Integrating a Luminescent Porous Aromatic Framework into Indicator Papers for Facile,Rapid, and Selective Detection of Nitro Compounds

Porous aromatic framework materials with high stability, sensitivity, and selectivity have great potential to provide new sensors for optoelectronic/fluorescent probe devices. In this work, a luminescent porous aromatic framework material (LNU-23) was synthesized via the palladium-catalyzed Suzuki cross-coupling reaction of tetrabromopyrene and 1,2-bisphenyldiborate pinacol ester. The resulting PAF solid exhibited strong fluorescence emission with a quantum yield of 18.31%, showing excellent light and heat stability. Because the lowest unoccupied molecular orbital (LUMO) of LNU-23 was higher than that of the nitro compounds, there was an energy transfer from the excited LNU-23 to the analyte, leading to the selective fluorescence quenching with a limit of detection (LOD) ≈ 1.47 × 10⁻⁵ M. After integrating the luminescent PAF powder on the paper by a simple dipping method, the indicator papers revealed a fast fluorescence response to gaseous nitrobenzene within 10 s, which shows great potential in outdoor fluorescence detection of nitro compounds.     

布里渊散射谱拟合的混合优化算法

基于布里渊光时域分析仪的全分布式光纤传感系统中,光纤沿途的探测信号含有噪声导致被测量的温度或应变信息难以识别,光谱拟合的精确度对传感信息的识别非常重要。在传感系统低信噪比的情况下,提出了一种提取高精度布里渊散射谱特征的拟合方法,利用小波去噪结合莱文伯-马奈特（LM）算法调节权值后向传输(BP)网络对布里渊散射谱进行特征提取。克服了传统BP神经网络易陷入局部极值的缺点,保证求解的精度。数值仿真表明,该方法适合不同权重比、不同线宽和低信噪比以及大测量范围的情况进行光谱拟合,并且在信噪比为10 dB的情况下得到拟合度均超过0.96。实验结果表明,该方法适用于多种泵浦功率情况下的布里渊散射谱的特征提取,优于传统BP神经网络算法且具有较高的拟合精度。     

端视ICP-AES法同时测定玩具涂料中可溶性铅、镉、汞、砷、铬、锑、硒和钡

采用端视电感耦合等离子体原子发射光谱(ICP-AES)法同时测定玩具涂料中可溶性铅、镉、汞、砷、铬、锑、硒和钡.对仪器的工作参数和被测元素的分析谱线进行了优化和选择.铅、镉、汞、砷、铬、锑、硒和钡的检出限分别为0.006、0.0009、0.012、0.023、0.000 8、0.013、0.030和0.0006 mg/L.定量下限分别为0.99、0.15、2.0、3.8、0.14、2.2、5.0和0.10 mg/kg.相对标准偏差为0.76%～2.72%(n=8),加标回收率为96.0%～104.0%.该法适用于玩具涂料中铅、镉、汞、砷、铬、锑、硒和钡的快速测定.     

Hairy Black Hole Solutions¶to SU(3) Einstein–Yang–Mills Equations

We give a rigorous proof of existence of infinitely many black hole solutions to the Einstein–Yang–Mills equations with gauge group SU(3). In the case that the radius of event horizon is not too small, we show that there is a black hole solution for any possible numbers of zeros of the two field variables. Received: 23 October 2000 / Accepted: 30 January 2001     

手性毛细管色谱法测定人尿中美芬妥英对映体的含量及其在代谢分型中的应用

 采用手性毛细管色谱柱和ＦＩＤ检测器建立了人尿中美芬妥英（ＭＰ）对映体的定量分析方法。尿样用二氯乙烷提取，用酸、碱洗涤得以纯化，测得各对映体的最低检测限为６０μｇ／Ｌ。在１１５～６９０μｇ／Ｌ浓度范围内，标准曲线呈良好的线性关系，ｒ＞０．９９，日内、日间精密度ＲＳＤ＜６．５％，Ｓ－ＭＰ的平均回收率为７４．４１％，Ｒ－ＭＰ的平均回收率为７３．７８％。并以ＭＰ为探针药物，对３２名志愿者的尿样进行了ＭＰ氧化代谢分型研究。     

