Morphology and spectral properties of thin films of benzoxazole derivatives of biphenyl

We have studied the spectral properties and morphology of thin films (TVD films) formed by thermal vacuum deposition of 4,4′-bis[(E)-1-(1,3-benzoxazol-2-yl)-2-ethenyl]-1,1′-biphenyl and its substituted derivatives. We have shown that introducing bulky 2,2′-oxyhexyl substituents into the biphenyl units leads to a shift of the fluorescence maximum for the TVD films toward shorter wavelengths, a decrease in their photostability, and aggregation of the films during storage. __________ Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 74, No. 3, pp. 300–303, May–June, 2007.     

Nonlinear rheological behavior of silica filled solution‐polymerized styrene butadiene rubber

The reinforcement and nonlinear viscoelastic behavior have been investigated for silica (SiO₂) filled solution‐polymerized styrene butadiene rubber (SSBR). Experimental results reveal that the nonlinear viscoelastic behavior of the filled rubber is similar to that of unfilled SSBR, which is inconsistent with the general concept that this characteristic comes from the breakdown and reformation of the filler network. It is interesting that the curves of either dynamic storage modulus (G′) or loss tangent (tan δ) versus strain amplitude (γ) for the filled rubber can be superposed, respectively, on those for the unfilled one, suggesting that the primary mechanism for the Payne effect is mainly involved in the nature of the entanglement network in rubbery matrix. It is believed there exists a cooperation between the breakdown and reformation of the filler network and the molecular disentanglement, resulting in enhancing the Payne effect and improving the mechanical hysteresis at high strain amplitudes. Moreover, the vertical and the horizontal shift factors for constructing the master curves could be well understood on the basis of the reinforcement factor f(φ) and the strain amplification factor A(φ), respectively. The surface modification of SiO₂ causes a decrease in f(φ), which is ascribed to weakeness of the filler–filler interaction and improvement of the filler dispersion. However, the surface nature of SiO₂ hardly affects A(φ). © 2007 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 45: 2594‐2602, 2007     

Spectral characteristics of a microwave radar signal backscattered by the sea surface at small incidence angles

We present a theoretical analysis of the Doppler-spectrum properties of a microwave radar signal scattered by the sea surface at small incidence angles. The dependences of Doppler-spectrum width and shift on the wind velocity and wave development stage and their azimuthal dependence are analyzed. The case of mixed sea (wind wave plus swell) is also considered. The JONSWAP spectrum model is used to describe sea waves. The study shows that Doppler-spectrum parameters are sensitive to variation of sea-surface state; for example, for the case of developed sea waves, an increase in wind velocity by 1 m/sec leads to increases in the Doppler-spectrum width and shift by 15 Hz and 3 Hz, respectively. It is shown that for the case of a moving radar the Doppler spectrum remains sensitive to variation of sea- surface state with a sufficiently narrow radar directivity pattern. Estimates show that in the case of a single sea- wave system on the surface, using Doppler-spectrum parameters we can, in principle, determine wave type (developing wind wave, developed wind wave, or swell), dominant wavelength, wave propagation direction, and wave height; wind velocity, direction, and acceleration distance can be determined for wind waves.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 39, No. 5, pp. 517–526, May, 1996.This paper was supported by the Russian Foundation for Fundamental Research (project 93-02-15892).     

GRIF-1 experiment on board the SPEKTR/MIR orbital complex: Study of solar X-ray,gamma-ray,and neutron flares and correlation of magnetosphere-charged particle fluxes with solar activity

The SPEKTR module of the MIR orbital station was launched in May 1995. The multipurpose experiment was based on the GRIF-1 research complex consisting of an oriented X-ray spectrometer, a spectrometer of gamma-quanta and neutrons, a spectrometer of electrons and protons with a large geometrical factor, and a spectrometer of electrons, protons, and nuclei with a small geometrical factor. The solar geophysical aspects of the experiment included the measurements of spectral and temporal parameters of solar hard electromagnetic (0.01–50 MeV) and neutron (>20 MзB) radiation, the study of spectral, temporal, and spatial characteristics of energetic electrons (0.04–1.5 MeV), protons, and nuclei (1–200 MeV/nucleon) in the circumterrestrial space, as well as the correlations of these parameters with solar activity phenomena.     

北京同步辐射装置3B1B生物光谱实验站

本文介绍北京同步辐射装置（ＢＳＲＦ）３Ｂ１Ｂ光束线、生物光谱实验站和圆二色谱仪的基本情况。报道北京正负电子对撞机（ＢＥＰＣ）同步辐射专用光期间，我们在站测量了１１种手征性生物和药物样品的圆二色（ＣＤ）谱，首次在国内利用同步辐射光获取了Ｄ－苯丙氨酸等样品的ＣＤ谱和Ｄ－及Ｌ－亮氨酸对称的ＣＤ曲线。     

多元整系数多项式因式分解的一种理论和算法

本文将ｔ（ｔ是大于２的整数）元整系数多项式看成为系数为ｔ－２元整系数多项式的二元多项式，建立了多元整系数多项式因式分解的一种新理论，进而得到了分解多元整系数多项式的一个有力的算法。     

Axial Structure of the Field Intensity in Diffusion-Controlled Surface-Wave Produced Plasmas

Surface-wave gas discharges sustained under the conditions of a diffusion controlled regime are studied on the basis of the fluid plasma model. The self-consistent behaviour of the plasma density and of the field intensity along the discharge length is obtained. It is shown that the nonlinearity in the particle balance equation due to stepwise ionisation determines the plasma density in terms of the field intensity and ensures self-consistent behaviour of the wave ? discharge characteristics in a diffusion controlled regime.     

Interaction of a point vortex with boundary singularities of higher orders

Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 3, pp. 167–168, May–June, 1993.