The nonlinear refraction sign turned to reverse by intercalating cresyl violent dye into layered titanate nanosheets

Solid-state dye-doped materials are an attractive alternative to conventional liquid dye solution. In this study, the spectral characteristics of dye cresyl violet before and after intercalating into layered titanate nanosheets and forming a nanohybrid thin film were investigated by measuring absorption and fluorescence spectra. In addition, their nonlinear optical properties were studied using single beam z-scan technique under irradiation of low power continuous wave (CW) produced by DPSS laser with a wavelength of 532 nm. The nonlinear studying results reveal that the dye cresyl violet in solution has a negative nonlinear refractive index, but it reverses to positive after the dye is intercalated into layered titanate nanosheets with a negative nonlinear refractive index forming CV/HTO nanohybrid thin film. This method can provide a way to turn to reverse nonlinear refraction sign of the materials.     

Single-bunch emittance dilution in the perfect ILC main linac

In the ILC(International Linear Collider)main linac, low emittance preservation is the most important issue for beam dynamics study. As the main sources of emittance dilution, the dispersive and wakefield effects were studied in this paper. The theoretical calculations and numerical simulations of these two effects on single-bunch emittance dilution, without any misalignment errors, are presented in detail.     

赤铁矿和三羟铝石吸附Cu~(2+)的红外光谱研究

应用红外光谱法,研究了不同pH值和Cu2+浓度条件下,合成赤铁矿和三羟铝石吸附Cu2+后表面羟基结构及其特征吸收峰的变化。结果表明:(1)随Cu2+浓度增加,赤铁矿表面H—O—H和OH的变形振动参与了吸附反应,Cu2+强烈地缔结在Fe—O上,形成了Fe—O—(Cu)结构。(2)酸性条件下,H+破坏了赤铁矿表面的O—H结构,NO3-促使弱峰1 131 cm-1的产生。随pH值增大,赤铁矿表面OH-逐渐由伸缩振动转变为变形振动,Fe—OH和Fe3+—O2-结构不断发生改变。(3)三羟铝石对Cu2+的吸附发生在高波位,随Cu2+浓度增大,其表面游离羟基的O—H弯曲振动、水分子的OH-伸缩振动和H—O—H弯曲振动均参与了吸附反应,Al—O基中的Al3+渐被Cu2+取代从而加强了较低波位的振动强度。(4)随pH值增加,三羟铝石Al—OH的弯曲振动和Al—O的伸缩振动逐渐发生着改变,表明吸附Cu2+后,在其表面形成了AlOCu+与AlOCuOH结构。     

Examples of entropy generating sequence

We introduce the notion of entropy generating sequence for infinite words and define its dimension when it exists. We construct an entropy generating sequence for each symbolic example constructed by Cassaigne such that the dimension of the sequence is the same as its topological entropy dimension. Hence the complexity can be measured via the dimension of an entropy generating sequence. Moreover, we construct a weakly mixing example with subexponential growth rate.     

A note on operator probability theory involving numerical ranges

In this note, the relationships between the expectation and variance in operator probability theory and numerical range of operators are considered.     

Construction of Multiform Hollow-Structured Covalent Organic Frameworks via a Facile and Universal Strategy for Enhanced Sonodynamic Cancer Therapy

The special structural morphology of hollow covalent organic frameworks (HCOFs) has an important influence on their applications. However, the rapid and precise control of morphology for HCOFs still remains largely challenging. Herein, we present a facile and universal two-step strategy based on solvent evaporation and oxidation of imine bond for the controllable synthesis of HCOFs. The strategy enables to prepare HCOFs in a greatly shortened reaction time and seven kinds of HCOFs are fabricated by the oxidation of imine bond via hydroxyl radicals (⋅OH) generated from Fenton reaction. Importantly, a fascinating library of HCOFs with diverse nanostructures, including bowl-like, yolk-shell, capsule-like and flower-like morphologies, has been ingeniously constructed. Owing to the large cavities, the obtained HCOFs are ideal candidates for drug delivery, which are employed to load five small molecule drugs, achieving the enhanced sonodynamic cancer therapy in vivo.     

Design Rules for Two-Dimensional Organic Semiconductor-Incorporated Perovskites (OSiP) Gleaned from Thousands of Simulated Structures**

Two-dimensional (2D) halide perovskites are an attractive class of hybrid perovskites that have additional optoelectronic tunability due to their accommodation of relatively large organic ligands. Nevertheless, contemporary ligand design depends on either expensive trial-and-error testing of whether a ligand can be integrated within the lattice or conservative heuristics that unduly limit the scope of ligand chemistries. Here, the structural determinants of stable ligand incorporation within Ruddlesden-Popper (RP) phase perovskites are established by molecular dynamics (MD) simulations of over ten-thousand RP-phase perovskites and training of machine learning classifiers capable of predicting structural stability based solely on generalizable ligand features. The simulation results show near-perfect predictions of positive and negative literature examples, predict trade-offs between several ligand features and stability, and ultimately predict an inexhaustibly large 2D-compatible ligand design-space.     

Two—dimensional Network Crown Ether Complex.Synthesis and Crystal Structure of 18—Crown—6 Complex：[K（18—C—6）]2[Cd—（nmt）2]

The novel complex [K(18-C-6)]2[Cd(mnt)2][18-C-6-18-crown-6,nmt=1,2-dicyanoethene-1,2-dithiolate,C2S2-(CN)2^2-] was synthesized and characterized by elemental analysis,IR spectrum and X-ray diffraction analysis.The complex displays two-dimensional network structure of [K(18-C-6)] complex segments and [Cd(nmt)2] complex segment bridged by S-K-S,S-K-N and N-K-N interactions between adjacent[K(18-C-6)] and [Cd(mnt)2]units.     

Study of lower emittance dedicated synchrotron radiation mode for the BEPCⅡ

In this paper,a dedicated synchrotron radiation （SR） mode for the BEPCⅡ with an emittance of 85 nm has been designed,including the linear lattice,chromaticity correction and dynamic aperture optimization.The emittance of the new mode is about 60% of the previous mode used for routine operation of the BEPCⅡ .The effect of wigglers on the linear lattice was compensated and the total dynamic aperture including the wigglers’ nonlinear effect was estimated.The preliminary commissioning at the end of 2008 and the formal operation with the new mode confirmed its merits.     

Cube‐like 12‐MC‐4 and Offset Stacked 10‐MC‐3 Metallacrowns: Synthesis,Structure, and Magnetic Properties

Two complexes [Mn^III₄(naphthsao)₄(naphthsaoH)₄] ( 1 ) and [Fe^III₆O₂(naphthsao)₄(O₂CPh)₆] ( 2 ) [naphthsao = 1‐(1‐hydroxy‐naphthalen‐2‐yl)ethanone oxime] were obtained through the reactions of naphthsao ligand and MnCl₂ · 4H₂O or FeCl₃ · 6H₂O in the presence of triethylamine (Et₃N). Their structures were determined by X‐ray single crystal diffraction, elemental analysis, and IR spectra. Complex 1 displays 12‐MC‐4 metallacrown structural type with cube‐like configuration and 2 shows an offset stacked 10‐MC‐3 structural type with the ring connectivity containing Fe–O–C–O–Fe–O–N–Fe–O–N. Magnetic susceptibility measurement reveals the ferromagnetic interactions and field‐induced slow relaxation of the magnetization for 1 , whereas out‐of‐phase signal is not observed for 2 .