Synthesis of unsaturated esters of pyridine- and quinolinedicarboxylic acids

The divinyl, diallyl, and dipropargyl esters of pyridine-2,4-, pyridine-2,6-, and quinoline-2,4-dicarboxylic acids and the divinyl and dipropargyl esters of pyridine-2,5-dicarboxylic acid have been synthesized.     

1-烃基-1-硅杂环丁烷的合成及其Si—H键伸缩振动频率与结构关系的研究

硅杂环丁烷在有机硅化学中是一类非常重要的小分子环系化合物。由于硅杂环丁烷和环丁烷的环张力相似,因而显示出较高的反应活性。例如能与某些试剂作用,生成开环产物;在光解或热解条件下,产生具有Si=C结构的高活性中间体,可用以合成多种有机硅化合物。     

1-Nucleosides of 5-substituted 4-chloro-1,2,3-triazoles

1-Nucleosides of 5-substituted 4-chloro-1,2,3-triazoles were produced by glycosylation of the corresponding triazoles by the method of fusion with tetra-0-acyl-D-ribofuranose in the presence of bis-p-nitrophenyl phosphate. The structure of the compounds obtained and their conformational peculiarities were studied by the methods of mass spectrometry and NMR spectroscopy.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 11, pp. 1556–1564, November, 1984.     

Cyclization of o-nitrosoacylbenzenes to anthranils

5-Bromo- and 5-methoxy-3-ethylanthranils, respectively, were obtained by cyclization of o-nitrosopropiophenone under the influence of hydrogen bromide in benzene and hydrogen chloride in methanol. In these reactions, the starting nitroso ketone undergoes redox transformations that also proceed readily in an inert solvent in the absence of any cyclizing reagents.Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 7, pp. 886–890, July. 1976.