硒化钨花状纳米晶的可控合成及电催化产氢性能研究

采用胶体化学法,以氧化钨(W18O49)为钨源制备出花状硒化钨纳米晶.采用透射电子显微镜(TEM)、高分辨透射电镜(HRTEM)和X射线衍射(XRD)手段对硒化钨纳米晶进行表征.本文对硒化钨花状纳米晶体的可控合成进行了初步探索,同时对烧结后的硒化钨纳米晶进行了电催化产氢测试.结果表明,硒化钨花状纳米晶具有良好的电催化性能.     

The iso-structural viscosity,configurational entropy and fragility of oxide liquids

This paper describes how the fragility of a liquid is linked to the ratio between the energy barrier (E_eq) for the equilibrium viscous behavior and that (E_iso) for the non-equilibrium iso-structural viscous behavior. Using the concept of iso-structural viscosity, two functions describing the variation of the configurational entropy (S_c) with temperature (T) are obtained from the Avramov-Milchev (AM) and the Vogel-Fulcher-Tammann (VFT) viscosity equations, respectively. The two S_c(T) functions exhibit different relations to the liquid fragility. The AM S_c(T) function is a power function with the exponent of F ? 1, where F is the AM fragility index. In this case, S_c vanishes at T = 0 K. For the VFT function, S_c vanishes as T is lowered to a finite temperature T₀, whereas it reaches the maximum value S_c,max at infinitively high T. S_c,max is proportional to the VFT fragility index. Thus, the VFT equation is not only a dynamical, but also a thermodynamic model. It is proved that for oxide liquids, the VFT equation describes viscosity data better than the AM equation, provided the pre-exponential factor η₀ is fixed to a generally accepted value, e.g., 10^?3.5 Pa s.     

Two Titanium-oxo-Clusters with Malonate and Succinate Ligands: Single-Crystal Structures and Catalytic Property

Two alkane dicarboxylates substituted titanium-oxo-clusters, Ti₆O₃(OOCCH₂COO)₂(O ⁱ Pr)₁₄ (1) and Ti₆O₃(OOCC₂H₄COO)₂(O ⁱ Pr)₁₄ (2), were successfully prepared by one step in situ solvothermal synthesis. The compounds are the first examples of only flexible alkane dicarboxylate-substituted titanium-oxo-clusters. The structures of the compounds are best described as two trinuclear oxo-Ti₃ subunits linked by a μ ₂-O bridge and two malonate or succinate ligands, forming Ti₆ clusters. A photochromic effect was observed upon irradiating the crystals, and the color of the crystals was changed from transparent to gray. Photodegradation of the methyl orange in aqueous dispersions of microcrystals of compounds 1 and 2 were carried out under UV cut white light with the assistance of H₂O₂. Compound 2 exhibited higher photocatalytic activity than 1, which might be related to the smaller angles of μ ₂-O bridge in 2.     

Two New Cubane-Type Tetranuclear Compounds of Copper(II), Nickel(II) Derived from Reduced Schiff Base Ligand: Syntheses,Structures and Magnetic Properties

Two tetranuclear complexes, [M(H₃L)]₄·X (1, M = Cu, X = 4,4′-dpdo; 2, M = Ni, X = DMF, H₅L = 2-[(3,5-dibromo-2-hydroxybenzyl) amino]-2-(hydroxymethyl)propane-1,3-diol, 4,4′-dpdo is 4,4′-bipyridine-N,N′-dioxide, DMF = N,N′-dimethyl formamide), have been synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. Compound 1 features a centrosymmetric tetranuclear copper cluster which further constructed a 1D chain through a tetra-acceptor hydrogen bonds of 4,4′-dpdo molecule. Compound 2 having a P2₁ /n space group also exhibits a tetranuclear nickel cluster with a cubane topology in which the central Ni(II) ion and oxygen atoms from H₃L^2? occupy the alternate vertices of the cube. Magnetic properties of 1 and 2 in the 2–300 K have also been discussed. The tetranuclear cubanes cores display dominant ferromagnetic interactions.     

无色散p-约化KP系列的弦方程

无色散p-约化KP系列是无色散KP系列的约化形式.基于两个形式劳伦级数,由特殊的附加对称流,无色散p-约化KP系列的弦方程被给出.     

