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991.
V. A. Krylov O. Yu. Chernova Yu. M. Salganskii L. S. Malygina A. P. Kotkov 《Journal of Analytical Chemistry》2003,58(8):750-755
It is shown that the results of determining methane in high-purity arsine by reaction gas chromatography can be overestimated by more than two orders of magnitude. This overestimation is caused by the formation of methane as a side product of the reaction. Cryogenic preconcentration at the injection stage is proposed to improve the accuracy of determination of methane, and the cryofocusing of impurity hydrocarbons is proposed to improve separation. Detection limits of (3–10) × 10–6 vol % are achieved for C1–C5 hydrocarbons. 相似文献
992.
A procedure was developed for the synthesis of polyfluoroalkylthiotrifluoroacetylketenes, and their reactions with nucleophilic reagents were studied. The resulting compounds were demonstrated to act as heterodienes in reactions with unsaturated compounds. 相似文献
993.
Pavlova N. V. Spiridonov F. F. Svetlov S. A. Pavlov I. N. Volkov Yu. P. 《Russian Journal of Applied Chemistry》2003,76(7):1094-1098
Centrifugal separation of low-concentration suspension in a biconical rotor of a centrifuge was modeled numerically. A system of equations describing the motion of solid particles in a fluid flow was constructed and solved. The effect of geometric parameters of the centrifuge rotor on the separation efficiency was demonstrated. 相似文献
994.
995.
Suzdalev I. P. Buravtsev V. N. Maksimov Yu. V. Zharov A. A. Imshennik V. K. Novichikhin S. V. Matveev V. V. 《Russian Chemical Bulletin》2003,52(9):1950-1958
Magnetic phase transitions of the first and second order were revealed by Mössbauer spectroscopy in nanosystems of - and -ferric oxides and metallic europium subjected to shear stress (240°) under high pressure (20 kbar). For - and -ferric oxide nanoclusters, the Curie (Neel) points decreased to 300 K, whereas for nanostructured europium the Neel point increased from 90 to 100 K. The thermodynamic model of magnetic phase transitions predicting a change in the character of magnetic phase transitions and a decrease (increase) in the critical Neel (Curie) points in nanoclusters was developed. The type of magnetic phase transitions and the change in the critical points were caused by defects in nanoclusters, whose maximum concentration was observed for the clusters with the 20—50 nm size range. 相似文献
996.
V. P. Borovik I. Yu. Bagryanskaya Yu. V. Gatilov O. P. Shkurko 《Journal of Structural Chemistry》2003,44(4):650-654
The crystal structures of 2-amino-4-phenyl-9H-pyrimido[4,5-b]indole and its nitrate were determined by XRD analysis. 13C NMR, XRD, and quantum-chemical data indicate that the acid proton is predominantly localized at the N(3) atom of the pyrimidine ring in both isolated nitrate molecules and in molecules in crystal and solution. 相似文献
997.
It was found experimentally that stacking defects formed in the mechanochemical activation of zinc ferrite enhanced the specific catalytic activity in the reaction of CO oxidation. The specific rate of CO oxidation was a linear function of defect concentration, which was determined using Mössbauer spectroscopy and X-ray diffraction. A conclusion was drawn that the same centers are responsible for an increase in the catalytic activity, the sorption capacity for hydrogen sulfide, and the reactivity of zinc ferrite in the interaction with hydrochloric acid. It was assumed that analogous factors caused an increase in the catalytic activity and reactivity of magnesium ferrite. 相似文献
998.
The results of a kinetic study of model reactions between substituted phenols and bromobenzene in the presence of potassium carbonate and the copper(I) chloride–8-hydroxyquinoline catalytic complex in N,N-dimethylformamide are presented. The reactions were found to obey a first-order rate law. Both orbital and charge interactions should be taken into account in a consideration of the effect of the structural characteristics of reactants on the rate of reaction. The kinetics of substitution of the phenoxide anion for an aromatically bound halogen atom in activated and nonactivated systems with the formation of practically valuable aryl ethers were comparatively studied. The results presented provide an opportunity to distinguish the common features and regularities of activated and nonactivated aromatic substitution in the test systems. 相似文献
999.
An indirect laser photoacoustic technique is described. The basic principle, the experimental set-up and the influencing factors are discussed in detail. This method was used to quantify phenylamine, arginine and methylene blue on membranes. The linear ranges of the calibration curve are up to two orders of magnitude. With 1 microliter of sample solution, the detection limits are 0.25, 1.52 and 0.14 pmol for phenylamine, arginine and methylene blue, respectively. 相似文献
1000.
S. Yu. Kudryashov Yu. G. Kuraeva L. A. Onuchak 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2006,80(7):1115-1118
The thermodynamic characteristics of adsorption of several organic compounds on the carbon adsorbent Carbopack B before and after its modification by a monomolecular layer of cholesteryl-n-pentyl oxybenzoate were determined by gas chromatography. The initial adsorbent was close in its properties to graphitized carbon black. Modification weakened adsorbate-adsorbent attraction and increased the mobility of adsorbed molecules, to a greater extent for nonpolar adsorbents and to a lesser extent for compounds capable of specifically interacting with modifier molecules. 相似文献