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965.
A tunable dual-band infrared polarization filter is proposed and investigated. Based on the perfect absorption characteristic of the metal-dielectric-metal sandwich structure, the reflection spectrum performs as a filter. The filter consists of three layers. The top layer is a compound metal nano-structure array comprised of rectangular strips. The middle and bottom layers are a dielectric spacer and metal film, respectively. The calculated results show that the filter properties are closely related to the polarization of the incident light. Different dual-band wavelengths are filtered while the incident light has different polarizations, which are parallel or vertical to the x axis. Moreover, it is found that the resonant wavelength strongly depends on the length of the rectangular strip(which causes the resonant effect) and is independent of other strips. Therefore, the filter wavelengths can be tuned freely by adjusting the length of the corresponding rectangular strip. In addition, the calculated results show that all of the intensities at the filter wavelengths are closed to zero, which implies that the filter exhibits good filtering performance. 相似文献
966.
The thermal modified rectorite (TR) was prepared and characterized by x-ray diffraction, scanning electron microscopy, and Fourier transform infrared spectroscopy. The structure of TR was destroyed gradually with increasing the calcination temperature, and the adsorption capacity for methylene blue (MB) of the rectorite can be improved by thermal modification in appropriate temperature ranges. The equilibrium data were well described by the Langmuir model. The kinetic studies indicated that the adsorption process was fitted well with the pseudo-second-order kinetic model. Thermodynamic studies indicated that adsorption of MB was endothermic in nature and favorable with the positive ΔH 0 value of 25.90 kJ/mol. 相似文献
967.
Jialiang PanAuthor Vitae Chengjiang ZhangAuthor VitaeZhuomin Zhang Gongke Li 《Analytica chimica acta》2014
Sample preparation is still considered as the bottleneck of the whole analytical procedure, and efforts has been conducted towards the automation, improvement of sensitivity and accuracy, and low comsuption of organic solvents. Development of online sample preparation techniques (SP) coupled with liquid chromatography (LC) is a promising way to achieve these goals, which has attracted great attention. This article reviews the recent advances on the online SP-LC techniques. Various online SP techniques have been described and summarized, including solid-phase-based extraction, liquid-phase-based extraction assisted with membrane, microwave assisted extraction, ultrasonic assisted extraction, accelerated solvent extraction and supercritical fluids extraction. Specially, the coupling approaches of online SP-LC systems and the corresponding interfaces have been discussed and reviewed in detail, such as online injector, autosampler combined with transport unit, desorption chamber and column switching. Typical applications of the online SP-LC techniques have been summarized. Then the problems and expected trends in this field are attempted to be discussed and proposed in order to encourage the further development of online SP-LC techniques. 相似文献
968.
P. Yáñez-Sedeño L. AgüíAuthor VitaeR. VillalongaAuthor Vitae J.M. PingarrónAuthor Vitae 《Analytica chimica acta》2014
Forensic analysis is an important branch of modern Analytical Chemistry with many legal and socially relevant implications. Biosensors can play an important role as efficient tools in this field considering their well known advantages of sensitivity, selectivity, easy functioning, affordability and capability of miniaturization and automation. This article reviews the latest advances in the use of biosensors for forensic analysis. The different methodologies for the transduction of the produced biological events are considered and the applications to forensic toxicological analysis, classified by the nature of the target analytes, as well as those related with chemical and biological weapons critically commented. The article provides several Tables where the more relevant analytical characteristics of the selected reported methods are gathered. 相似文献
969.
The combination of electrochemistry (EC) and mass spectrometry (MS) has become a more and more frequently used approach in metabolism studies in the last decade. This review provides insight into the importance of metabolism studies during the drug development process and gives a short overview about the conventionally used methods since electrochemistry is often intended to substitute or minimize animal-based studies. The optimization of the electrochemical conditions is of great importance for a successful comparison with in vitro approaches. The type of metabolism reactions, which can be simulated by EC, has been extended with new cell types and working electrodes. Although the mechanism differs from the enzyme-catalyzed turnover, electrochemistry can be used to simulate a significant number of the respective reactions. 相似文献
970.
MicroRNAs (miRNAs) are short noncoding RNAs that conduct important roles in many cellular processes such as development, proliferation, differentiation, and apoptosis. In particular, circulating miRNAs have been proposed as biomarkers for cancer, diabetes, cardiovascular disease, and other illnesses. Therefore, determination of miRNA expression levels in various biofluids is important for the investigation of biological processes in health and disease and for discovering their potential as new biomarkers and drug targets. Capillary electrophoresis (CE) is emerging as a useful analytical tool for analyzing miRNA because of its simple sample preparation steps and efficient resolution of a diverse size range of compounds. In particular, CE with laser-induced fluorescence detection is a promising and relatively rapidly developing tool with the potential to provide high sensitivity and specificity in the analysis of miRNAs. This paper covers a short overview of the recent developments and applications of CE systems in miRNA studies in biological and biomedical areas. 相似文献