Cerium oxide nanoparticles protect primary mouse bone marrow stromal cells from apoptosis induced by oxidative stress

The sintering of a silver (Ag) nanoparticle film by laser beam irradiation was studied using a CW DPSS laser. The laser sintering of the Ag nanoparticle thin film gave a transparent conductive film with a thickness of ca. 10 nm, whereas a thin film sintered by conventional heat treatment using an electronic furnace was an insulator because of the formation of isolated silver grains during the slow heating process. The laser sintering of the Ag nanoparticle thin film gave a unique conductive network structure due to the rapid heating and quenching process caused by laser beam scanning. The influences of the laser sintering conditions such as laser scan speed on the conductivity and the transparency were studied. With the increase of scan speed from 0.50 to 5.00 mm/s, the surface resistivity remarkably decreased from 4.45 × 10⁸ to 6.30 Ω/sq. The addition of copper (Cu) nanoparticles to silver thin film was also studied to improve the homogeneity of the film and the conductivity due to the interaction between the oxidized surface of Cu nanoparticle and a glass substrate. By adding 5 wt% Cu nanoparticles to the Ag thin film, the surface resistivity improved to 2.40 Ω/sq.     

Design of CASSEGRAIN telescope baffles with honeycomb entrance

The stray radiation suppression in Cassegrain family optical system is presented. The design method for ultra-short outer baffle with honeycomb structure is proposed. Meanwhile the constraint formulas for designing the geometries of primary baffle and secondary baffle are deduced when basing the characteristic and taking vignette into account. According to the ray trace simulated data, the point source transmit- tance values of the baffle are less than 10-^10 when incident angles are larger than the rejection angle. The honeycomb-look front baffle guarantees a comparable performance of stray light suppression with traditional tube baffle, while reducing the size greatly.     

RF and field measurements of the SSC-LINAC RFQ

The 53.667 MHz continuous-wave heavy ion RFQ has been designed and manufactured for the SSC-LINAC project.This four-rod RFQ accelerates ions with maximum mass to charge ratio of 7 from 3.728 keV/u to 143 keV/u.Measurements have been carried out to check the RF performance of the cavity and the quality of the electric field.The S11 of the power coupler is adjusted to better than-44 dB,and the Q0 of the cavity is 6440.The quality of the electric field is evaluated by the perturbation method.The measurement procedure and data analysis will be discussed in detail.The error due to gravity of the perturbation bead has been corrected by averaging the fields in different quadrants.As a result,the unflatness of the electric field is±2.5%,and the dipole field component distributes from 0%to 20%in different longitudinal positions,which indicates the asymmetry of the quadrupole field.The unflatness of the quadrupole field distribution represents a good agreement with the simulation results.High power RF test and beam commissioning of the RFQ are on schedule in early 2014.     

Reservoir Pore Structure Classification Technology of Carbonate Rock Based on NMR T 2 Spectrum Decomposition

The carbonate reservoir has a number of properties such as multi-type pore space, strong heterogeneity, and complex pore structure, which make the classification of reservoir pore structure extremely difficult. According to nuclear magnetic resonance (NMR) T ₂ spectrum characteristics of carbonate rock, an automatic pore structure classification and discrimination method based on the T ₂ spectrum decomposition is proposed. The objective function is constructed based on the multi-variate Gaussian distribution properties of the NMR T ₂ spectrum. The particle swarm optimization algorithm was used to solve the objective function and get the initial values and then the generalized reduced gradient algorithm was proposed for solving the objective function, which ensured the stability and convergence of the solution. Based on the featured parameters of the Gaussian function such as normalized weights, spectrum peaks and standard deviations, the combinatory spectrum parameters (by multiplying peak value and normalized weight for every peak) are constructed. According to the principle of fuzzy clustering, the carbonate rock pore structure is classified automatically and the discrimination function of each pore structure type is obtained using Fisher discrimination analysis. The classification results were analyzed with the corresponding casting thin section and scanning electron microscopy. The study shows that the type of the pore structure based on the NMR T ₂ spectrum decomposition is strongly consistent with other methods, which provides a good basis for the quantitative characterization of the carbonate rock reservoir pore space and lays a foundation of the carbonate rock reservoir classification based on NMR logging.