首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   4404篇
  免费   692篇
  国内免费   492篇
化学   3464篇
晶体学   57篇
力学   171篇
综合类   14篇
数学   437篇
物理学   1445篇
  2024年   7篇
  2023年   100篇
  2022年   173篇
  2021年   211篇
  2020年   242篇
  2019年   205篇
  2018年   190篇
  2017年   150篇
  2016年   246篇
  2015年   255篇
  2014年   259篇
  2013年   368篇
  2012年   455篇
  2011年   433篇
  2010年   249篇
  2009年   290篇
  2008年   248篇
  2007年   240篇
  2006年   220篇
  2005年   144篇
  2004年   126篇
  2003年   88篇
  2002年   78篇
  2001年   56篇
  2000年   61篇
  1999年   75篇
  1998年   52篇
  1997年   39篇
  1996年   62篇
  1995年   25篇
  1994年   35篇
  1993年   29篇
  1992年   28篇
  1991年   19篇
  1990年   23篇
  1989年   22篇
  1988年   13篇
  1987年   19篇
  1986年   9篇
  1985年   7篇
  1984年   13篇
  1983年   6篇
  1982年   6篇
  1981年   2篇
  1976年   1篇
  1975年   1篇
  1974年   1篇
  1973年   1篇
  1959年   1篇
  1957年   2篇
排序方式: 共有5588条查询结果,搜索用时 969 毫秒
61.
Diamond crystals and films have been success full y synthesized by DC thermal plasma jet CVD at a pressure of I atrn. A novel triple torch plasma reactor has been used to generate a convergent plasma volume to entrain the participating gases. Three coalescing plasma jets produces! by this reactor direct the dissociated and ionized gaseous species onto ( 100) silicon wafer substrates where the diamond grows. In a typical 10-min run, depending on the method of .substrate preparation, either microcrystals with sizes up to 8 m or continuous films with thicknesses of 1–2 m have been obtained. X-ray diffraction, scanning electron microscopy, and Raman spectroscopy have been used for the characterization of the crystals and of the films.  相似文献   
62.
63.
Monuron (C9H11ClN2O; N,N-dimethyl-N′-(4-chlorophenyl) urea, CAS 150-68-5) was synthesized and the heat capacities of the compound were measured in the temperature range from 79 to 385 K with a high precision automated adiabatic calorimeter. No phase transition or thermal anomaly was observed in this range. The enthalpy and entropy data of the compound relative to the reference temperature 298.15 K were derived based on the heat capacity data. The thermodynamic properties of the compound were further investigated through DSC and TG analysis. The melting point, the molar enthalpy, and entropy of fusion were determined to be 447.6±0.1 K, 29.3±0.2 kJ mol−1, and 65.4 J K−1 mol−1, respectively.  相似文献   
64.
咪唑类离子液体结构与熔点的构效关系及其基本规律   总被引:1,自引:0,他引:1  
蒋栋  王媛媛  刘洁  戴立益 《化学通报》2007,70(5):371-375
熔点是界定、研究离子液体及其使用过程的一个重要参考指标,因此研究离子液体分子结构与熔点之间的构效关系及其基本规律有特别重要的意义。本文以从近两百遍文献及Beilstein Gmelin网络数据库中收集的约900种咪唑类离子液体中的384种咪唑类离子液体的熔点数据为依据,考察了离子液体分子结构与熔点之间的构效关系及其基本规律,这对离子液体的设计合成及应用有指导作用。  相似文献   
65.
A stepwise deposition method was employed to create ordered polyaniline (PANI) nanowires with remarkably enhanced capacitance. Cyclic voltammetry, AC impedance, and galvanostatic charge/discharge cycling were employed to investigate the electrochemical performance of the PANI electrodes. The PANI-deposited electrode exhibits much higher capacitance than those prepared by one-step deposition method, which were mainly contributed from the unique nano structure of PANI and the increased biological, economical, and technical surface areas. The superior capacitive behaviors of the nano PANI electrodes show great potential in preparation of high efficient electrochemical capacitors or rechargeable batteries.  相似文献   
66.
A simple and accurate RP-HPLC method using photodiode array detection (PAD) was developed for the simultaneous determination of four flavonoids, namely quercetin (QU),luteolin(LU),apigenin(AP) and isorhamnetin (IS) in pigeonpea leaves.Extract samples were separated on HIQ SIL C18V column using methanol-acetonitrile-water(31:10:59, v/v/v) as mobile phase.The flavonoids were detected at 254.5 nm for QU and IS, and at 345 nm for LU and AP.Contents were determined with satisfactory repeatability (R. S. D. < 2.2%) and recovery (97.27 – 99.98%). The developed method was found to be simple and efficient.  相似文献   
67.
Based on the unique absorbent characters and three-dimensional network structure of polyacrylamide (PAM) superabsorbent polymer, a photocatalytic degradable TiO2/PAM composite was synthesized by an aqueous solution polymerization method with N,N′-methylene bisacrylamide as crosslinker, potassium peroxydisulfate as initiator, acrylamide as monomer, and TiO2 (P-25) as functional filler. The photocatalytic degradability of the composite was evaluated using methyl orange as photodegradation target, and the recovery and reproducibility of the composite was investigated. It was found that TiO2/PAM composite had a good photocatalytic degradability, the composite also possessed a good reproducibility of photocatalytic degradability, which is possible to be used in practical process.  相似文献   
68.
The recent advances in the study of light emission from matter induced by synchrotron radiation: X‐ray excited optical luminescence (XEOL) in the energy domain and time‐resolved X‐ray excited optical luminescence (TRXEOL) are described. The development of these element (absorption edge) selective, synchrotron X‐ray photons in, optical photons out techniques with time gating coincide with advances in third‐generation, insertion device based, synchrotron light sources. Electron bunches circulating in a storage ring emit very bright, widely energy tunable, short light pulses (<100 ps), which are used as the excitation source for investigation of light‐emitting materials. Luminescence from silicon nanostructures (porous silicon, silicon nanowires, and Si–CdSe heterostructures) is used to illustrate the applicability of these techniques and their great potential in future applications.  相似文献   
69.
用时间分辨富里叶红外发射谱研究了高振动激发态CO向C2H2的传能,得到了CO(v=1-3)各振动态布居及其随时间的变化。利用微分法解出弛豫微分方程组,获得CO(v=1-3)向C2H2的传能速率常数分别为:2.0±0.1,6.0±0.2和9.4±0.8(10^-13cm^3·molecule^-1·s^-1)。传能速率随着振动量子数的增加而迅速增加。CO的振动能应向C2H2的对称伸缩模v2近共振V-  相似文献   
70.
We report studies of supersonically cooled indan using two-color resonantly enhanced multiphoton ionization and two-color zero-kinetic-energy photoelectron spectroscopy. With the aid of ab initio and density-functional calculations, vibrational modes of the first electronically excited state of the neutral species and those of the cation have been assigned, and the adiabatic ionization energy has been determined to be 68458 +/- 5 cm(-1). Similar to the ground state and the first electronically excited state of the neutral molecule, the ground state of the cation is also proven to be nonplanar, with an estimated barrier of 213 cm(-1) and a puckering angle of 15.0 degrees. These conclusions will be discussed in comparison with a previous study of an indan derivative 1,3-benzodioxole.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号