Applications of coupled LC-GC: A review

Although coupled liquid chromatographygas chromatography (LC-GC) was first demonstrated ten years ago, only in the last few years has there been a sudden surge of interest in the technique. Approximately 70% of the total number of LC-GC applications have been published in the last two years (1987–88) alone. This review categorizes LC-GC publications into four main application areas: fossil fuels, foods, environmental samples, biologiical/pharmaceutical samples, and miscellaneous samples. Multidimensional separations carried out using other coupled-column chromatographic techniques (such as supercritical fluid chromatography (SFC) with GC, and on-line trace enrichment-GC) have also been included in this review.     

激光等离子体2660紫外探针及干涉系统

成功地在六路高功率Nd玻璃激光装置上建立了2660紫外激光探针和适合紫外波段的Normaski干涉仪,首次将可见波长的连续激光应用于紫外干涉仪中靶成像调整和光路准直。利用该紫外光干涉仪,在铜柱状靶(φ500μm)上测量了厚等离子体中高达0.6n。的电子密度。     

Quantum interference of electrons in disordered metals

Investigation of the galvanomagnetic properties of disordered metals in weak magnetic fields [r(H)?l, wherer(H) is the electron trajectory radius andl, the electron free path], proved to be one of the effective experimental methods of studying disordered metals. The phase difference between the interfering electron waves is affected by the presence of magnetic flux in the sample. One of the observable effects is the oscillatory magnetoresistanceK(H) of multiconnected samples predicted by Altshuleret al (1981). The period ofK(H) oscillations for the hollow cylinders, networks or chains with orifices cross-sections areasS isΔH=φ ₀/2S [whereφ ₀=hc/e]. The amplitude and the phase of the oscillations depend on the spin orbit interaction, the intensity of superconductive fluctuation etc. It should be noted that in small “mesoscopic” single loops the oscillations with the periodΔH?φ ₀/S were also observed recently (see also Altshuleret al 1987 included in this issue).     

On the variational representation of solutions to some quasilinear equations and systems of hyperbolic type on the basis of potential theory

We demonstrate a method that permits to obtain generalized solutions for some quasilinear equations and systems of hyperbolic type. The corresponding variational principle is constructed using the theory of equilibrium of a potential in an external field. Dedicated to the memory of B. M. Levitan Supported by RFBR grants Nos. 05-01-00522 and NSh-1551.2003.1, by Program No. 1 of the Branch of Mathematics, Russian Academy of Sciences, and by INTAS project No. 03-51-6637.     

Observation of the nonlinear effect in relativistic Thomson scattering of electron and laser beams

Thomson scattering of high-power laser and electron beams is a good test of electrodynamics in the high-field region. We demonstrated production of high-intensity X-rays in the head-on collision of a CO₂ laser and 60-MeV electron beams at Brookhaven National Laboratory, Accelerator Test Facility. The energy of an X-ray photon was limited at 6.5 keV in the linear (lowest order) Thomson scattering, but the nonlinear (higher order) process produces higher energy X-rays. We measured the angular distribution of the high-energy X-rays and confirmed that it agrees with theoretical predictions.     

General strategy for a short and efficient synthesis of 3-hydroxy-4-methylprolines (HMP)

The non-proteinogenic amino acid 3-hydroxy-4-methylproline (HMP) is an active constituent of some potent antimicrobials including echinocandins, nostopeptins, pneumocandins, sporiofungin and mulundocandins. A synthesis has been achieved in 10 steps with 29% overall yield; the Evans’ aldol reaction using Crimmins’ modified method was pivotal to the success of the strategy.     

Standard enthalpy of formation of La2CoO4(cr)

The enthalpies of reactions of La₂CoO₄(cr) and CoCl₂(cr) with hydrochloric acid were measured with an isothermal-jacket calorimeter. The results obtained and the available literature data were used to calculate the standard enthalpy of formation of La₂CoO₄(cr) at 298.15 K, Δ_f H ^o = ?2179 ± 7 kJ/mol.     

On construction of symmetries from integrals of hyperbolic partial differential systems

An algorithm is proposed which allows one to construct higher symmetries of arbitrary order for some special classes of hyperbolic systems possessing integrals. The Pohlmeyer-Lund-Regge system and the open two-dimensional Toda lattices are shown to belong to the class of systems where our algorithm is applicable. __________ Translated from Fundamental’naya i Prikladnaya Matematika (Fundamental and Applied Mathematics), Vol. 10, No. 1, Geometry of Integrable Models, 2004.