多酸有机亚胺衍生物的紫外-可见光谱及其取代基效应

以(Bu₄N)₄[α-Mo₈O₂₆]和各种取代苯胺及其盐酸盐为原料, 在碳二环己基亚胺(DCC)存在下, 经脱水反应,合成了多种六钼酸根有机亚胺衍生物, 并用元素分析,1H-NMR,IR和UV-Vis光谱等进行表征,重点研究了六钼酸根有机亚胺衍生物在乙腈溶液中的紫外光谱。研究结果表明,该类化合物具有典型的分子内电子转移的紫外-可见光谱特征,其特征峰位移Δλ_max与苯胺的苯环取代基的共轭效应指数(σ_R)之间存在良好的线性关系。     

Coherence Measurement of White Light Emission from Femtosecond Laser Propagation in Air

Strong white light emission is observed from femtosecond laser propagation in air. The divergence angle of the white light emission is measured to be about 5mrad. Young＇s double-slits and a Michelson interferometer are used to investigate the coherence. The wavelength components of the white light emission are identified to have a good spatial coherence and a coherence time of about 0.5ps.     

n人可信策略博弈

本文研究模糊支付n人策略博弈,由于支付信息的不完全性,模糊支付可视为模糊变量。基于可信性理论,在不同的决策环境中引入模糊排序方法表征支付者行为。因此,本文定义四种可信均衡,等价于纳什均衡。其次证明了可信均衡存在性定理。除此之外,在现实策略博弈中用算例说明四种可信均衡的现实意义。最后讨论四种可信均衡之间可能存在的关系。     

Adaptive Penalized Weighted Least Absolute Deviations Estimation for the Accelerated Failure Time Model

The accelerated failure time model always offers a valuable complement to the traditional Cox proportional hazards model due to its direct and meaningful interpretation. We propose a variable selection method in the context of the accelerated failure time model for survival data, which can simultaneously complete variable selection and parameter estimation. Meanwhile, the proposed method can deal with the potential outliers in survival times as well as heteroscedastic model errors, which are frequently encountered in practice. Specifically, utilizing the general nonconvex penalty, we propose the adaptive penalized weighted least absolute deviation estimator for the accelerated failure time model. Under some regularity conditions, we show that the proposed method yields consistent estimator and possesses the oracle property. In addition, we propose a new algorithm to compute the estimate in the high dimensional settings, and evaluate the practical utility of the proposed method through extensive simulation studies and two real examples.     

Experimental research on distributed fiber sensor for sliding damage monitoring

A distributed optical fiber sensor (DOFS) with the principle of microbend loss has been developed for concrete or rock-sliding damage measurement. The combination of multiple microbend sensors can form a sensor array for distributed sensing application in monitoring local slippage or deformation along the rock mass of the high slope, and the optical time-domain reflectometry (OTDR) can be conveniently used for interrogation of each sensor point. The sensor sensitivity can be obtained at a specific range according to the requirement of the model test condition. Connected with multiplexed sensing processing schemes, its sliding range of dynamic sensing response reached 0–3.6 mm and semi-empirical formula was fitted according to data from model tests. The DOFS array may find a potential application in real-time monitoring and damage detection of large and critical slope engineering structures.     

强磁场条件下金属凝固过程中第二相的迁移行为

理论分析表明,第二相的迁移行为可以通过迁移速度进行表征.影响迁移速度的因素包括第二相和熔体的物理性质、磁场强度和梯度大小、第二相的形状和体积等因素.强磁场下洛伦兹力的效果为促进第二相在基体中的均匀分布,其效率在磁场强度大于某一定值时逐渐降低.在梯度强磁场条件下,第二相迁移行为和分布状态的主要控制参数是梯度磁场下的磁化力.在磁场梯度较小时,因洛伦兹力的制约磁化力控制第二相迁移的效果不明显,随着磁场梯度的增加,磁化力的作用效果逐渐增强.通过研究强磁场下Al-Si合金、Al-Ni合金中原位自生第二相的迁移行为实 关键词： 强磁场 迁移 第二相 凝固     

δ势垒对多臂量子环中持续电流的影响

提出了含δ势垒的多臂量子环模型.研究发现总磁通为零时,持续电流随半导体环增大发生非周期性振荡,下臂因含δ势垒而获得最小的平均持续电流.AB磁通增强时,持续电流会发生周期性等幅振荡,并与电极的磁矩方向以及隧穿电子的自旋方向相关.两电极磁矩方向平行时,Rashba自旋轨道耦合具有改变持续电流相位和相位差的效应;两电极磁矩方向反平行时,Rashba自旋轨道耦合具有改变持续电流振幅的效应.各臂之间持续电流的不同与臂长和磁通分布的差异相关.在一定条件下,两种波函数所对应的持续电流是可分离的. 关键词： 多臂量子环 持续电流 δ势垒 Rashba自旋轨道耦合     

A simple and efficient algorithm for fused lasso signal approximator with convex loss function

We consider the augmented Lagrangian method (ALM) as a solver for the fused lasso signal approximator (FLSA) problem. The ALM is a dual method in which squares of the constraint functions are added as penalties to the Lagrangian. In order to apply this method to FLSA, two types of auxiliary variables are introduced to transform the original unconstrained minimization problem into a linearly constrained minimization problem. Each updating in this iterative algorithm consists of just a simple one-dimensional convex programming problem, with closed form solution in many cases. While the existing literature mostly focused on the quadratic loss function, our algorithm can be easily implemented for general convex loss. We also provide some convergence analysis of the algorithm. Finally, the method is illustrated with some simulation datasets.     

Relativistic Mean Field Study of the Z=117 Isotopic Chain

The properties of the Z = 117 isotopic chain are studied within the framework of the axially deformed relativistic mean field theory （RMFT） in the blocked BCS approximation. The ground-state properties, such as hinging energies, deformations as well as the possible α decay energies and lifetimes are calculated with the parameter set of NL-Z2 and compared with results from the finite range droplet model. The analysis by RMFT shows that the isotopes in the range of mass number A =291 ~ 300 exhibit higher stability, which suggests that they may be promising nuclei to be hopefully synthesized in the lab among the nuclei Z = 117.     

Li,N双受主共掺杂实现p型ZnO的第一性原理研究

基于密度泛函理论,采用第一性原理平面波超软赝势法,首先对六方纤锌矿结构的ZnO晶体和N,Li分别掺杂ZnO以及Li-N共掺杂ZnO晶体的几何结构分别进行了优化计算,在此基础上计算得到了未掺杂ZnO晶体和不同掺杂情况下ZnO晶体的能带结构、总体态密度、分波态密度和电荷布居数.利用计算的结果,从理论上分析了Li-N共掺杂ZnO更容易得到稳定的p型ZnO. 关键词： ZnO 电子结构 第一性原理 p型共掺杂