Determination of ionization constants of saccharides by capillary zone electrophoresis with amperometric detection

Summary A method based on a linear model enabling the efficient determination of the ionization constants (K _a) of saccharides by capillary zone electrophoresis with amperometric detection has been demonstrated. TheK _a values obtained from the plots of the reciprocal effective mobility against the inverse concentration of sodium hydroxide were in agreement with literature values.     

Structural anisotropy study by resonance Raman scattering in nematics with different dyes

The method for the structural anisotropy determination, which is based on a comparison of the degree of polarization of absorption and resonance Raman bands, is tested with three dyes having different molecular dimensions in one nematic liquid crystal. The experimentally observed correlation between the variation of the structural anisotropy factor and the order parameters deviates from the predictions of the Segre model. This method could also be applied to determine the local field anisotropy for liquid crystals, but we must take into account the observed dependence of the structural anisotropy on the dimensions of the probe molecules.     

强场下煤的13C NMR谱

由强场静态¹³C煤谱可以获得与低场魔角旋转高分辨谱相同的fa,从而避免了样品的快速旋转的要求,同时得到了高灵敏度。     

Effect of promoters on the behavior and properties of VPO catalysts for the selective oxidation of n-butane to maleic anhydride

A series of vanadyl pyrophosphate (VPO) modified by several additives has been investigated with the aim to reveal the promotion mechanism of the additives for selective conversion of n-butane to maleic anhydride (MA). Catalyst performance and various physicochemical characterization including XPS, XRD, FT-IR, DTA and BET indicated that the properties of additives, such as electronegativity and ion radius, contributed much to the effect of the additives on the structure and surface characteristics of VPO catalysts, and then influenced the catalytic behavior. The remarkable effects of additives on the surface vanadium and oxygen species were discussed. It was shown that maximum MA selectivity could be found with a moderate V⁵⁺ /V⁴⁺ ratio, and the catalytic activity and selectivity were improved, respectively, with the increase of surface active oxygen species, as well as as their amount and stability.     

5-桥图F(2,a,a,b,c)的色等价刻画

设P(G，λ)是图G关于变量λ的色多项式，P(G，λ)=P(H，λ)，称G和H色等价，由连接两个顶点的S条内部不交的路组成的图叫S-桥图。本讨论了5-桥图F(2,a,a,b,c)(c≥b≥a 1，a≥2)的色性，完整刻画了这类图的色等价图。     

强反射复杂表面随机缺陷检测照明系统分析

分析了采用CCD光电检测法对强反射复杂表面随机缺陷进行检测时的光学照明问题。给出了缺陷显现力的具体定义。对比了平行光和均匀散射光对消除强反射光的不同作用及对不同表面缺陷的显现力。分析了使用均匀散射光作为光源时，工件表面照度对成像质量的影响。给出了在上述条件下光照系统设计的基本原则。     

On the existence of area-minimizing surfaces with free boundary

Research partially supported by NSF grant # DMS87-03537     

大角度Cu晶界在升温、急冷条件下晶界结构的分子动力学研究

应用分子动力学方法模拟了大角度重位点阵数Σ=5（310）/［001］对称倾斜Cu 晶界在被升温、降温到300,800和1100 K时的晶界结构. 结果表明，随着温度的升高晶界区域的结构发生变化.在远低于块体熔点温度时，晶界就已经发生了预熔化，在晶界区域存在着晶体-熔体共存的现象. 通过对高温晶界的急冷处理，改变了晶界处的原子结构. 关键词： 分子动力学 晶界 熔化 凝固     

与k1∪Pm0的补图有相同色划分的图

本应用色项式的性质讨论了K1∪Pm0的补图的色划分，并完全刻画了与此类图有相同色划分的图。