能动磨盘变形检测中的各误差因素分析

针对现有f530 mm能动磨盘的检测系统（有效检测口径f420 mm）,系统分析了检测过程中的球头误差、传感器安装角度误差和坐标定位误差,并给出了各项误差对检测精度的影响。同时,还针对检测基座不完全水平的问题建立模型,应用最小二乘法实现了检测数据的去倾斜处理。给出了实测数据去倾斜前后和误差补偿前后的检测精度对比情况,结果表明去倾斜算法能较好地还原实测数据,补偿检测中的系统误差有助于提高检测精度。     

Temporal properties in clear speech perception

Three experiments were conducted to study relative contributions of speaking rate, temporal envelope, and temporal fine structure to clear speech perception. Experiment I used uniform time scaling to match the speaking rate between clear and conversational speech. Experiment II decreased the speaking rate in conversational speech without processing artifacts by increasing silent gaps between phonetic segments. Experiment III created "auditory chimeras" by mixing the temporal envelope of clear speech with the fine structure of conversational speech, and vice versa. Speech intelligibility in normal-hearing listeners was measured over a wide range of signal-to-noise ratios to derive speech reception thresholds (SRT). The results showed that processing artifacts in uniform time scaling, particularly time compression, reduced speech intelligibility. Inserting gaps in conversational speech improved the SRT by 1.3 dB, but this improvement might be a result of increased short-term signal-to-noise ratios during level normalization. Data from auditory chimeras indicated that the temporal envelope cue contributed more to the clear speech advantage at high signal-to-noise ratios, whereas the temporal fine structure cue contributed more at low signal-to-noise ratios. Taken together, these results suggest that acoustic cues for the clear speech advantage are multiple and distributed.     

Single C59N molecule as a molecular rectifier

We report a new kind of experimental realization of a molecular rectifier, which is based on a single azafullerene C59N molecule in a double-barrier tunnel junction via the single electron tunneling effect. An obvious rectifying effect is observed. The positive onset voltage is about 0.5-0.7 V, while the negative onset voltage is about 1.6-1.8 V. Theoretical analyses show that the half-occupied molecular orbital of the C59N molecule and the asymmetric shift of the molecular Fermi level when the molecule is charged are responsible for the molecular rectification.     

Chiral magnetic metal-organic frameworks of dimetal subunits: magnetism tuning by mixed-metal compositions of the solid solutions

The isostructural, chiral molecular magnetic materials with the formula [MxM'(2-x)(ca)2(1,4-dimb)]n [H2ca = D-(+)-camphoric acid, 1,4-dimb = 1,4-di-(1-imidazolyl-methyl)-benzene, M = Ni(II), M' = CoII, 0 < or = x < or = 2] consist of ca-bridged (4,4) layers with [M2(O2CR)4] as secondary building units that are pillared by the 1,4-dimb ligands into a unique 3D framework. The high-spin octahedral symmetry and the proportions of the mixed-metal ions were characterized by UV-vis spectroscopy. The compounds exhibit the onset of antiferromagnetic ordering at 7.5 approximately 23 K, as well as weak ferromagnetism, spin-flop, and glassy behavior that result from the randomness of the mixed-metal pairs, magnetic anisotropy of the metallic cations, and antisymmetric exchange. The composites should be regarded as molecular alloys of the pure Ni(II) and Co(II) compounds. The magnetic behavior of the solid solutions shows unambiguously that the organic bridges, bond angles, and bond distances greatly influence the effective interactions and bring about cooperative magnetic behavior in the chiral 3D frameworks.     

关于分光计调整方法的分析

本文对自准直调节方法的成像规律和光栅侧向倾斜对测量结果的影响等问题,进行了半定量分析,给出了相关的调节依据和正确的调节步骤     

A Hydroxytricyanopyrrole-Based Fluorescent Probe for Sensitive and Selective Detection of Hypochlorous Acid

Hypochlorous acid (HOCl) is a reactive substance that reacts with most biomolecules and is essential in physiological and pathological processes. Abnormally elevated HOCl levels may cause inflammation and other disease responses. To further understand its key role in inflammation, HOCl must be detected in situ. Here, we designed a hydroxytricyanopyrrole-based small-molecule fluorescent probe (HTCP-NTC) to monitor and identify trace amounts of HOCl in biological systems. In the presence of HOCl, HTCP-NTC released hydroxyl groups that emit strong fluorescence covering a wide wavelength range from the visible to near-infrared region owing to the resumption of the intramolecular charge transfer process. Additionally, HTCP-NTC demonstrated a 202-fold fluorescence enhancement accompanied by a large Stokes shift and a low detection limit (21.7 nM). Furthermore, HTCP-NTC provided a rapid response to HOCl within 18 s, allowing real-time monitoring of intracellular HOCl. HTCP-NTC exhibited rapid kinetics and biocompatibility, allowing effective monitoring of the exogenous and endogenous HOCl fluctuations in living cells. Finally, based on fluorescence imaging, HTCP-NTC is a potential method for understanding the relationship between inflammation and HOCl.     

半导体脉冲功率开关的最新进展

简述了脉冲功率开关的发展及国内外脉冲功率晶闸管产品的现状,并详细介绍了国内的脉冲功率开关产品及其特点。阐述了脉冲功率晶闸管组件产品的设计与应用,以及半导体脉冲功率开关的测试试验平台。简要介绍了脉冲功率晶闸管及其组件在工程应用中的同步驱动、感应取能和串联均压等关键技术,并简述了脉冲功率晶闸管组件的工程应用实际效果。阐述了半导体脉冲功率开关及其测试试验平台的发展方向。     

50-5000 eV电子被C4H8O, C5H10O2, C6H5CH3和C4H8O2散射的总截面

使用电子被C, H和O原子散射总截面的实验数据, 利用修正后的可加性规则计算了能量为50-5000 eV的电子被4个复杂大分子C4H8O, C5H10O2, C6H5CH3和C4H8O2散射的总截面, 并将计算结果与实验结果及其他理论计算结果进行了比较. 结果表明, 即使是在几十电子伏的入射能量下, 修正后的可加性规则计算出的总截面依然能与实验结果符合很好, 而使用未修正的可加性规则进行计算, 即使是在几百电子伏的入射能量下得到的总截面仍偏离实验值较远. 分析表明, 未修正的可加性规则计算得到的总截面在中低能区过大、随电子入射能量的增加而衰减太快的问题是由可加性规则本身引起的, 其实质是未考虑低能下分子内原子间的相互屏蔽对散射总截面的计算所带来的影响.