对羟基苯甲醛的液相催化氧化合成

研究了活性炭负载磺化酞菁钴催化氧化对甲酚合成对羟基苯甲醛（ＰＨＢ）的诸多影响因素，筛选到较好的反应条件：反应时间，１２小时；温度，６０℃；ＮａＯＨ／对甲酚（ｍｏｌ比）为３．５∶１；催化剂，１５０ｐｐｍ；对甲酚的转化率，９７％；ＰＨＢ收率，８２．５％；选择性，８５．１％。     

Synthesis and characterization of novel low band-gap polymers containing squaraine units

Novel conjugated polymers based on squaric acid having 2,5-Bis[(E)-N-alkylpyrrol-2-ylvinyl]-3-alkylthiophene(PVTVP) unit in the main chain were successfully synthesized in good yields through polycondensation reaction.Their molecular structures were characterized by FT-IR and ~1H NMR.They have good solubility in common organic solvents,good thermal stability by thermal gravimetric analysis and high molecular weights.Their optical properties were investigated by UV-vis absorption spectra in CH_2Cl_2 solution,the results indicated all these compounds showed broad and strong spectral responses from 200nm to 900nm, suggesting their potential for application as organic plastic solar cells.     

均匀折射率包层铌酸锂单晶光纤远离截止区的模特性讨论

给出了具有均匀折射率包层铌酸锂单晶光纤的场强颁上和本征值方程，分析了远离截止区的模特性。     

Analysis on high speed response of a uni-traveling-carrier double hetero-junction phototransistor

In this paper, the positive influence of a uni-traveling-carrier(UTC) structure to ease the contract between the responsivity and working speed of the In P-based double hetero-junction phototransistor(DHPT) is illustrated in detail. Different results under electrical bias, optical bias or combined electrical and optical bias are analyzed for an excellent UTC-DHPT performance. The results show that when the UTC-DHPT operates at three-terminal(3T) working mode with combined electrical bias and optical bias in base, it keeps a high optical responsivity of 34.72 A/W and the highest optical transition frequency of 120 GHz. The current gain of the 3T UTC-DHPT under 1.55-μm light illuminations reaches 62 d B. This indicates that the combined base electrical bias and optical bias of 3T UTC-DHPT can make sure that the UTC-DHPT provides high optical current gain and high optical transition frequency simultaneously.     

有限厚度板穿透裂纹前缘附近三维弹性应力场分析

通过三维有限元计算来研究有限宽度、有限厚度含有穿透裂纹板的裂纹前缘应力场，从中找出应力强度因子与板的厚度、裂纹长度之间的关系，同时还分析了裂尖的三维约束程度和三维约束区的大小。分析结果表明：应力强度因子沿厚度的分布是不均匀的，应力强度因子的最大值及其位置与厚度有关；有限厚度板中面应力强度因子(KI)m-p及最大应力强度因子(KI)max均大于平面应力或平面应变的应力强度因子。对有限厚度裂纹问题，按平面应力或平面应变来考虑是不安全的；板中面的应力强度因子(KI)m-p及最大应力强度因子(KI)max是厚度B／a的函数；板的中面离面约束系数Tx最大，自由面(z=B)Tx=0。沿厚度方向裂尖附近的离面约束系数Tx也是z／B和B／a的函数，随着厚度的增加离面约束系数Tx增大，离中面越近离面约束系数Tx越大。Tx随着x的增大急剧减小，三维约束影响区域大小大约为板厚的一半，且裂纹长度a／W对应力强度因子沿厚度变化规律及Tx影响区域大小影响较小。     

Effect of end groups on the raman spectra of lycopene and β-carotene under high pressure

The Raman spectra of all-trans-lycopene in n-hexane were measured under high pressure, and the results compared with those of β-carotene. The different pressure effects on Raman spectra are analyzed taking into account the different structures of lycopene and β-carotene molecules. It is concluded that: (a) the vibronic coupling between the S? and S? states of β-carotene is stronger than that of lycopene, (b) the diabatic frequency increment of the ν? mode is more susceptible to pressure than that of the ν? mode for lycopene, and (c) β-rings rotation can relieve the pressure effect on the C=C bond length in β-carotene. This work provides some insights for elucidating the structural and environmental effects on Raman spectra of carotenoids.     

On Marcinkiewicz integrals associated to compound mappings with rough kernels

The Lp bounds for the parametric Marcinkiewicz integrals associated to compound mapq pings, which contain many classical surfaces as model examples, are given, where the kernels of our operators are rather rough on the unit sphere as well as in the radial direction. These results substan- tially improve and extend some known results.     

Layered elastic solid method for the generation of unstructured dynamic mesh

The layered elastic solid method (LESM), a modified elastic solid method (ESM) was put forward in the present study. In LESM, the computational zone is divided into several layers and material properties of these layers, which stay a certain value in ESM, are changed with mesh deformation. The deformation capability of mesh in LESM is better than ESM and the quality of the mesh generated by LESM is superior to that generated by ESM when they undergo the same deformation. In ESM, the main influence factors on mesh quality and deformation capability are Poisson’s ratio and single-step rotation angle. In LESM, mesh quality and deformation capability reach a largest value with an increase in Young’s modulus. Meanwhile, the mesh can achieve a larger deformation capability when single-step rotation angle is 0.25°. Finally, numerical simulation on a two-dimensional aerofoil using LESM was carried out. It is found that the results of LESM show a better agreement with experiment results.     

Modeling and control-oriented thermal characteristics under variable load of the solid oxide fuel cell

Journal of Solid State Electrochemistry - The performance of the solid oxide fuel cell (SOFC) is greatly influenced by its operating temperature. Therefore, making a profound study of the thermal...     

Hollow Porous MnFe2O4 Sphere Grown on Elm-Money-Derived Biochar towards Energy-Saving Full Water Electrolysis

The development of inexpensive and efficient bifunctional electrocatalysts is significant for widespread practical applications of overall water splitting technology. Herein, a one-pot solvothermal method is used to prepare hollow porous MnFe₂O₄ spheres, which are grown on natural-abundant elm-money-derived biochar material to construct MnFe₂O₄/BC composite. When the overpotential is 156 mV for both the oxygen evolution reaction and the hydrogen evolution reaction, the current density reaches up to 10 mA cm⁻², and its duration is 10 h. At 1.51 V, the overall water decomposition current density of 10 mA cm⁻² can be obtained in 1 m KOH. This work proves that elm-money-derived biochar is a valid substrate for growing hollow porous spheres. MnFe₂O₄/BC give a promising general strategy for preparing the effective and stable bifunctional catalysis that can be expand to multiple transition metal oxide.