极对称性在溶剂化稳定中得以较大程度的保持.     

The Linear Optical Unambiguous Discrimination of Hyperentangled Bell States Assisted by Time Bin

A linear optical unambiguous discrimination of hyperentangled Bell states is proposed for two‐photon systems entangled in both the polarization and momentum degrees of freedom (DOFs) assisted by time bin. This unambiguous discrimination scheme can completely identify 16 orthogonal hyperentangled Bell states using only linear optical elements, where the function of the auxiliary entangled Bell state is replaced by time bin. Moreover, the possibility of extending this scheme for distinguishing hyperentangled Bell states in n DOFs is discussed, and it shows that $2^{n+k+1}$ hyperentangled Bell states in n ( $n\ge 2$) DOFs can be distinguished with k ( $k<n$) auxiliary entangled states of additional DOFs by introducing a time delay, which decreases the auxiliary entanglement resource required for unambiguous discrimination of hyperentangled Bell state. Therefore, this scheme provides a new way for distinguishing hyperentangled states with current technology, which will extend the application of discrimination of hyperentangled states via linear optics to other quantum information protocols besides hyperdense coding schemes in the future.     

Rationally Designing Molecularly Imprinted Polymer Toward a High Specific Adsorbent by Using Metal as Assembled Pivot

This article presents an original work aimed at rationally designing molecularly imprinted polymer (MIP) toward a high specific adsorbent. Assembling with cobalt as the pivot, the MIP was prepared by coordinating polymerizable monomers around an inducible template. The use of pivot obviously plays a positive role on increasing the specificity of MIP, so as to adsorb more for the template and less for its analogue. Related studies indicate that these may be a result of increasing specific interaction, which makes the MIP capable of recognizing the imprint species. Further information from thermodynamic analysis reveals that the increasing specific interaction, in logic, can be due to a higher fidelity of imprint, which specifically allures the template to bind.     

Thermal stability of phosphorus-containing styrene–acrylic copolymer and its fire retardant performance in waterborne intumescent coatings

Phosphorus-containing styrene–acrylic copolymers are synthesized by free radical seeded emulsion polymerization with the monomers of MMA/St/BA/MAA and phosphorus-containing vinyl monomer (SIPOMER PAM100). The properties of copolymer films are characterized by water adsorption test, thermogravimetry, Fourier transform infrared spectroscopy (FTIR), and energy dispersive spectroscopy (EDS), etc. The copolymer emulsions are used as the binder in an intumescent coatings formulation, and the fire-retardant performances of the coatings are determined by an instrument which the furnace temperature is analoging the cellulose fire temperature. The water adsorption of copolymer film increases remarkably owing to the increasing of phosphoric acid group in the polymer chain. The thermal decomposition stability and thermal-oxidative decomposition stability of the copolymer are improved when PAM100 is introduced into its chain, which is strongly supported by the FTIR and EDS results of copolymer residual treated at different temperature. The EDS results also illustrate that the fire retardancy enhanced by PAM100 during combustion owing to the condensed-phase mechanism. The fire-retardant test results show that the intumescent coatings using StA-P_1.5 copolymer emulsion as the binder obtains the best fire retardant performance. We suggested that StA-P_1.5 presents the lower reactivity with the acid source (APP) in 275–400 °C, and the higher reactivity with APP when the temperature is greater than 500 °C would be benefit for the swelling–charring process and the final fire retardant performance. The exorbitant crosslinking in StA-P₇ brings a negative effect on the fire-retardant performance of intumescent coatings, even if it introduces a densy swollen char layer.