全文获取类型
收费全文 | 193854篇 |
免费 | 22960篇 |
国内免费 | 12810篇 |
专业分类
化学 | 134053篇 |
晶体学 | 2274篇 |
力学 | 10564篇 |
综合类 | 951篇 |
数学 | 22324篇 |
物理学 | 59458篇 |
出版年
2023年 | 1976篇 |
2022年 | 3354篇 |
2021年 | 4290篇 |
2020年 | 5551篇 |
2019年 | 6746篇 |
2018年 | 5668篇 |
2017年 | 5265篇 |
2016年 | 9004篇 |
2015年 | 8063篇 |
2014年 | 9647篇 |
2013年 | 12834篇 |
2012年 | 13051篇 |
2011年 | 12985篇 |
2010年 | 10609篇 |
2009年 | 10587篇 |
2008年 | 10542篇 |
2007年 | 9257篇 |
2006年 | 8484篇 |
2005年 | 7711篇 |
2004年 | 6561篇 |
2003年 | 5679篇 |
2002年 | 6335篇 |
2001年 | 5316篇 |
2000年 | 4572篇 |
1999年 | 3489篇 |
1998年 | 2866篇 |
1997年 | 2501篇 |
1996年 | 2506篇 |
1995年 | 2150篇 |
1994年 | 2166篇 |
1993年 | 1961篇 |
1992年 | 1813篇 |
1991年 | 1767篇 |
1990年 | 1655篇 |
1989年 | 1520篇 |
1988年 | 1278篇 |
1987年 | 1268篇 |
1986年 | 1187篇 |
1985年 | 1218篇 |
1984年 | 1116篇 |
1983年 | 1002篇 |
1982年 | 944篇 |
1981年 | 815篇 |
1979年 | 850篇 |
1978年 | 864篇 |
1977年 | 857篇 |
1976年 | 970篇 |
1975年 | 870篇 |
1974年 | 892篇 |
1973年 | 905篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
The influence of a large signal on the characteristics of a small signal near the frequency of the former is experimentally studied for the case of their simultaneous propagation through a resonant transmission line based on backward volume magnetostatic waves. The effects observed are caused by the excitation of spin waves in a ferromagnetic film at different large-signal frequencies and by the back influence of excited spin-wave packets on the amplitude and phase characteristics of the small signal. 相似文献
992.
人工神经网络在SARS疫情分析与预测中的应用 总被引:4,自引:0,他引:4
讨论人工神经网络在 SARS疫情分析与预测中的应用 .采用三层结构的反向传播网络 ( Backpropagation network,简称 BP网络 ) ,对 SARS在中国的传播与流行趋势及控制策略建立了网络模型 .并利用实际数据拟合参数 ,针对北京、山西的疫情进行了计算仿真 .结果表明 ,该网络模型算法收敛速度较快 ,预测精度很高 相似文献
993.
运用多种密度泛函理论 (DFT)和从头算 (abinitio)方法研究了草酰胺顺、反异构体的分子几何构型 ,结果表明Beck88交换函数与LYP非局域相关函数形成杂化的DFT方法B3LYP与MP2方法计算结果比较吻合。在此基础上选择B3LYP方法对草酰胺分子电子结构、红外光谱和前线分子轨道组成进行了系统研究 ;与实验事实对比分析了气态草酰胺分子中配位原子的反应活性 相似文献
994.
995.
