Ni2P-NiS双助剂促进g-C3N4光催化产氢动力学

本文通过简单的一步水热法得到Ni₂P-NiS双助催化剂,之后采用溶剂蒸发法将Ni₂P-NiS与g-C₃N₄纳米片结合构建获得无贵金属的Ni₂P-NiS/g-C₃N₄异质结。研究结果表明,优化后的复合材料具有良好的光催化产氢活性,其产氢速率最高可到6892.7 μmol·g^-1·h^-1,分别为g-C₃N₄ (150 μmol·g^-1·h^-1)、15%NiS/g-C₃N₄ (914.5 μmol·g^-1·h^-1)和15%Ni₂P/g-C₃N₄ (1565.9 μmol·g^-1·h^-1)的46.1、7.5和4.4倍。这主要归因于Ni₂P-NiS相比Ni₂P和NiS单体具有更好的载流子转移能力,其与g-C₃N₄形成的肖特基势垒能有效促进光生载流子在二者界面上的分离,同时Ni₂P-NiS能进一步降低析氢过电势,进而显著增强了表面析氢反应动力学。本研究为开发稳定、高效的非贵金属产氢助剂提供了实验基础。     

旋涡与行进表面水波相互作用的实验研究

采用振动板式造波器在二维水槽中生成近似单色的行进表面水波，采用夹板式涡发生器生成稳定上浮的涡对，在Ｆｒｏｕｄｅ数约为０．５的条件下，得到了水下涡对与不同波长和振幅的行进表面水波相互作用时的干扰图象，以实验方法验证了理论分析和数值计算的结果，并为进一步研究旋涡与行进表面水波的相互作用提供了一种实验研究方法     

Modal part analysis of slosh of the liquid in a cylindrical container in the case of small bond number

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跳马项目的三维实时动态测量系统

为跳马项目研究的电测系统中引入数字信号处理的传递函数及频谱分析的方法,采集和处理了因人体冲击三维力对信号的耦合干扰造成的十分复杂的响应信号,具有较高的动态测试精度.可以获得跳马动作的全部运动生物力学参数.现已用于中国国家体操队进行计算机辅助训炼.     

结构动力优化设计述评与展望

结构动力优化设计是当前工程结构设计研究领域中的前沿性课题。文中着重从结构动力特性优化、结构动力响应设计、结构动力灵敏度分析和基于可靠性的结构动力优化设计等四个专题方面对结构动力优化设计研究的发展与现状进行了述评,并粗略地展望了结构动力优化研究未来的发展趋势。      

NONLINEAR UNIFIED STRENGTH MODEL OF GEOMATERIALS

将材料的破坏归结为剪切破坏,每种材料对应于特定的剪切滑动面,抗剪强度为滑动面上正应力的函数,基于不同材料的强度特性将一系列的剪切滑动面统一起来,建立了岩土材料的非线性统一强度模型.非线性统一强度模型的滑动面为β应力空间内的等倾面,在β应力空间内的强度面为圆锥面;在普通应力空间内的强度面为一系列连续光滑、外凸的锥面,在偏平面上强度曲线涵盖了从下限Matsuoka-Nakai曲线到上限Drucker-Prager圆之间的所有区域,子午面上强度线为直线.非线性统一强度模型只有3个材料参数,参数都具有明确的物理意义,通过与国内外学者已取得的岩土类材料真三轴强度试验结果的比较,表明模型可适用于多种类型的材料,并合理描述其非线性强度特性.     

线性随机桁架结构的平稳随机响应分析

研究了随机桁架结构的平稳随机响应问题。同时考虑结构的物理参数、几何尺寸的随机性，从结构平稳随机响应在频域上的表达式出发，利用求解随机变量函数矩的方法，导出了随机桁架结构在平稳随机激励下位移响应均方值的均值、均方差和变异系数的计算表达式。通过算例考察了随机荷载激励下结构物理参数、几何尺寸的随机性对结构随机响应的影响。     

LC–MS3 Strategy for Quantification of Carbamazepine in Human Plasma and Its Application in Therapeutic Drug Monitoring

This study developed a detection method based on the strategy of HPLC/MS³ and verified its suitability by quantifying carbamazepine in human plasma. The high-performance liquid chromatography–tandem mass spectrometry (HPLC/MS³) system was performed using a Shimadzu UFLC XR liquid chromatography and a SCIEX QTRAP^® 5500 linear ion trap triple quadrupole mass spectrometer. The specific operation was as follows: the sample protein was firstly precipitated using methanol, then carbamazepine and carbamazepine-D₂N¹⁵ were separated on an ACQUITY UPLC HSS T3 column using the gradient elution with solvent A (0.1% formic acid) and solvent B (0.1% formic acid in acetonitrile) at a flow rate of 0.25 mL/min. Each sample was run for 7 min. This method was validated for various parameters including accuracy, precision, selectivity, linearity, LLOQ, etc. Only 5 μL of sample plasma could obtain the result of LLOD 0.5 µg/mL. The intra-day and inter-day precision was <8.23%, and accuracy was between −1.74% and 2.92%. This method was successfully used for monitoring the blood concentration of epilepsy patients after carbamazepine treatment.     

Immunomodulatory Properties of Masticadienonic Acid and 3α-Hydroxy Masticadienoic Acid in Dendritic Cells

Dendritic cells are antigen-presenting cells, which identify and process pathogens to subsequently activate specific T lymphocytes. To regulate the immune responses, DCs have to mature by the recognition of TLR ligands, TNFα or IFNγ. These ligands have been used as adjuvants to activate DCs in situ or in vitro, with toxic effects. It has been shown that some molecules affect the immune system, e.g., Masticadienonic acid (MDA) and 3α-hydroxy masticadienoic acid (3α-OH MDA) triterpenes naturally occurring in several medicinal plants, since they activate the nitric oxide synthase in macrophages and induce T lymphocyte proliferation. The DCs maturation induced by MDA or 3a-OH MDA was determined by incubating these cells with MDA or 3α-OH MDA, and their phenotype was afterwards analyzed. The results showed that only 3α-OH MDA was able to induce DCs maturation. When mice with melanoma were inoculated with DCs/3α-OH MDA, a decreased tumor growth rate was observed along with an extended cell death area within tumors compared to mice treated with DCs incubated with MDA. In conclusion, it is proposed that 3α-OH MDA may be an immunostimulant molecule. Conversely, it is proposed that MDA may be a molecule with anti-inflammatory properties.