全文获取类型
收费全文 | 4404篇 |
免费 | 692篇 |
国内免费 | 492篇 |
专业分类
化学 | 3464篇 |
晶体学 | 57篇 |
力学 | 171篇 |
综合类 | 14篇 |
数学 | 437篇 |
物理学 | 1445篇 |
出版年
2024年 | 7篇 |
2023年 | 100篇 |
2022年 | 173篇 |
2021年 | 211篇 |
2020年 | 242篇 |
2019年 | 205篇 |
2018年 | 190篇 |
2017年 | 150篇 |
2016年 | 246篇 |
2015年 | 255篇 |
2014年 | 259篇 |
2013年 | 368篇 |
2012年 | 455篇 |
2011年 | 433篇 |
2010年 | 249篇 |
2009年 | 290篇 |
2008年 | 248篇 |
2007年 | 240篇 |
2006年 | 220篇 |
2005年 | 144篇 |
2004年 | 126篇 |
2003年 | 88篇 |
2002年 | 78篇 |
2001年 | 56篇 |
2000年 | 61篇 |
1999年 | 75篇 |
1998年 | 52篇 |
1997年 | 39篇 |
1996年 | 62篇 |
1995年 | 25篇 |
1994年 | 35篇 |
1993年 | 29篇 |
1992年 | 28篇 |
1991年 | 19篇 |
1990年 | 23篇 |
1989年 | 22篇 |
1988年 | 13篇 |
1987年 | 19篇 |
1986年 | 9篇 |
1985年 | 7篇 |
1984年 | 13篇 |
1983年 | 6篇 |
1982年 | 6篇 |
1981年 | 2篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1959年 | 1篇 |
1957年 | 2篇 |
排序方式: 共有5588条查询结果,搜索用时 969 毫秒
61.
Z. P. Lu L. Stachowicz P. Kong J. Heberlein E. Pfender 《Plasma Chemistry and Plasma Processing》1991,11(3):387-394
Diamond crystals and films have been success full y synthesized by DC thermal plasma jet CVD at a pressure of I atrn. A novel triple torch plasma reactor has been used to generate a convergent plasma volume to entrain the participating gases. Three coalescing plasma jets produces! by this reactor direct the dissociated and ionized gaseous species onto ( 100) silicon wafer substrates where the diamond grows. In a typical 10-min run, depending on the method of .substrate preparation, either microcrystals with sizes up to 8 m or continuous films with thicknesses of 1–2 m have been obtained. X-ray diffraction, scanning electron microscopy, and Raman spectroscopy have been used for the characterization of the crystals and of the films. 相似文献
62.
63.
Monuron (C9H11ClN2O; N,N-dimethyl-N′-(4-chlorophenyl) urea, CAS 150-68-5) was synthesized and the heat capacities of the compound were measured in the temperature range from 79 to 385 K with a high precision automated adiabatic calorimeter. No phase transition or thermal anomaly was observed in this range. The enthalpy and entropy data of the compound relative to the reference temperature 298.15 K were derived based on the heat capacity data. The thermodynamic properties of the compound were further investigated through DSC and TG analysis. The melting point, the molar enthalpy, and entropy of fusion were determined to be 447.6±0.1 K, 29.3±0.2 kJ mol−1, and 65.4 J K−1 mol−1, respectively. 相似文献
64.
65.
Xiaohua Zou Song Zhang Mianhong Shi Jilie Kong 《Journal of Solid State Electrochemistry》2007,11(2):317-322
A stepwise deposition method was employed to create ordered polyaniline (PANI) nanowires with remarkably enhanced capacitance. Cyclic voltammetry, AC impedance, and galvanostatic charge/discharge cycling were employed to investigate the electrochemical performance of the PANI electrodes. The PANI-deposited electrode exhibits much higher capacitance than those prepared by one-step deposition method, which were mainly contributed from the unique nano structure of PANI and the increased biological, economical, and technical surface areas. The superior capacitive behaviors of the nano PANI electrodes show great potential in preparation of high efficient electrochemical capacitors or rechargeable batteries. 相似文献
66.
A simple and accurate RP-HPLC method using photodiode array detection (PAD) was developed for the simultaneous determination of four flavonoids, namely quercetin (QU),luteolin(LU),apigenin(AP) and isorhamnetin (IS) in pigeonpea leaves.Extract samples were separated on HIQ SIL C18V column using methanol-acetonitrile-water(31:10:59, v/v/v) as mobile phase.The flavonoids were detected at 254.5 nm for QU and IS, and at 345 nm for LU and AP.Contents were determined with satisfactory repeatability (R. S. D. < 2.2%) and recovery (97.27 – 99.98%). The developed method was found to be simple and efficient. 相似文献
67.
Based on the unique absorbent characters and three-dimensional network structure of polyacrylamide (PAM) superabsorbent polymer, a photocatalytic degradable TiO2/PAM composite was synthesized by an aqueous solution polymerization method with N,N′-methylene bisacrylamide as crosslinker, potassium peroxydisulfate as initiator, acrylamide as monomer, and TiO2 (P-25) as functional filler. The photocatalytic degradability of the composite was evaluated using methyl orange as photodegradation target, and the recovery and reproducibility of the composite was investigated. It was found that TiO2/PAM composite had a good photocatalytic degradability, the composite also possessed a good reproducibility of photocatalytic degradability, which is possible to be used in practical process. 相似文献
68.
The recent advances in the study of light emission from matter induced by synchrotron radiation: X‐ray excited optical luminescence (XEOL) in the energy domain and time‐resolved X‐ray excited optical luminescence (TRXEOL) are described. The development of these element (absorption edge) selective, synchrotron X‐ray photons in, optical photons out techniques with time gating coincide with advances in third‐generation, insertion device based, synchrotron light sources. Electron bunches circulating in a storage ring emit very bright, widely energy tunable, short light pulses (<100 ps), which are used as the excitation source for investigation of light‐emitting materials. Luminescence from silicon nanostructures (porous silicon, silicon nanowires, and Si–CdSe heterostructures) is used to illustrate the applicability of these techniques and their great potential in future applications. 相似文献
69.
70.
We report studies of supersonically cooled indan using two-color resonantly enhanced multiphoton ionization and two-color zero-kinetic-energy photoelectron spectroscopy. With the aid of ab initio and density-functional calculations, vibrational modes of the first electronically excited state of the neutral species and those of the cation have been assigned, and the adiabatic ionization energy has been determined to be 68458 +/- 5 cm(-1). Similar to the ground state and the first electronically excited state of the neutral molecule, the ground state of the cation is also proven to be nonplanar, with an estimated barrier of 213 cm(-1) and a puckering angle of 15.0 degrees. These conclusions will be discussed in comparison with a previous study of an indan derivative 1,3-benzodioxole. 相似文献