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61.
Copper and zinc were determined in municipal solid waste (MSW) samples with different deposit ages from Tianziling landfill site. The pseudototal metal contents of the MSW samples were determined following an aqua regia digestion. Operational speciation was performed using the modified BCR sequential extraction procedure. Analyses were carried out by AAS. Agreement between most of triplicate samples was acceptable. The amount of copper and zinc extracted in the sequential procedure (i.e. Step 1, Step 2, Step 3, residual) did not generally agree well with pseudototal digestion. Various MSW samples contained significant different levels of copper and zinc, but these were with different potential migrations. For example, 49.88%-76.34% of copper existed in five MSW samples was present as oxidable fraction while ~ 40% of zinc was present as acid soluble fraction. The study illustrates the feasibility and importance of modified BCR sequential extraction procedure used as evaluation method when assessing the potential mobility of heavy metal in MSW landfill. 相似文献
62.
2-氨基-5-烷基-1,3,4-噻二唑修饰环糊精的制备与表征 总被引:1,自引:0,他引:1
在N2气保护下, 用单-(6-对甲苯磺酰基)-CD(β-CD-6-OTs)和过量的2-氨基-5-烷基-1,3,4-噻二唑在80 ℃反应2 d, 合成了5种新的2-氨基-5-烷基-1,3,4-噻二唑修饰β-环糊精. 化合物的结构用IR, 1H NMR, 13C NMR, UV, MS和元素分析等方法进行了表征. 由于环糊精的屏蔽效应, 在2-氨基-1,3,4-噻二唑修饰β-环糊精的 1H NMR中, 修饰产物中的噻二唑质子发生了高场位移. 其它的谱图数据同理论值相吻合, 这证明合成与分离方法是可行的. 研究了产物的生物活性, 结果显示部分化合物(2d, 2e)的抗菌活性明显增强. 相似文献
63.
A diamine, 9,9-bis[4-(4-amino-2-trifluromethylphenoxy)phenyl]fluroene (I) containing the CF3 group, was prepared from 9,9-bis(4-hydroxyphenyl)fluorene and 2-chloro-5-nitrobenzotrifluoride. The imide-containing diacids (V
a-j and VI
a,b) were prepared by condensation reaction of amino acids, aromatic diamines, and trimellitic anhydride. Then, a series of soluble fluorinated polyamides (VII
a-e) and poly(amide imide)s (VIII
a-j and X
a,b) were synthesized from diamine (I) with various aromatic diacids II
a-h and the imide-containing diacids (V
a-j and VI
a,b) via direct polycondensation with triphenyl phosphate and pyridine. All polymers showed excellent solubility in amide-type solvents such as N-dimethylforamide and can also be dissolved in pyridine, m-cresol, and tetrahydrofuran. Polymers afford transparent and tough films by solvent casting. The glass transition temperature of these polymers were in the range of 278–366°C, and the poly(amide imide)s had better thermal stability than polyamides. In comparison with the isomeric IX
a-d, VIII
a-d showed a lighter color with lower b* (yellowness index) values than the corresponding IX series. 相似文献
64.
合成了一系列的10-苄基吖啶酮类化合物, 并探讨了一种用硼氢化钠氢化还原吖啶酮制备10-苄基-9,10-二氢吖啶的简便方法. 吖啶酮1与氯化苄及其衍生物2在氢化钠/N,N-二甲基甲酰胺/碘化钾中反应高产率生成10-苄基吖啶酮类化合物3; 3经硼氢化钠氢化还原生成10-苄基-9,10-二氢吖啶类化合物4, 产率88%~96%. 反应中没有得到预期的产物10-苄基-9,10-二氢吖啶醇类化合物4’, 其反应机理可能是3首先被硼氢化钠还原成醇中间体4’, 4’在硼氢化钠存在下不稳定, 迅速地被进一步还原成4. 相似文献
65.