用能量法求多自由度振动系统的角频率

利用简谐振动能量方程，通过分析振幅矢量的关系，用能量法求多自由度振动系统的角频率或简正振动频率。     

二价铕激活的Ba1-xCaxFCl体系及其发光

本文研究了Ba1-xCaxFCl:Eu体系及其发光。从差热分析相图和X射线衍射分析发现在Ba1-xCaxFCl体系中存在着Ba0.5Ca0.5FCl这个物相。Ba1-xCaxFCl:Eu体系在X射线激发下的发光包含一个3630Å的锐峰和一宽带发射峰,其峰值由BaFCl:Eu的3868Å到CaFCl:Eu的4640Å,阴极射线和紫外线激发下的发射光谱与此类似。在X射线激发下,Ba0.8Ca0.2FCl:Eu的发光最强,而在阴极射线激发下,CaFCl:Eu的发光强度最大,在紫外线激发下,Ba1-xCaxFCl:Eu的发光强度校弱。在以上三种激发情况下,Ba0.5Ca0.5FCl:Eu的发光都比较弱。     

1,10-邻菲咯啉-5,6-二酮制备反应中副产物的形成与控制

由1,10-邻菲咯啉合成1,10-邻菲咯啉-5,6-二酮反应的副产物的形成与控制研究表明,1,10-邻菲咯啉在5,6位二酮化反应中的副反应产物及主产物分离时产生的副产物均为4,5-二氮杂芴-9-酮,二酮化反应条件(包括作为氧化剂的强混合酸H2SO4/HNO3的加入量、时间和温度)和主产物分离时体系的酸度对副产物的形成有重要影响,优化了二酮化反应条件和产物分离时的体系pH控制范围。在此优化条件下,可有效控制副产物的形成,使主产物1,10-邻菲咯啉-5,6-二酮的收率达到92%以上。     

MoO_3、NiO、ZnO在小表面金红石上的分散行为

氧化物、盐类在氧化物载体表面的自发分散是一种广泛存在的现象，文献中已报导过大量氧化物和盐类在高比表面载体上分散的研究结果［'－3］TIO。作为一种较新型的载体，与Y－AI。O。、硅胶等传统载体相比，有许多不同特性．活性组分在TIO。表面的分散状态及所得催化剂的性能已有不少报导［'－'］，但所用的TIOZ主要是较高比表面的锐钛矿型TIOZ（刘金红石型TIO。（r）和锐钛矿型TIOZ（a）的结构不同，它是高温生成相，比表面较小［'］．氧化物在金红石上的分散行为仍未见报导．我们制备了三种具有不同比表面的TIO水），系统地研…     

Significant Acceleration of Photocatalytic CO2 Reduction at the Gas-Liquid Interface of Microdroplets**

Solar-driven CO₂ reduction reaction (CO₂RR) is largely constrained by the sluggish mass transfer and fast combination of photogenerated charge carriers. Herein, we find that the photocatalytic CO₂RR efficiency at the abundant gas-liquid interface provided by microdroplets is two orders of magnitude higher than that of the corresponding bulk phase reaction. Even in the absence of sacrificial agents, the production rates of HCOOH over WO₃ ⋅ 0.33H₂O mediated by microdroplets reaches 2536 μmol h⁻¹ g⁻¹ (vs. 13 μmol h⁻¹ g⁻¹ in bulk phase), which is significantly superior to the previously reported photocatalytic CO₂RR in bulk phase reaction condition. Beyond the efficient delivery of CO₂ to photocatalyst surfaces within microdroplets, we reveal that the strong electric field at the gas-liquid interface of microdroplets essentially promotes the separation of photogenerated electron-hole pairs. This study provides a deep understanding of ultrafast reaction kinetics promoted by the gas-liquid interface of microdroplets and a novel way of addressing the low efficiency of photocatalytic CO₂ reduction to fuel.