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Yuanyuan Han Qinghai Cai Bin Lu Xue Xiao Shuhan Cui 《Reaction Kinetics and Catalysis Letters》2007,91(1):29-35
A novel solid acid prepared from concentrated sulfuric, boric and phosphoric acid is a highly selective catalyst for the dimerization
of α-methylstyrene at room temperature to generate 4-methyl-2,4-diphenyl-1-pentene. 相似文献
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Alkaline-earth (Ae) metals have attracted a wealth of interdependent research from synthetic chemists. In Ae-catalyzed organometallic reactions, β-diketiminate is a typical ligand used to stabilize Ae catalysts by forming six-membered rings comprising Ae metals. Herein, studies focusing on the configuration of β-diketiminate-coordinated Ae compounds observed that the CC and CN bonds are homogeneous and unchanged. Furthermore, energetic studies observed that the formation of the Ae-incorporated six-membered rings results in enhanced stability of >20 kcal/mol. The nucleus-independent chemical shifts, anisotropy of the induced current density, and molecular orbital analyses demonstrated the non-aromaticity of the β-diketiminate-coordinated Ae compounds. The improved stability of these compounds can be explained by the delocalization of the π electrons derived from the β-diketiminate moiety. 相似文献
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The mesoporous TiO(2) solid and hollow spheres have been synthesized via a controllable and simple chemical route. Structural characterization indicates that these TiO(2) mesoporous spheres after calcined at 500 degrees C have an obvious mesoporous structure with the diameters of 200-300 nm for solid spheres and 200-500 nm for hollow spheres. The average pore sizes and BET surface areas of the mesoporous TiO(2) solid and hollow spheres are 6.8, 7.0 nm and 162, 90 m(2)/g, respectively. Optical adsorption investigation shows that TiO(2) solid and hollow spheres possess a direct band gap structure with the optical band gap of 3.68 and 3.75 eV, respectively. A possible formation mechanism for TiO(2) solid and hollow spheres is discussed. 相似文献
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Based on the unique absorbent characters and three-dimensional network structure of polyacrylamide (PAM) superabsorbent polymer, a photocatalytic degradable TiO2/PAM composite was synthesized by an aqueous solution polymerization method with N,N′-methylene bisacrylamide as crosslinker, potassium peroxydisulfate as initiator, acrylamide as monomer, and TiO2 (P-25) as functional filler. The photocatalytic degradability of the composite was evaluated using methyl orange as photodegradation target, and the recovery and reproducibility of the composite was investigated. It was found that TiO2/PAM composite had a good photocatalytic degradability, the composite also possessed a good reproducibility of photocatalytic degradability, which is possible to be used in practical process. 相似文献
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Annals of Global Analysis and Geometry - In this paper, we study a problem of finding compact hypersurfaces of prescribed mean curvature with free boundary in a ball. We transform the problem to an... 相似文献