A study on the microwave responses of YBCO and TBCCO thin films by coplanar resonator technique
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YBa2Cu3O7(YBCO) thin films have been prepared by
thermal coevaporation on LaAlO3(LAO) substrates, and
Tl2Ba2CaCu2O8(TBCCO) thin films are synthesized
by magnetron sputtering method on LAO substrates. The transition
temperature Tc is 90\,K for YBCO/LAO and 104\,K for
TBCCO/LAO. Microwave responses of the films are studied
systematically by coplanar resonator technique. Energy gaps of the
films obtained are {\it\Delta}0=1.04kBTc for YBCO
films and ${\it\Delta}_0=0.84kBTc for TBCCO films by
analysing the temperature dependence of resonant frequencies of
coplanar resonator. Penetration depth at 0\,K \lambda 0=198nm
for YBCO films and \lambda0 =200nm for TBCCO films could also
be obtained by using the weak coupling theory and two fluid theory.
Results of penetration depth and energy gap confirm the weak coupling
properties of the films. In addition, microwave surface resistances
Rs of YBCO/LAO and TBCCO/LAO are also investigated by
analysing the quality factor and insert loss of the coplanar
resonator. Surface resistance of TBCCO/LAO is less than that of
YBCO/LAO, so that TBCCO/LAO films may have more potential
applications. 相似文献
66.
采用AAO模板及后处理方法合成了圆盘状α-Co(OH)2并研究了其电化学电容性能. 在该合成方法中, 先采用阳极氧化铝模板结合交流电沉积的方法获得钴纳米线, 而后将其在碱液中通过溶解氧氧化生成终端产物. 用红外光谱(FT-IR), X射线衍射(XRD)和场发射扫描电子显微镜(FE-SEM)表征了产物的结构和形貌; 用循环伏安、恒电流充放电测试方法对其电化学性能进行了测试. 此外, 对圆盘状Co(OH)2的形成机理进行了初步探讨. 结果表明, 用此方法合成的Co(OH)2具有圆盘状形貌, 属α相态, 且表现出较好的电容特性. 相似文献
67.
处理由偏微分方程描述的新的平面曲线流:DX/Dt=β(k)N,X(μ,0)=X0(μ),当初始曲线X0(μ)是凸的Jordan曲线和β(k)满足适当的条件时,应用偏微分方程中的最大值原理和先验估计,证明了发展曲线的周长和面积同时收缩,最终它们都收缩到一点。 相似文献
68.
69.
在二乙酰丙酮铂存在下, 以紫外光引发AB4型单体双(N,N-二烯丙基胺基)甲基硅烷发生硅氢加成反应, 制备了超支化聚碳硅氮烷. 聚合产物通过FTIR, 1H NMR, 13C NMR和29Si NMR谱和体积排除色谱/激光光散射联用技术进行表征. 与常规加热条件下Karstedt's催化剂催化的硅氢加成聚合相比, 光引发聚合的反应速度快. 波谱分析表明, 聚合过程中以α位硅氢加成反应为主. 光引发聚合制备的超支化聚碳硅氮烷支化度(DB)和平均支化数(ANB)分别为0.46和0.53, 与理论值相近. 其重均分子量为12500 g/mol, 分子量分布系数为2.1, Mark-Houwink方程指数α为0.44, 与热聚合制备的超支化聚碳硅氮烷的参数相近. 相似文献
70.
Structural and thermal stabilities of Au@Ag core-shell nanoparticles and their arrays:A molecular dynamics simulation
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Thermal stability of core-shell nanoparticles(CSNPs)is crucial to their fabrication processes,chemical and physical properties,and applications.Here we systematically investigate the structural and thermal stabilities of single Au@Ag CSNPs with different sizes and their arrays by means of all-atom molecular dynamics simulations.The formation energies of all Au@Ag CSNPs we reported are all negative,indicating that Au@Ag CSNPs are energetically favorable to be formed.For Au@Ag CSNPs with the same core size,their melting points increase with increasing shell thickness.If we keep the shell thickness unchanged,the melting points increase as the core sizes increase except for the CSNP with the smallest core size and a bilayer Ag shell.The melting points of Au@Ag CSNPs show a feature of non-monotonicity with increasing core size at a fixed NP size.Further simulations on the Au@Ag CSNP arrays with 923 atoms reveal that their melting points decrease dramatically compared with single Au@Ag CSNPs.We find that the premelting processes start from the surface region for both the single NPs and their arrays. 相似文献