Sheng‐Huei Hsiao Chien‐Wei Chen Guey‐Sheng Liou 《Journal of polymer science. Part A, Polymer chemistry》2004,42(13):3302-3313
Two new diamines, 2,4‐diaminotriphenylamine ( 3 ) and N‐(2,4‐diaminophenyl)carbazole ( 4 ), were synthesized via the cesium fluoride‐mediated aromatic substitution reactions of 1‐fluoro‐2,4‐dinitrobenzene with diphenylamine and carbazole, followed by palladium‐catalyzed hydrazine reduction. Amorphous and soluble aramids having pendent diphenylamino and carbazolyl groups were prepared by the phosphorylation polycondensation of aromatic dicarboxylic acids with diamines 3 and 4 , respectively. The aramids derived from diamine 3 had sufficiently high molecular weights to permit the casting of flexible and tough films. They exhibited excellent mechanical properties and moderately high softening temperatures in the 221–298 °C range. However, the reactions of diamine 4 with aromatic diacids gave relatively lower molecular weights products that could not afford flexible films. For a comparative purpose, the parent aramids derived from m‐phenylenediamine and aromatic diacids were also prepared and characterized. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3302–3313, 2004 相似文献
996.
A novel copolymer, poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐2,6‐pyridylene‐1,2‐ethenylene) ( P3 ), containing N‐hexyl‐3,7‐phenothiazylene and 2,6‐pyridylene chromophores was synthesized to investigate the effect of protonation, metal complexation, and chemical oxidation on its absorption and photoluminescence (PL). Poly(N‐hexyl‐3,8‐iminodibenzyl‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) and poly(N‐hexyl‐3,7‐phenothiazylene‐1,2‐ethenylene‐1,3‐phenylene‐1,2‐ethenylene) ( P2 ), consisting of 1,3‐divinylbenzene alternated with N‐hexyl‐3,8‐iminodibenzyl and N‐hexyl‐3,7‐phenothiazylene, respectively, were also prepared for comparison. Electrochemical investigations revealed that P3 exhibited lower band gaps (2.34 eV) due to alternating donor and acceptor conjugated units (push–pull structure). The absorption and PL spectral variations of P3 were easily manipulated by protonation, metal chelation, and chemical oxidation. P3 displayed significant bathochromic shifts when protonated with trifluoroacetic acid in chloroform. The complexation of P3 with Fe3+ led to a significant absorption change and fluorescence quenching, and this implied the coordination of ferric ions with the 2,6‐pyridylene groups in the backbone. Moreover, both phenothiazylene‐containing P2 and P3 showed conspicuous PL quenching with a slight redshift when oxidized with NOBF4. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 1272–1284, 2004 相似文献
997.
Two new compounds have been isolated from the whole plant of Monochoria vaginalis and characterized as: (10Z)‐1‐(2,6‐dihydroxyphenyl)octadec‐10‐en‐1‐one ( 1 ) (20R, 24R)‐campest‐5‐ene‐3β, 4β‐diol ( 2 ) together with nine known ones. The structures of these compounds were elucidated on the basis of spectral data and chemical evidence. 相似文献
998.
A study is conducted of the relationship between the asymptotic behavior of a subharmonic function of finite order in a cone and the distribution of the measure associated with it.Translated from Ukrainskii Matematicheskii Zhurnal, Vol. 43, No. 2, pp. 247–261, Febraury, 1991. 相似文献
999.
G. V. Dubrovskiy A. V. Kuzmenko Yu. G. Markoff 《Theoretical and Mathematical Physics》1995,105(1):1291-1306
A three-dimensional lattice gas approximation for multilayer adsorbates is substantiated on the basis of statistical physics. In addition, some problems of equilibrium thermodynamics and kinetics are formulated, and a number of approximations are derived. A detailed kinetic theory of thin film growth, which is complementary to the applied approaches based on phenomenological models, thermodynamics of nonequilibrium processes, and solid medium and lattice gas models, is developed.Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 105, No. 1, pp. 130–148, October, 1995. 相似文献
1000.
Wei-yi SU~ 《中国科学A辑(英文版)》2007,50(7):1005-1014
The Lipschitz class Lipαon a local field K is defined in this note,and the equivalent relationship between the Lipschitz class Lipαand the Holder type space C~α(K)is proved.Then,those important characteristics on the Euclidean space R~n and the local field K are compared,so that one may interpret the essential differences between the analyses on R~n and K.Finally,the Cantor type fractal functionθ(x)is showed in the Lipschitz class Lip(m,K),m<(ln 2/ln 3). 相似文献